METHOD FOR ON-SITE GLYOXYLATION OF POLYACRYLAMIDE

Method for on-site glyoxylation of polyacrylamide in paper mill, board mill or the like is disclosed. Discontinuous batch glyoxylation reaction of aqueous reaction mixture is performed. The method comprises forming or obtaining the aqueous reaction mixture having a start viscosity and comprising pol...

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Hauptverfasser: KEMPAS, Tomi, KARPPI, Asko, HIETANIEMI, Matti, KONN, Jonas, VANZETTI, Giorgio
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Sprache:eng ; fre ; ger
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creator KEMPAS, Tomi
KARPPI, Asko
HIETANIEMI, Matti
KONN, Jonas
VANZETTI, Giorgio
description Method for on-site glyoxylation of polyacrylamide in paper mill, board mill or the like is disclosed. Discontinuous batch glyoxylation reaction of aqueous reaction mixture is performed. The method comprises forming or obtaining the aqueous reaction mixture having a start viscosity and comprising polyacrylamide base polymer having weight average molecular weight of 30 000-300 000 g/mol and glyoxal. Concentration of the polyacrylamide base polymer in the reaction mixture is 1.5-8% above a Critical Concentration of the polyacrylamide base polymer. A feed of an alkali is added to the reaction mixture while measuring viscosity of the reaction mixture and/or a process variable related to the viscosity of the reaction mixture and the on-site glyoxylation reaction of polyacrylamide base polymer in the reaction mixture is allowed to proceed. When a predetermined end viscosity value is attained the feed of alkali is ended and acid is added to the reaction mixture.
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
IMPREGNATING OR COATING OF PAPER
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
PAPER NOT OTHERWISE PROVIDED FOR
PAPER-MAKING
PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D
PRODUCTION OF CELLULOSE
PULP COMPOSITIONS
TEXTILES
THEIR PREPARATION OR CHEMICAL WORKING-UP
TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G
title METHOD FOR ON-SITE GLYOXYLATION OF POLYACRYLAMIDE
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