Variable energy photoionization device and method for mass spectrometry
A mass spectrometer using a variable energy photoionization device for ionizing and/or cleaving molecules is disclosed. The device permits ionizing photon wavelengths to be selected from a range of wavelengths allowing the ionizing photon energies to be tuned so as to ionize molecules without excess...
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creator | VIORICA LOPEZ-AVILA RANDALL URDAHL JAMES E COOLEY ARTHUR SCHLEIFER |
description | A mass spectrometer using a variable energy photoionization device for ionizing and/or cleaving molecules is disclosed. The device permits ionizing photon wavelengths to be selected from a range of wavelengths allowing the ionizing photon energies to be tuned so as to ionize molecules without excessive fragmentation or to cleave molecules in a controlled manner by breaking only certain molecular bonds. Selection of the wavelengths is afforded by the choice of a plasma-forming gas combined with windowlessly radiating the ionizing photons from a plasma chamber. A method of mass spectrometry featuring selected ionizing photon wavelengths is also disclosed. |
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The device permits ionizing photon wavelengths to be selected from a range of wavelengths allowing the ionizing photon energies to be tuned so as to ionize molecules without excessive fragmentation or to cleave molecules in a controlled manner by breaking only certain molecular bonds. Selection of the wavelengths is afforded by the choice of a plasma-forming gas combined with windowlessly radiating the ionizing photons from a plasma chamber. 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subjects | BASIC ELECTRIC ELEMENTS ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS ELECTRICITY |
title | Variable energy photoionization device and method for mass spectrometry |
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