Preparing organic solution of dialkyl peroxydicarbonate in organic solvent, comprises reacting, in medium with water, alkyl haloformate with inorganic peroxide, where organic solvent is esters derived from aliphatic monocarboxylic acid

Preparing an organic solution of a dialkyl peroxydicarbonate in a liquid organic solvent (S), comprises reacting, in a medium containing water, alkyl haloformate with an inorganic peroxide, where the liquid organic solvent is esters derived from at least aliphatic monocarboxylic acid and at least an...

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Hauptverfasser: BODART VINCENT, DOMPAS DIRK HUGO, JOZEF
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DOMPAS DIRK HUGO, JOZEF
description Preparing an organic solution of a dialkyl peroxydicarbonate in a liquid organic solvent (S), comprises reacting, in a medium containing water, alkyl haloformate with an inorganic peroxide, where the liquid organic solvent is esters derived from at least aliphatic monocarboxylic acid and at least an aliphatic saturated monohydric alcohol. Independent claims are included for: (1) organic solution of dialkyl peroxydicarbonate in a liquid organic solvent obtained by the method; and (2) preparing polymer derived from halogenated ethylenically unsaturated monomers comprising polymerizing at least a halogenous ethylenically unsaturated monomer in aqueous suspension or aqueous microsuspension, in the presence of an initiator including at least a dialkyl peroxydicarbonate. Procédé de préparation d'une solution organique d'un peroxydicarbonate de dialkyle dans un solvant organique liquide (S), réalisé au moins en partie en présence du solvant organique liquide (S) et comprenant au moins une étape au cours de laquelle on fait réagir, dans un milieu contenant de l'eau, un halogénoformiate d'alkyle avec un peroxyde inorganique, le solvant organique liquide (S) étant choisi parmi les esters (E) dérivés d'au moins un acide monocarboxylique aliphatique et d'au moins un alcool aliphatique saturé monohydroxylé. Solution organique d'un peroxydicarbonate de dialkyle dans ce solvant (S) et procédé de préparation d'un polymère dérivé d'un ou plusieurs monomères éthyléniquement insaturés halogénés.
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC CHEMISTRY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title Preparing organic solution of dialkyl peroxydicarbonate in organic solvent, comprises reacting, in medium with water, alkyl haloformate with inorganic peroxide, where organic solvent is esters derived from aliphatic monocarboxylic acid
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