Thiazolyl- and thiazolinyl-amide(s) of phosphorus acids - useful as insecticides, acaricides and herbicides

Thiazole derivs. of formula (I) are new: (where R is 1-4C alkyl, haloalkyl or alkoxy; R1 is 1-4C alkoxy, phenoxy, halophenoxy, 1-4C alkylamino, dialkylamino or 2-thiazolinylamino; X is O, S; Z is CH2CH2 or CH=CH). (I) are useful as (a) insecticides and acaricides, eg with higher activity than chloro...

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1. Verfasser: NIKOLAI NIKOLAEVICH MELNIKOV, ARTHUR FELIXOVICH GRAPOV, LJUDMILA VLADIMIROVNA RAZVODOVSKAYA, PETR VASILIEVICH POPOV, AELITA SERGEEVNA SEDYKH, GALINA KONSTANTINOVNA SHAPOVALOVA, GALINA MIKHAILOVNA ABELENTSEVA, TAMARA ALEXANDROVNA SIFOROVA, TATYANA ANDREEVNA NIKOLAEVA, VALENTINA VASILIEVNA GALITSINA, LEONID DMITRIEVICH STONOV ET LJUDMILA ALEXANDROVNA BAKUMENK
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Sprache:eng ; fre
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Zusammenfassung:Thiazole derivs. of formula (I) are new: (where R is 1-4C alkyl, haloalkyl or alkoxy; R1 is 1-4C alkoxy, phenoxy, halophenoxy, 1-4C alkylamino, dialkylamino or 2-thiazolinylamino; X is O, S; Z is CH2CH2 or CH=CH). (I) are useful as (a) insecticides and acaricides, eg with higher activity than chlorophos against Colorado beetle and higher activity than halekron and menason against red spider; (b) herbicides, e.g. active against millet and oats. In an example, O-phenyl N-(2-thiazolinyl)methylphosphonamidate, is prepd. from O-phenyl methylphosphonyl chloride and 2-aminothiazoline. L'invention a pour objet des thiazolinyl (ou thiazoly)amides d'acides du phosphore et des compositions pesticides et herbicides les contenant Les composés de l'invention répondent à la formule :