MODIFIED BETA ZEOLITE, CATALYTIC CRACKING CATALYST AS WELL AS PREPARATION METHOD THEREFOR AND APPLICATION THEREOF
The present invention relates to a modified β zeolite, a catalytic cracking catalyst, and their preparation method and application. The modified β zeolite comprises 0.5-15 wt% of an IVB group metal element in terms of oxide on the dry basis weight of the modified β zeolite. The number of medium stro...
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creator | TANG, Liwen YAN, Jiasong YU, Shanqing ZHANG, Jiexiao |
description | The present invention relates to a modified β zeolite, a catalytic cracking catalyst, and their preparation method and application. The modified β zeolite comprises 0.5-15 wt% of an IVB group metal element in terms of oxide on the dry basis weight of the modified β zeolite. The number of medium strong acid centers of the modified β zeolite accounts for 30-60% of the total acid amount, the number of strong acid centers accounts for 5-25% of the total acid amount, and the ratio of B acid to L acid is 0.8 or more. The ratio of the weight content of the IVB group metal element in the modified β zeolite body phase to the weight content of the IVB group metal element on the surface is 0.1-0.8. The catalytic cracking catalyst containing the modified β zeolite of the present invention has good selectivity and yield of C4 olefin. |
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The modified β zeolite comprises 0.5-15 wt% of an IVB group metal element in terms of oxide on the dry basis weight of the modified β zeolite. The number of medium strong acid centers of the modified β zeolite accounts for 30-60% of the total acid amount, the number of strong acid centers accounts for 5-25% of the total acid amount, and the ratio of B acid to L acid is 0.8 or more. The ratio of the weight content of the IVB group metal element in the modified β zeolite body phase to the weight content of the IVB group metal element on the surface is 0.1-0.8. 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subjects | CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY COMPOUNDS THEREOF CRACKING HYDROCARBON OILS FUELS INORGANIC CHEMISTRY LUBRICANTS METALLURGY MINERAL WAXES NON-METALLIC ELEMENTS PEAT PERFORMING OPERATIONS PETROLEUM, GAS OR COKE INDUSTRIES PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS REFORMING OF NAPHTHA TECHNICAL GASES CONTAINING CARBON MONOXIDE THEIR RELEVANT APPARATUS TRANSPORTING |
title | MODIFIED BETA ZEOLITE, CATALYTIC CRACKING CATALYST AS WELL AS PREPARATION METHOD THEREFOR AND APPLICATION THEREOF |
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