CATALYST FOR PREPARING CHLORINE BY HYDROGEN CHLORIDE OXIDATION, AND PREPARATION METHOD AND APPLICATION THEREOF

A catalyst for preparing chlorine gas by hydrogen chloride oxidation, comprising the following components calculated according to mass content based on the total weight of the catalyst: 0.5-20 wt% copper; 2-10 wt% manganese; 0.05-2 wt% boron; 0.01-3 wt% chromium; 0.1-10 wt% rare earth metal; 0.1-10...

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Hauptverfasser: ZHANG, Hongke, YAO, Yu, XU, Dan, ZHAO, Dongke, ZAI, Zhangwei, XU, Yanlong, YANG, Jingjing, HUA, Weiqi, ZHOU, Bo, DING, Jiansheng
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creator ZHANG, Hongke
YAO, Yu
XU, Dan
ZHAO, Dongke
ZAI, Zhangwei
XU, Yanlong
YANG, Jingjing
HUA, Weiqi
ZHOU, Bo
DING, Jiansheng
description A catalyst for preparing chlorine gas by hydrogen chloride oxidation, comprising the following components calculated according to mass content based on the total weight of the catalyst: 0.5-20 wt% copper; 2-10 wt% manganese; 0.05-2 wt% boron; 0.01-3 wt% chromium; 0.1-10 wt% rare earth metal; 0.1-10 wt% potassium; and 3-15 wt% titanium; also comprising 0.02-1.1 wt% phosphorus; and 0.03-1.9 wt% iron; the carrier content is 55-90 wt%. In the case of a fluidized bed reactor, the present catalyst can achieve a one-way hydrogen chloride conversion rate of 80 - 85%. Almost all of the 0-1000 mg/kg of chlorinated benzene contained in hydrogen chloride gas can be converted into CO 2 and H 2 O without generating polychlorinated benzene.
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In the case of a fluidized bed reactor, the present catalyst can achieve a one-way hydrogen chloride conversion rate of 80 - 85%. 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In the case of a fluidized bed reactor, the present catalyst can achieve a one-way hydrogen chloride conversion rate of 80 - 85%. Almost all of the 0-1000 mg/kg of chlorinated benzene contained in hydrogen chloride gas can be converted into CO 2 and H 2 O without generating polychlorinated benzene.</abstract><oa>free_for_read</oa></addata></record>
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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
COMPOUNDS THEREOF
INORGANIC CHEMISTRY
METALLURGY
NON-METALLIC ELEMENTS
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title CATALYST FOR PREPARING CHLORINE BY HYDROGEN CHLORIDE OXIDATION, AND PREPARATION METHOD AND APPLICATION THEREOF
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