Partly novel azole chemical embossing inhibitor cpds

A printing ink compsn. comprises a resin, a solvent and an inhibitor, the inhibitor being an azole cpd. of formula (I): where the A ring is benzenoid, naphthenoid or satd. cycloaliphatic and is opt. substd. with R'; R' = 1-4C alkyl; R = H or methyl; X = N or gp. of formula (i); R" = H...

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Hauptverfasser: HERWEH JOHN E, REMAR JOSEPH, WIKER ANTHONY L, SIDEMAN CARL E, SYNDER DONALD M
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creator HERWEH JOHN E
REMAR JOSEPH
WIKER ANTHONY L
SIDEMAN CARL E
SYNDER DONALD M
description A printing ink compsn. comprises a resin, a solvent and an inhibitor, the inhibitor being an azole cpd. of formula (I): where the A ring is benzenoid, naphthenoid or satd. cycloaliphatic and is opt. substd. with R'; R' = 1-4C alkyl; R = H or methyl; X = N or gp. of formula (i); R" = H or 1-4C alkyl; and Y, Z = organic moieties or when taken together with the N to which they are attached form an organic ring structure. The inhibitor has a 24 hr. room temp. isopropyl alcohol solubility of less than 5 wt.%. Triazole cpds. of formula (II) are new: where the A ring is benzenoid and R' = H or 2-4C alkyl; or the A ring is satd. cycloaliphatic or naphthenoid and R' = H or 1-4C alkyl; and R" = H or 1-4C alkyl; or the cpd. is selected from: 1,3-bis(5'-tolyltriazol-1'-yl methyl)urea; 1,5-bis-(benzotriazol-1'-yl methyl)biuret; 2,3,6-tris(benzotriazol-1'-yl methyl)-s-triazine; 2,4-bis(benzotriazol-1'-yl methyl) benzoguanamine, L1,L1-bis(benzotriazol-1-yl methyl) glycine; N-(benzotriazol-1-yl methyl)-4 '-carboxybenzene sulphonamide; 1(1',5'-naphthalene disulphonamido) methyl benzotriazole; 1(1',3'-benzene disulphonamido) methyl benzotriazole; 1-bis(benzotriazol-1'-yl methyl)-2-benzoyl hydroxide; bis(benzotriazol-1-yl methyl)amine; 1,3-bis-(5'-butyl benzotriazol-1'-yl methyl) urea; and N,N'-bis(benzimidazol-1-yl methyl) piperazine. Un inhibiteur de gaufrage chimique à base d'azole aromatique ou cycloaliphatique solide à haut point de fusion est essentiellement insoluble et inerte dans l'eau et/ou des mélanges d'eau et d'alcool. Ces azoles solides peuvent être facilement micronisés et dispersés dans des encres d'imprimerie à base aqueuse utilisables dans la production de surfaces de matières plastiques moussées texturées. Ces composés comprennent une classe générale de dérivés 1-N-substitués d'aminométhylaryl- ou cyclohexyl-triazole et imidazole. Certains des composés préférés sont des dérivés de triazoles difonctionnels symétriques ou ont une partie carboxy ou une partie sulfonyle attachée à un atome d'azote.
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The inhibitor has a 24 hr. room temp. isopropyl alcohol solubility of less than 5 wt.%. Triazole cpds. of formula (II) are new: where the A ring is benzenoid and R' = H or 2-4C alkyl; or the A ring is satd. cycloaliphatic or naphthenoid and R' = H or 1-4C alkyl; and R" = H or 1-4C alkyl; or the cpd. is selected from: 1,3-bis(5'-tolyltriazol-1'-yl methyl)urea; 1,5-bis-(benzotriazol-1'-yl methyl)biuret; 2,3,6-tris(benzotriazol-1'-yl methyl)-s-triazine; 2,4-bis(benzotriazol-1'-yl methyl) benzoguanamine, L1,L1-bis(benzotriazol-1-yl methyl) glycine; N-(benzotriazol-1-yl methyl)-4 '-carboxybenzene sulphonamide; 1(1',5'-naphthalene disulphonamido) methyl benzotriazole; 1(1',3'-benzene disulphonamido) methyl benzotriazole; 1-bis(benzotriazol-1'-yl methyl)-2-benzoyl hydroxide; bis(benzotriazol-1-yl methyl)amine; 1,3-bis-(5'-butyl benzotriazol-1'-yl methyl) urea; and N,N'-bis(benzimidazol-1-yl methyl) piperazine. Un inhibiteur de gaufrage chimique à base d'azole aromatique ou cycloaliphatique solide à haut point de fusion est essentiellement insoluble et inerte dans l'eau et/ou des mélanges d'eau et d'alcool. Ces azoles solides peuvent être facilement micronisés et dispersés dans des encres d'imprimerie à base aqueuse utilisables dans la production de surfaces de matières plastiques moussées texturées. Ces composés comprennent une classe générale de dérivés 1-N-substitués d'aminométhylaryl- ou cyclohexyl-triazole et imidazole. 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The inhibitor has a 24 hr. room temp. isopropyl alcohol solubility of less than 5 wt.%. Triazole cpds. of formula (II) are new: where the A ring is benzenoid and R' = H or 2-4C alkyl; or the A ring is satd. cycloaliphatic or naphthenoid and R' = H or 1-4C alkyl; and R" = H or 1-4C alkyl; or the cpd. is selected from: 1,3-bis(5'-tolyltriazol-1'-yl methyl)urea; 1,5-bis-(benzotriazol-1'-yl methyl)biuret; 2,3,6-tris(benzotriazol-1'-yl methyl)-s-triazine; 2,4-bis(benzotriazol-1'-yl methyl) benzoguanamine, L1,L1-bis(benzotriazol-1-yl methyl) glycine; N-(benzotriazol-1-yl methyl)-4 '-carboxybenzene sulphonamide; 1(1',5'-naphthalene disulphonamido) methyl benzotriazole; 1(1',3'-benzene disulphonamido) methyl benzotriazole; 1-bis(benzotriazol-1'-yl methyl)-2-benzoyl hydroxide; bis(benzotriazol-1-yl methyl)amine; 1,3-bis-(5'-butyl benzotriazol-1'-yl methyl) urea; and N,N'-bis(benzimidazol-1-yl methyl) piperazine. Un inhibiteur de gaufrage chimique à base d'azole aromatique ou cycloaliphatique solide à haut point de fusion est essentiellement insoluble et inerte dans l'eau et/ou des mélanges d'eau et d'alcool. Ces azoles solides peuvent être facilement micronisés et dispersés dans des encres d'imprimerie à base aqueuse utilisables dans la production de surfaces de matières plastiques moussées texturées. Ces composés comprennent une classe générale de dérivés 1-N-substitués d'aminométhylaryl- ou cyclohexyl-triazole et imidazole. 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The inhibitor has a 24 hr. room temp. isopropyl alcohol solubility of less than 5 wt.%. Triazole cpds. of formula (II) are new: where the A ring is benzenoid and R' = H or 2-4C alkyl; or the A ring is satd. cycloaliphatic or naphthenoid and R' = H or 1-4C alkyl; and R" = H or 1-4C alkyl; or the cpd. is selected from: 1,3-bis(5'-tolyltriazol-1'-yl methyl)urea; 1,5-bis-(benzotriazol-1'-yl methyl)biuret; 2,3,6-tris(benzotriazol-1'-yl methyl)-s-triazine; 2,4-bis(benzotriazol-1'-yl methyl) benzoguanamine, L1,L1-bis(benzotriazol-1-yl methyl) glycine; N-(benzotriazol-1-yl methyl)-4 '-carboxybenzene sulphonamide; 1(1',5'-naphthalene disulphonamido) methyl benzotriazole; 1(1',3'-benzene disulphonamido) methyl benzotriazole; 1-bis(benzotriazol-1'-yl methyl)-2-benzoyl hydroxide; bis(benzotriazol-1-yl methyl)amine; 1,3-bis-(5'-butyl benzotriazol-1'-yl methyl) urea; and N,N'-bis(benzimidazol-1-yl methyl) piperazine. Un inhibiteur de gaufrage chimique à base d'azole aromatique ou cycloaliphatique solide à haut point de fusion est essentiellement insoluble et inerte dans l'eau et/ou des mélanges d'eau et d'alcool. Ces azoles solides peuvent être facilement micronisés et dispersés dans des encres d'imprimerie à base aqueuse utilisables dans la production de surfaces de matières plastiques moussées texturées. Ces composés comprennent une classe générale de dérivés 1-N-substitués d'aminométhylaryl- ou cyclohexyl-triazole et imidazole. Certains des composés préférés sont des dérivés de triazoles difonctionnels symétriques ou ont une partie carboxy ou une partie sulfonyle attachée à un atome d'azote.</abstract><edition>6</edition><oa>free_for_read</oa></addata></record>
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subjects ADHESIVES
CHEMICAL PAINT OR INK REMOVERS
CHEMISTRY
COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS
CORRECTING FLUIDS
DYES
FILLING PASTES
HETEROCYCLIC COMPOUNDS
INKS
METALLURGY
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
NATURAL RESINS
ORGANIC CHEMISTRY
PAINTS
PASTES OR SOLIDS FOR COLOURING OR PRINTING
POLISHES
USE OF MATERIALS THEREFOR
WOODSTAINS
title Partly novel azole chemical embossing inhibitor cpds
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