METHOD FOR PRODUCING HYDROFLUOROOLEFIN
There is provided a method of producing HFO with which diluent gas is easily separated even at a low boiling point and which has excellent productivity. A method of producing HFO includes: a reaction step of converting, in the presence of fluorine-containing compound in a gaseous state having a boil...
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creator | TOMIYORI, Yusuke NAKAMURA, Masahiko |
description | There is provided a method of producing HFO with which diluent gas is easily separated even at a low boiling point and which has excellent productivity. A method of producing HFO includes: a reaction step of converting, in the presence of fluorine-containing compound in a gaseous state having a boiling point higher than a boiling point of HFO represented by the following formula (2), HFC represented by the following formula (1) into the HFO represented by the following formula (2), to obtain a first gas composition containing the HFO and the fluorine-containing solvent, CR 1 R 2 X 1 CR 3 R 4 X 2 (1), CR 1 R 2 = CR 3 R 4 (2), where in the formula (1) and the formula (2), R 1 to R 3 are H or F, R 4 is H, F, CH 3 , CH 2 F, CHF 2 or CF 3 , the total number of fluorine atoms of R 1 to R 4 is one or more, and the total number of hydrogen atoms of R 1 to R 4 is one or more, one of X 1 and X 2 is H, and the other of X 1 and X 2 is F; and a separation step of separating the fluorine-containing solvent from the first gas composition to obtain a second gas composition containing the HFO. |
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A method of producing HFO includes: a reaction step of converting, in the presence of fluorine-containing compound in a gaseous state having a boiling point higher than a boiling point of HFO represented by the following formula (2), HFC represented by the following formula (1) into the HFO represented by the following formula (2), to obtain a first gas composition containing the HFO and the fluorine-containing solvent, CR 1 R 2 X 1 CR 3 R 4 X 2 (1), CR 1 R 2 = CR 3 R 4 (2), where in the formula (1) and the formula (2), R 1 to R 3 are H or F, R 4 is H, F, CH 3 , CH 2 F, CHF 2 or CF 3 , the total number of fluorine atoms of R 1 to R 4 is one or more, and the total number of hydrogen atoms of R 1 to R 4 is one or more, one of X 1 and X 2 is H, and the other of X 1 and X 2 is F; and a separation step of separating the fluorine-containing solvent from the first gas composition to obtain a second gas composition containing the HFO.</description><language>eng ; fre ; ger</language><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS ; APPARATUS THEREFOR ; CHEMISTRY ; GENERAL METHODS OF ORGANIC CHEMISTRY ; METALLURGY ; ORGANIC CHEMISTRY</subject><creationdate>2018</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20181024&DB=EPODOC&CC=EP&NR=3392229A1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,309,781,886,25569,76552</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20181024&DB=EPODOC&CC=EP&NR=3392229A1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>TOMIYORI, Yusuke</creatorcontrib><creatorcontrib>NAKAMURA, Masahiko</creatorcontrib><title>METHOD FOR PRODUCING HYDROFLUOROOLEFIN</title><description>There is provided a method of producing HFO with which diluent gas is easily separated even at a low boiling point and which has excellent productivity. A method of producing HFO includes: a reaction step of converting, in the presence of fluorine-containing compound in a gaseous state having a boiling point higher than a boiling point of HFO represented by the following formula (2), HFC represented by the following formula (1) into the HFO represented by the following formula (2), to obtain a first gas composition containing the HFO and the fluorine-containing solvent, CR 1 R 2 X 1 CR 3 R 4 X 2 (1), CR 1 R 2 = CR 3 R 4 (2), where in the formula (1) and the formula (2), R 1 to R 3 are H or F, R 4 is H, F, CH 3 , CH 2 F, CHF 2 or CF 3 , the total number of fluorine atoms of R 1 to R 4 is one or more, and the total number of hydrogen atoms of R 1 to R 4 is one or more, one of X 1 and X 2 is H, and the other of X 1 and X 2 is F; and a separation step of separating the fluorine-containing solvent from the first gas composition to obtain a second gas composition containing the HFO.</description><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS</subject><subject>APPARATUS THEREFOR</subject><subject>CHEMISTRY</subject><subject>GENERAL METHODS OF ORGANIC CHEMISTRY</subject><subject>METALLURGY</subject><subject>ORGANIC CHEMISTRY</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2018</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZFDzdQ3x8HdRcPMPUggI8ncJdfb0c1fwiHQJ8nfzCfUP8vf3cXXz9ONhYE1LzClO5YXS3AwKbq4hzh66qQX58anFBYnJqXmpJfGuAcbGlkZGRpaOhsZEKAEAnZYjfg</recordid><startdate>20181024</startdate><enddate>20181024</enddate><creator>TOMIYORI, Yusuke</creator><creator>NAKAMURA, Masahiko</creator><scope>EVB</scope></search><sort><creationdate>20181024</creationdate><title>METHOD FOR PRODUCING HYDROFLUOROOLEFIN</title><author>TOMIYORI, Yusuke ; NAKAMURA, Masahiko</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_EP3392229A13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; fre ; ger</language><creationdate>2018</creationdate><topic>ACYCLIC OR CARBOCYCLIC COMPOUNDS</topic><topic>APPARATUS THEREFOR</topic><topic>CHEMISTRY</topic><topic>GENERAL METHODS OF ORGANIC CHEMISTRY</topic><topic>METALLURGY</topic><topic>ORGANIC CHEMISTRY</topic><toplevel>online_resources</toplevel><creatorcontrib>TOMIYORI, Yusuke</creatorcontrib><creatorcontrib>NAKAMURA, Masahiko</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>TOMIYORI, Yusuke</au><au>NAKAMURA, Masahiko</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>METHOD FOR PRODUCING HYDROFLUOROOLEFIN</title><date>2018-10-24</date><risdate>2018</risdate><abstract>There is provided a method of producing HFO with which diluent gas is easily separated even at a low boiling point and which has excellent productivity. A method of producing HFO includes: a reaction step of converting, in the presence of fluorine-containing compound in a gaseous state having a boiling point higher than a boiling point of HFO represented by the following formula (2), HFC represented by the following formula (1) into the HFO represented by the following formula (2), to obtain a first gas composition containing the HFO and the fluorine-containing solvent, CR 1 R 2 X 1 CR 3 R 4 X 2 (1), CR 1 R 2 = CR 3 R 4 (2), where in the formula (1) and the formula (2), R 1 to R 3 are H or F, R 4 is H, F, CH 3 , CH 2 F, CHF 2 or CF 3 , the total number of fluorine atoms of R 1 to R 4 is one or more, and the total number of hydrogen atoms of R 1 to R 4 is one or more, one of X 1 and X 2 is H, and the other of X 1 and X 2 is F; and a separation step of separating the fluorine-containing solvent from the first gas composition to obtain a second gas composition containing the HFO.</abstract><oa>free_for_read</oa></addata></record> |
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subjects | ACYCLIC OR CARBOCYCLIC COMPOUNDS APPARATUS THEREFOR CHEMISTRY GENERAL METHODS OF ORGANIC CHEMISTRY METALLURGY ORGANIC CHEMISTRY |
title | METHOD FOR PRODUCING HYDROFLUOROOLEFIN |
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