LITHIUM NICKEL-BASED COMPOSITE OXIDE AS A POSITIVE ELECTRODE ACTIVE MATERIAL FOR RECHARGEABLE LITHIUM-ION BATTERIES

Positive electrode active material for solid-state batteries, comprising Li, M′, and oxygen, wherein M′ comprises:Ni in a content x between 70.0 mol % and 95.0 mol %,Co in a content y between 0.0 mol % and 40.0 mol %,Mn in a content z between 0.0 mol % and 40.0 mol %,dopants in a content a between 0...

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Hauptverfasser: PAULSEN, Jens Martin, KUMAKURA, Shinichi, KANG, JiHoon, YANG, TaeHyeon, HYOUNG, JooEun, YANG, HyeJeong, OH, JinDoo
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creator PAULSEN, Jens Martin
KUMAKURA, Shinichi
KANG, JiHoon
YANG, TaeHyeon
HYOUNG, JooEun
YANG, HyeJeong
OH, JinDoo
description Positive electrode active material for solid-state batteries, comprising Li, M′, and oxygen, wherein M′ comprises:Ni in a content x between 70.0 mol % and 95.0 mol %,Co in a content y between 0.0 mol % and 40.0 mol %,Mn in a content z between 0.0 mol % and 40.0 mol %,dopants in a content a between 0.0 mol % and 2.0 mol %,Zr in a content b between 0.1 mol % and 5.0 mol %,wherein x+y+z+a+b is 100.0 mol %,whereinZrA=b(x+y+z+b),wherein the positive electrode active material has a Zr content ZrB is expressed as molar fraction compared to the sum of molar fractions of Co, Mn, Ni, and Zr all as measured by XPS analysis,wherein ZrB/ZrA>50.0,the positive electrode active material comprising secondary particles having a plurality of primary particles,said primary particles having an average diameter of at least 250 nm.
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subjects BASIC ELECTRIC ELEMENTS
CHEMISTRY
COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F
ELECTRICITY
INORGANIC CHEMISTRY
METALLURGY
PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY
title LITHIUM NICKEL-BASED COMPOSITE OXIDE AS A POSITIVE ELECTRODE ACTIVE MATERIAL FOR RECHARGEABLE LITHIUM-ION BATTERIES
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