PROCEDE DE FABRICATION DE (METH)ACRYLATE DE DIALKYLAMINOALKYLE
Process for the manufacture of dialkylaminoalkyl (meth)acrylates (I) of formula: H2C=C(R1)-C(O)-O-A-N(R2)(R3) R1 being a hydrogen atom or a methyl radical, A being a linear or branched alkyl radical containing 1 to 5 carbon atoms, and R2 and R3, which are identical or different from each other, are...
Gespeichert in:
| Hauptverfasser: | , , , |
|---|---|
| Format: | Patent |
| Sprache: | fre |
| Schlagworte: | |
| Online-Zugang: | Volltext bestellen |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | |
| container_start_page | |
| container_title | |
| container_volume | |
| creator | FRANCOIS DE CHAMPS JEAN-MICHEL PAUL CHARLES HAZAN PATRICE HURTEL |
| description | Process for the manufacture of dialkylaminoalkyl (meth)acrylates (I) of formula: H2C=C(R1)-C(O)-O-A-N(R2)(R3) R1 being a hydrogen atom or a methyl radical, A being a linear or branched alkyl radical containing 1 to 5 carbon atoms, and R2 and R3, which are identical or different from each other, are an alkyl radical containing 1 to 5 carbon atoms, or an aryl group, or R2 and R3 form a cyclic alkyl radical, in which ethyl (meth)acrylate is reacted with an aminoalcohol (II) of formula (R3)(R2)N-A-OH, A being a linear or branched alkyl radical containing 1 to 5 carbon atoms, in the presence of a polymerization inhibitor, at a temperature of between 20 DEG and 120 DEG C. and at a pressure equal to or lower than atmospheric pressure, in a molar ratio of ethyl (meth)acrylate to aminoalcohol (II) of between 1.5 and 5, in the presence of tetraethyl titanate, the azeotropic mixture of ethyl (meth)acrylate and ethanol is removed during the reaction, and the dialkylaminoalkyl (meth)acrylate (I) obtained is isolated at the end of reaction. |
| format | Patent |
| fullrecord | <record><control><sourceid>epo_EVB</sourceid><recordid>TN_cdi_epo_espacenet_FR2617840B1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>FR2617840B1</sourcerecordid><originalsourceid>FETCH-epo_espacenet_FR2617840B13</originalsourceid><addsrcrecordid>eNrjZLALCPJ3dnVxVQAiN0enIE9nxxBPfz8QV8PXNcRD09E5KNLHMQSswMXT0ccbyPP19PMHs1x5GFjTEnOKU3mhNDeDgptriLOHbmpBfnxqcUFicmpeakm8W5CRmaG5hYmBk6ExEUoA0jkpYA</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>patent</recordtype></control><display><type>patent</type><title>PROCEDE DE FABRICATION DE (METH)ACRYLATE DE DIALKYLAMINOALKYLE</title><source>esp@cenet</source><creator>FRANCOIS DE CHAMPS ; JEAN-MICHEL PAUL ; CHARLES HAZAN ; PATRICE HURTEL</creator><creatorcontrib>FRANCOIS DE CHAMPS ; JEAN-MICHEL PAUL ; CHARLES HAZAN ; PATRICE HURTEL</creatorcontrib><description>Process for the manufacture of dialkylaminoalkyl (meth)acrylates (I) of formula: H2C=C(R1)-C(O)-O-A-N(R2)(R3) R1 being a hydrogen atom or a methyl radical, A being a linear or branched alkyl radical containing 1 to 5 carbon atoms, and R2 and R3, which are identical or different from each other, are an alkyl radical containing 1 to 5 carbon atoms, or an aryl group, or R2 and R3 form a cyclic alkyl radical, in which ethyl (meth)acrylate is reacted with an aminoalcohol (II) of formula (R3)(R2)N-A-OH, A being a linear or branched alkyl radical containing 1 to 5 carbon atoms, in the presence of a polymerization inhibitor, at a temperature of between 20 DEG and 120 DEG C. and at a pressure equal to or lower than atmospheric pressure, in a molar ratio of ethyl (meth)acrylate to aminoalcohol (II) of between 1.5 and 5, in the presence of tetraethyl titanate, the azeotropic mixture of ethyl (meth)acrylate and ethanol is removed during the reaction, and the dialkylaminoalkyl (meth)acrylate (I) obtained is isolated at the end of reaction.</description><edition>4</edition><language>fre</language><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS ; APPARATUS THEREFOR ; CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY ; CHEMISTRY ; GENERAL METHODS OF ORGANIC CHEMISTRY ; HETEROCYCLIC COMPOUNDS ; METALLURGY ; ORGANIC CHEMISTRY ; PERFORMING OPERATIONS ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; THEIR RELEVANT APPARATUS ; TRANSPORTING</subject><creationdate>1989</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19890901&DB=EPODOC&CC=FR&NR=2617840B1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25543,76294</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19890901&DB=EPODOC&CC=FR&NR=2617840B1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>FRANCOIS DE CHAMPS</creatorcontrib><creatorcontrib>JEAN-MICHEL PAUL</creatorcontrib><creatorcontrib>CHARLES HAZAN</creatorcontrib><creatorcontrib>PATRICE HURTEL</creatorcontrib><title>PROCEDE DE FABRICATION DE (METH)ACRYLATE DE DIALKYLAMINOALKYLE</title><description>Process for the manufacture of dialkylaminoalkyl (meth)acrylates (I) of formula: H2C=C(R1)-C(O)-O-A-N(R2)(R3) R1 being a hydrogen atom or a methyl radical, A being a linear or branched alkyl radical containing 1 to 5 carbon atoms, and R2 and R3, which are identical or different from each other, are an alkyl radical containing 1 to 5 carbon atoms, or an aryl group, or R2 and R3 form a cyclic alkyl radical, in which ethyl (meth)acrylate is reacted with an aminoalcohol (II) of formula (R3)(R2)N-A-OH, A being a linear or branched alkyl radical containing 1 to 5 carbon atoms, in the presence of a polymerization inhibitor, at a temperature of between 20 DEG and 120 DEG C. and at a pressure equal to or lower than atmospheric pressure, in a molar ratio of ethyl (meth)acrylate to aminoalcohol (II) of between 1.5 and 5, in the presence of tetraethyl titanate, the azeotropic mixture of ethyl (meth)acrylate and ethanol is removed during the reaction, and the dialkylaminoalkyl (meth)acrylate (I) obtained is isolated at the end of reaction.</description><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS</subject><subject>APPARATUS THEREFOR</subject><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</subject><subject>CHEMISTRY</subject><subject>GENERAL METHODS OF ORGANIC CHEMISTRY</subject><subject>HETEROCYCLIC COMPOUNDS</subject><subject>METALLURGY</subject><subject>ORGANIC CHEMISTRY</subject><subject>PERFORMING OPERATIONS</subject><subject>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</subject><subject>THEIR RELEVANT APPARATUS</subject><subject>TRANSPORTING</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>1989</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZLALCPJ3dnVxVQAiN0enIE9nxxBPfz8QV8PXNcRD09E5KNLHMQSswMXT0ccbyPP19PMHs1x5GFjTEnOKU3mhNDeDgptriLOHbmpBfnxqcUFicmpeakm8W5CRmaG5hYmBk6ExEUoA0jkpYA</recordid><startdate>19890901</startdate><enddate>19890901</enddate><creator>FRANCOIS DE CHAMPS</creator><creator>JEAN-MICHEL PAUL</creator><creator>CHARLES HAZAN</creator><creator>PATRICE HURTEL</creator><scope>EVB</scope></search><sort><creationdate>19890901</creationdate><title>PROCEDE DE FABRICATION DE (METH)ACRYLATE DE DIALKYLAMINOALKYLE</title><author>FRANCOIS DE CHAMPS ; JEAN-MICHEL PAUL ; CHARLES HAZAN ; PATRICE HURTEL</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_FR2617840B13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>fre</language><creationdate>1989</creationdate><topic>ACYCLIC OR CARBOCYCLIC COMPOUNDS</topic><topic>APPARATUS THEREFOR</topic><topic>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</topic><topic>CHEMISTRY</topic><topic>GENERAL METHODS OF ORGANIC CHEMISTRY</topic><topic>HETEROCYCLIC COMPOUNDS</topic><topic>METALLURGY</topic><topic>ORGANIC CHEMISTRY</topic><topic>PERFORMING OPERATIONS</topic><topic>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</topic><topic>THEIR RELEVANT APPARATUS</topic><topic>TRANSPORTING</topic><toplevel>online_resources</toplevel><creatorcontrib>FRANCOIS DE CHAMPS</creatorcontrib><creatorcontrib>JEAN-MICHEL PAUL</creatorcontrib><creatorcontrib>CHARLES HAZAN</creatorcontrib><creatorcontrib>PATRICE HURTEL</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>FRANCOIS DE CHAMPS</au><au>JEAN-MICHEL PAUL</au><au>CHARLES HAZAN</au><au>PATRICE HURTEL</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>PROCEDE DE FABRICATION DE (METH)ACRYLATE DE DIALKYLAMINOALKYLE</title><date>1989-09-01</date><risdate>1989</risdate><abstract>Process for the manufacture of dialkylaminoalkyl (meth)acrylates (I) of formula: H2C=C(R1)-C(O)-O-A-N(R2)(R3) R1 being a hydrogen atom or a methyl radical, A being a linear or branched alkyl radical containing 1 to 5 carbon atoms, and R2 and R3, which are identical or different from each other, are an alkyl radical containing 1 to 5 carbon atoms, or an aryl group, or R2 and R3 form a cyclic alkyl radical, in which ethyl (meth)acrylate is reacted with an aminoalcohol (II) of formula (R3)(R2)N-A-OH, A being a linear or branched alkyl radical containing 1 to 5 carbon atoms, in the presence of a polymerization inhibitor, at a temperature of between 20 DEG and 120 DEG C. and at a pressure equal to or lower than atmospheric pressure, in a molar ratio of ethyl (meth)acrylate to aminoalcohol (II) of between 1.5 and 5, in the presence of tetraethyl titanate, the azeotropic mixture of ethyl (meth)acrylate and ethanol is removed during the reaction, and the dialkylaminoalkyl (meth)acrylate (I) obtained is isolated at the end of reaction.</abstract><edition>4</edition><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext_linktorsrc |
| identifier | |
| ispartof | |
| issn | |
| language | fre |
| recordid | cdi_epo_espacenet_FR2617840B1 |
| source | esp@cenet |
| subjects | ACYCLIC OR CARBOCYCLIC COMPOUNDS APPARATUS THEREFOR CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY GENERAL METHODS OF ORGANIC CHEMISTRY HETEROCYCLIC COMPOUNDS METALLURGY ORGANIC CHEMISTRY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR RELEVANT APPARATUS TRANSPORTING |
| title | PROCEDE DE FABRICATION DE (METH)ACRYLATE DE DIALKYLAMINOALKYLE |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-22T05%3A53%3A13IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-epo_EVB&rft_val_fmt=info:ofi/fmt:kev:mtx:patent&rft.genre=patent&rft.au=FRANCOIS%20DE%20CHAMPS&rft.date=1989-09-01&rft_id=info:doi/&rft_dat=%3Cepo_EVB%3EFR2617840B1%3C/epo_EVB%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |