CATALYST SUPPORT STRUCTURES AND METHODS
A method of preparing a catalyst support structure for use in a catalytic reaction. According to the method, a mixed metal oxide compound which defines a crystal lattice is synthesized. Cations of at least one catalytic promoter element are dispersed within the compound and incorporated into the cry...
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creator | CLAEYS, Michael Christian Maximilian FISCHER, Nico Frederik |
description | A method of preparing a catalyst support structure for use in a catalytic reaction. According to the method, a mixed metal oxide compound which defines a crystal lattice is synthesized. Cations of at least one catalytic promoter element are dispersed within the compound and incorporated into the crystal lattice. The conditions of synthesis are preselected to inhibit destabilization of the catalyst support structure such that the structure remains stable against collapse and exsolution under reaction conditions associated with the catalytic reaction. The metal oxide compound may comprise an oxidic perovskite having the formula A(1-x)A′(x)B(1-y)B′yO3 wherein A and B represent metal cations and A′ and B′ represent cations of the promoter element or elements. Also provided is a catalyst support structure having cations of a promoter element incorporated into its crystal lattice. The support structure is stable against collapse and exsolution under reaction conditions. |
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According to the method, a mixed metal oxide compound which defines a crystal lattice is synthesized. Cations of at least one catalytic promoter element are dispersed within the compound and incorporated into the crystal lattice. The conditions of synthesis are preselected to inhibit destabilization of the catalyst support structure such that the structure remains stable against collapse and exsolution under reaction conditions associated with the catalytic reaction. The metal oxide compound may comprise an oxidic perovskite having the formula A(1-x)A′(x)B(1-y)B′yO3 wherein A and B represent metal cations and A′ and B′ represent cations of the promoter element or elements. Also provided is a catalyst support structure having cations of a promoter element incorporated into its crystal lattice. 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According to the method, a mixed metal oxide compound which defines a crystal lattice is synthesized. Cations of at least one catalytic promoter element are dispersed within the compound and incorporated into the crystal lattice. The conditions of synthesis are preselected to inhibit destabilization of the catalyst support structure such that the structure remains stable against collapse and exsolution under reaction conditions associated with the catalytic reaction. The metal oxide compound may comprise an oxidic perovskite having the formula A(1-x)A′(x)B(1-y)B′yO3 wherein A and B represent metal cations and A′ and B′ represent cations of the promoter element or elements. Also provided is a catalyst support structure having cations of a promoter element incorporated into its crystal lattice. 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According to the method, a mixed metal oxide compound which defines a crystal lattice is synthesized. Cations of at least one catalytic promoter element are dispersed within the compound and incorporated into the crystal lattice. The conditions of synthesis are preselected to inhibit destabilization of the catalyst support structure such that the structure remains stable against collapse and exsolution under reaction conditions associated with the catalytic reaction. The metal oxide compound may comprise an oxidic perovskite having the formula A(1-x)A′(x)B(1-y)B′yO3 wherein A and B represent metal cations and A′ and B′ represent cations of the promoter element or elements. Also provided is a catalyst support structure having cations of a promoter element incorporated into its crystal lattice. The support structure is stable against collapse and exsolution under reaction conditions.</abstract><oa>free_for_read</oa></addata></record> |
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subjects | ACYCLIC OR CARBOCYCLIC COMPOUNDS CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY CRACKING HYDROCARBON OILS FUELS LUBRICANTS METALLURGY MINERAL WAXES ORGANIC CHEMISTRY PEAT PERFORMING OPERATIONS PETROLEUM, GAS OR COKE INDUSTRIES PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS REFORMING OF NAPHTHA TECHNICAL GASES CONTAINING CARBON MONOXIDE THEIR RELEVANT APPARATUS TRANSPORTING |
title | CATALYST SUPPORT STRUCTURES AND METHODS |
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