MODIFIED BETA ZEOLITE, CATALYTIC CRACKING CATALYST AS WELL AS PREPARATION METHOD THEREFOR AND APPLICATION THEREOF

The present invention relates to a modified β zeolite, a catalytic cracking catalyst, and their preparation method and application. The modified β zeolite comprises 0.5-15 wt% of an IVB group metal element in terms of oxide on the dry basis weight of the modified β zeolite. The number of medium stro...

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Hauptverfasser: TANG, Liwen, YAN, Jiasong, YU, Shanqing, ZHANG, Jiexiao
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creator TANG, Liwen
YAN, Jiasong
YU, Shanqing
ZHANG, Jiexiao
description The present invention relates to a modified β zeolite, a catalytic cracking catalyst, and their preparation method and application. The modified β zeolite comprises 0.5-15 wt% of an IVB group metal element in terms of oxide on the dry basis weight of the modified β zeolite. The number of medium strong acid centers of the modified β zeolite accounts for 30-60% of the total acid amount, the number of strong acid centers accounts for 5-25% of the total acid amount, and the ratio of B acid to L acid is 0.8 or more. The ratio of the weight content of the IVB group metal element in the modified β zeolite body phase to the weight content of the IVB group metal element on the surface is 0.1-0.8. The catalytic cracking catalyst containing the modified β zeolite of the present invention has good selectivity and yield of C4 olefin.
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The modified β zeolite comprises 0.5-15 wt% of an IVB group metal element in terms of oxide on the dry basis weight of the modified β zeolite. The number of medium strong acid centers of the modified β zeolite accounts for 30-60% of the total acid amount, the number of strong acid centers accounts for 5-25% of the total acid amount, and the ratio of B acid to L acid is 0.8 or more. The ratio of the weight content of the IVB group metal element in the modified β zeolite body phase to the weight content of the IVB group metal element on the surface is 0.1-0.8. 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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
COMPOUNDS THEREOF
CRACKING HYDROCARBON OILS
FUELS
INORGANIC CHEMISTRY
LUBRICANTS
METALLURGY
MINERAL WAXES
NON-METALLIC ELEMENTS
PEAT
PERFORMING OPERATIONS
PETROLEUM, GAS OR COKE INDUSTRIES
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION
RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES
REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS
REFORMING OF NAPHTHA
TECHNICAL GASES CONTAINING CARBON MONOXIDE
THEIR RELEVANT APPARATUS
TRANSPORTING
title MODIFIED BETA ZEOLITE, CATALYTIC CRACKING CATALYST AS WELL AS PREPARATION METHOD THEREFOR AND APPLICATION THEREOF
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