PROCEDE DE PREPARATION D'ACIDE ACETIQUE EN PRESENCE D'HYDROGENE

L'INVENTION CONCERNE LA PREPARATION DE L'ACIDE ACETIQUE.ELLE SE RAPPORTE A UN PROCEDE DE PREPARATION D'ACIDE ACETIQUE PAR REACTION DE METHANOL AVEC DE L'OXYDE DE CARBONE, EN PRESENCE D'UN CATALYSEUR A BASE DE MOLYBDENE ET DE NICKEL OU DE TUNGSTENE ET DE NICKEL, EN PRESENCE D...

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1. Verfasser: MITCHELL BECKER ET HOWARD MARTIN SACHS
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description L'INVENTION CONCERNE LA PREPARATION DE L'ACIDE ACETIQUE.ELLE SE RAPPORTE A UN PROCEDE DE PREPARATION D'ACIDE ACETIQUE PAR REACTION DE METHANOL AVEC DE L'OXYDE DE CARBONE, EN PRESENCE D'UN CATALYSEUR A BASE DE MOLYBDENE ET DE NICKEL OU DE TUNGSTENE ET DE NICKEL, EN PRESENCE D'UN IODURE ET EN PRESENCE D'UN PROMOTEUR ORGANIQUE DU PHOSPHORE OU DE L'AZOTE. SELON L'INVENTION, LA REACTION EST EXECUTEE EN PRESENCE D'HYDROGENE, LE RAPPORT DES PRESSIONS PARTIELLES DE L'HYDROGENE ET DE L'OXYDE DE CARBONE ETANT COMPRIS ENTRE 0,05 ET 0,4 PENDANT LA REACTION.APPLICATION A LA FABRICATION D'ACIDE ACETIQUE QUI CONSTITUE UN PRODUIT INDUSTRIEL IMPORTANT. Acetic acid is produced by reacting methanol with carbon monoxide in the presence of hydrogen, in the presence of a catalyst comprising a molybdenum- nickel or a tungsten-nickel co- catalyst component, in the presence of an iodide, and in the presence of a promoter comprising an organo- phosphorus compound or an organo- nitrogen compound, the ratio of the partial pressure of hydrogen to the partial pressure of carbon monoxide in the reaction zone being 0.05 to 0.4.
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
APPARATUS THEREFOR
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title PROCEDE DE PREPARATION D'ACIDE ACETIQUE EN PRESENCE D'HYDROGENE
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