Preparation method for high-purity iron phosphate and use thereof

The present application belongs to the technical field of battery materials. Disclosed are a preparation method for a high-purity iron phosphate and use thereof. The preparation method comprises the following steps: mixing and stirring an iron phosphide waste, an acid liquid, an oxidant, and an adso...

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Hauptverfasser: Ruokui Chen, Changdong Li, Cunpeng Qin, Dingshan Ruan, Shenghe Tang, Zhenshuan Shi
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creator Ruokui Chen
Changdong Li
Cunpeng Qin
Dingshan Ruan
Shenghe Tang
Zhenshuan Shi
description The present application belongs to the technical field of battery materials. Disclosed are a preparation method for a high-purity iron phosphate and use thereof. The preparation method comprises the following steps: mixing and stirring an iron phosphide waste, an acid liquid, an oxidant, and an adsorbent, heating and leaching, and performing solid-liquid separation to give a first filtrate and a first filter residue; adding an alkali liquid to the first filtrate, adjusting the pH and preserving the heat, and performing solid-liquid separation to give a second filter residue and a second filtrate; performing heat treatment on the second filter residue to give iron oxide; performing high-energy ball milling on the iron oxide, and adding a surfactant for activation to give a slurry; and mixing the slurry with phosphoric acid, heating for reaction, performing solid-liquid separation, washing a solid phase, and then sintering to give iron phosphate. According to the present application, iron oxide and phosphoric acid are prepared from the iron phosphide waste and the like as raw materials. After activation, by means of a low-temperature reaction, the high-purity iron phosphate is prepared. The reaction process is closed-loop preparation, and less waste is produced.
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Disclosed are a preparation method for a high-purity iron phosphate and use thereof. The preparation method comprises the following steps: mixing and stirring an iron phosphide waste, an acid liquid, an oxidant, and an adsorbent, heating and leaching, and performing solid-liquid separation to give a first filtrate and a first filter residue; adding an alkali liquid to the first filtrate, adjusting the pH and preserving the heat, and performing solid-liquid separation to give a second filter residue and a second filtrate; performing heat treatment on the second filter residue to give iron oxide; performing high-energy ball milling on the iron oxide, and adding a surfactant for activation to give a slurry; and mixing the slurry with phosphoric acid, heating for reaction, performing solid-liquid separation, washing a solid phase, and then sintering to give iron phosphate. According to the present application, iron oxide and phosphoric acid are prepared from the iron phosphide waste and the like as raw materials. After activation, by means of a low-temperature reaction, the high-purity iron phosphate is prepared. 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Disclosed are a preparation method for a high-purity iron phosphate and use thereof. The preparation method comprises the following steps: mixing and stirring an iron phosphide waste, an acid liquid, an oxidant, and an adsorbent, heating and leaching, and performing solid-liquid separation to give a first filtrate and a first filter residue; adding an alkali liquid to the first filtrate, adjusting the pH and preserving the heat, and performing solid-liquid separation to give a second filter residue and a second filtrate; performing heat treatment on the second filter residue to give iron oxide; performing high-energy ball milling on the iron oxide, and adding a surfactant for activation to give a slurry; and mixing the slurry with phosphoric acid, heating for reaction, performing solid-liquid separation, washing a solid phase, and then sintering to give iron phosphate. According to the present application, iron oxide and phosphoric acid are prepared from the iron phosphide waste and the like as raw materials. After activation, by means of a low-temperature reaction, the high-purity iron phosphate is prepared. 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Disclosed are a preparation method for a high-purity iron phosphate and use thereof. The preparation method comprises the following steps: mixing and stirring an iron phosphide waste, an acid liquid, an oxidant, and an adsorbent, heating and leaching, and performing solid-liquid separation to give a first filtrate and a first filter residue; adding an alkali liquid to the first filtrate, adjusting the pH and preserving the heat, and performing solid-liquid separation to give a second filter residue and a second filtrate; performing heat treatment on the second filter residue to give iron oxide; performing high-energy ball milling on the iron oxide, and adding a surfactant for activation to give a slurry; and mixing the slurry with phosphoric acid, heating for reaction, performing solid-liquid separation, washing a solid phase, and then sintering to give iron phosphate. According to the present application, iron oxide and phosphoric acid are prepared from the iron phosphide waste and the like as raw materials. After activation, by means of a low-temperature reaction, the high-purity iron phosphate is prepared. The reaction process is closed-loop preparation, and less waste is produced.</abstract><oa>free_for_read</oa></addata></record>
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subjects BASIC ELECTRIC ELEMENTS
CHEMISTRY
COMPOUNDS THEREOF
ELECTRICITY
INORGANIC CHEMISTRY
METALLURGY
NON-METALLIC ELEMENTS
PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY
title Preparation method for high-purity iron phosphate and use thereof
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