TURBULENT MESOPHASE PITCH PROCESS AND PRODUCTS

A process for producing mesophase pitch using a long tube reactor is disclosed. An aromatic rich feed, preferably a petroleum pitch having a softening point above 100°C, is preheated to a temperature above its softening point and mixed with a vapor, preferably steam, in a long tubular reactor under...

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LEE, Donald, M
description A process for producing mesophase pitch using a long tube reactor is disclosed. An aromatic rich feed, preferably a petroleum pitch having a softening point above 100°C, is preheated to a temperature above its softening point and mixed with a vapor, preferably steam, in a long tubular reactor under intense mixing conditions, preferably fully developed turbulent flow such as mist annular flow, with a residence time at least an order of magnitude less than prior art processes and preferably less than 10 seconds. Preferably the reactor is heated by electric resistance or induction heating or by immersion in a heated fluid or in a fired heater. Mesophase pitch with a high coking value and a surprisingly low quinolone insoluble content is produced. The byproducts of thermal polymerization and thermal dealkylation have less than 50 % as much olefin and diene content as compared to similar byproducts from prior art processes.
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An aromatic rich feed, preferably a petroleum pitch having a softening point above 100°C, is preheated to a temperature above its softening point and mixed with a vapor, preferably steam, in a long tubular reactor under intense mixing conditions, preferably fully developed turbulent flow such as mist annular flow, with a residence time at least an order of magnitude less than prior art processes and preferably less than 10 seconds. Preferably the reactor is heated by electric resistance or induction heating or by immersion in a heated fluid or in a fired heater. Mesophase pitch with a high coking value and a surprisingly low quinolone insoluble content is produced. 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An aromatic rich feed, preferably a petroleum pitch having a softening point above 100°C, is preheated to a temperature above its softening point and mixed with a vapor, preferably steam, in a long tubular reactor under intense mixing conditions, preferably fully developed turbulent flow such as mist annular flow, with a residence time at least an order of magnitude less than prior art processes and preferably less than 10 seconds. Preferably the reactor is heated by electric resistance or induction heating or by immersion in a heated fluid or in a fired heater. Mesophase pitch with a high coking value and a surprisingly low quinolone insoluble content is produced. The byproducts of thermal polymerization and thermal dealkylation have less than 50 % as much olefin and diene content as compared to similar byproducts from prior art processes.</abstract><oa>free_for_read</oa></addata></record>
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
FUELS
LUBRICANTS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
PEAT
PETROLEUM, GAS OR COKE INDUSTRIES
PYROLIGNEOUS ACID
TECHNICAL GASES CONTAINING CARBON MONOXIDE
THEIR PREPARATION OR CHEMICAL WORKING-UP
WORKING-UP PITCH, ASPHALT, BITUMEN, TAR
title TURBULENT MESOPHASE PITCH PROCESS AND PRODUCTS
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