POLYOXOMETALATES COMPRISING NOBLE METALS AND CARBOXYLATE-BASED CAPPING GROUPS AND METAL CLUSTERS THEREOF

The invention relates to polyoxometalates represented by the formula (An)m+[M′M12Oy(RCOO)zHq]m− or solvates thereof, corresponding supported polyoxometalates, and processes for their preparation, as well as corresponding metal clusters, optionally in the form of a dispersion in a liquid carrier medi...

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Bibliographische Detailangaben
Hauptverfasser: MA, Tian, LIN, Zhengguo, YANG, Peng, AYASS, W. Wassim, KORTZ, Ulrich
Format: Patent
Sprache:eng ; fre ; ger
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Zusammenfassung:The invention relates to polyoxometalates represented by the formula (An)m+[M′M12Oy(RCOO)zHq]m− or solvates thereof, corresponding supported polyoxometalates, and processes for their preparation, as well as corresponding metal clusters, optionally in the form of a dispersion in a liquid carrier medium or immobilized on a solid support, and processes for their preparation, as well as their use in reductive conversion of organic substrate.