METHOD FOR PRODUCING IRON COMPLEXES AND METHOD FOR PRODUCING ESTER COMPOUNDS USING IRON COMPLEX

The invention provides a simple and high-yield method for producing an iron dinuclear complex which has, in its molecule, a structure having two iron atoms bonded to each other via one oxygen atom and a ligand structure containing a Schiff base; an ester compound production method which can produce...

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Hauptverfasser: OKADA, Kimio, HOSOKI, Tomoya, TAKAHATA, Yusuke, KAJIYASHIKI, Tsuyoshi
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creator OKADA, Kimio
HOSOKI, Tomoya
TAKAHATA, Yusuke
KAJIYASHIKI, Tsuyoshi
description The invention provides a simple and high-yield method for producing an iron dinuclear complex which has, in its molecule, a structure having two iron atoms bonded to each other via one oxygen atom and a ligand structure containing a Schiff base; an ester compound production method which can produce an ester compound with a high yield by the transesterification of an alcohol compound with a carboxylate ester even in the case where the raw material alcohol has a tertiary hydroxyl group which is usually difficult to esterify by transesterification; and an ester compound production method which can produce by transesterification catalyzed by an iron complex a wholly esterified compound, i.e., can esterify all the hydroxyl groups, with a high yield even in the case where the alcohol compound has a plurality of hydroxyl groups. A method for producing an iron complex represented by the general formula (4) or (5) includes a step (I-1) of preparing a precursor solution by mixing in the presence of water an iron salt and a compound represented by the general formula (1), and a step (I-2) of mixing the precursor solution with a compound represented by the general formula (2) or (3). A method for producing an ester compound includes a step (IV) of transesterifying a carboxylate ester with an alcohol compound in the presence of the iron complex described above.
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
title METHOD FOR PRODUCING IRON COMPLEXES AND METHOD FOR PRODUCING ESTER COMPOUNDS USING IRON COMPLEX
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