METODO DE PRODUCCION DE ACIDO DICARBOXILICO USANDO COCATALIZADOR DE CERIO

A method for oxidizing a dimethyl aromatic compound includes reacting the dimethyl aromatic compound and an oxidant in the presence of a catalyst and a co-catalyst in a solvent to produce a reaction product comprising an aromatic dicarboxylic acid. The catalyst comprises cobalt, manganese, and bromi...

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Hauptverfasser: DAS, Debasish, HASHMI, Syed Azhar, SUBRAMANIAN, Selvakumar, PATHATH, Prasanna Kumar, JANA, Suman Kumar, SATHU, Naveen K
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creator DAS, Debasish
HASHMI, Syed Azhar
SUBRAMANIAN, Selvakumar
PATHATH, Prasanna Kumar
JANA, Suman Kumar
SATHU, Naveen K
description A method for oxidizing a dimethyl aromatic compound includes reacting the dimethyl aromatic compound and an oxidant in the presence of a catalyst and a co-catalyst in a solvent to produce a reaction product comprising an aromatic dicarboxylic acid. The catalyst comprises cobalt, manganese, and bromine. A weight ratio of cobalt to manganese is equal to or greater than 1:1. The co-catalyst comprises at least one of cerium or iron. The co-catalyst is present in an amount in a range of 10 ppm to 200 ppm, based on a total weight of the dimethyl aromatic compound and the solvent. The aromatic dicarboxylic acid is present in the reaction product in an amount equal to or greater than 70 wt.%, or equal to or greater than 90 wt.%, based on a total weight of solids in the reaction product.
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title METODO DE PRODUCCION DE ACIDO DICARBOXILICO USANDO COCATALIZADOR DE CERIO
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