SYNGAS PRODUCTION VIA CYCLIC REDUCTION AND OXIDATION METAL OXIDES
A chemical-looping system utilizes oxygen-carrier particles to produce syngas from carbonaceous fuels. The system provides a circuitous flow path for the oxygen-carrier particles, which are used to partially oxidize the fuel to produce syngas. The circuitous flow path can proceed through a plurality...
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| creator | SIENGCHUM, Tritti FLYNN, Thomas DEVAULT, Douglas VELAZQUEZ-VARGAS, Luis |
| description | A chemical-looping system utilizes oxygen-carrier particles to produce syngas from carbonaceous fuels. The system provides a circuitous flow path for the oxygen-carrier particles, which are used to partially oxidize the fuel to produce syngas. The circuitous flow path can proceed through a plurality of unit operations, including a reducer, a conversion reactor, an oxidizer, and a combustor. The conversion reactor is designed to partially oxidize carbonaceous fuel in co-current flow with the oxygen-carrier particles to produce syngas. In embodiments including an oxidizer, the oxidizer is designed to at partially re-oxidize the carrier particles, yielding hydrogen that can be mixed with partially oxidized products from the conversion reactor to adjust syngas quality. The combustor can be used to fully oxidize the carrier particles traveling in a closed loop. Reactions carried out in the combustor are highly exothermic and yield thermal energy that is absorbed by the carrier particles. The absorbed energy is used at other parts of the process, including the conversion reactor, to drive endothermic reactions. In this manner the system can be operated autothermally or nearly so. Methods of producing syngas are also disclosed. |
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The system provides a circuitous flow path for the oxygen-carrier particles, which are used to partially oxidize the fuel to produce syngas. The circuitous flow path can proceed through a plurality of unit operations, including a reducer, a conversion reactor, an oxidizer, and a combustor. The conversion reactor is designed to partially oxidize carbonaceous fuel in co-current flow with the oxygen-carrier particles to produce syngas. In embodiments including an oxidizer, the oxidizer is designed to at partially re-oxidize the carrier particles, yielding hydrogen that can be mixed with partially oxidized products from the conversion reactor to adjust syngas quality. The combustor can be used to fully oxidize the carrier particles traveling in a closed loop. Reactions carried out in the combustor are highly exothermic and yield thermal energy that is absorbed by the carrier particles. The absorbed energy is used at other parts of the process, including the conversion reactor, to drive endothermic reactions. In this manner the system can be operated autothermally or nearly so. Methods of producing syngas are also disclosed.</description><language>eng ; fre ; ger</language><subject>CARBURETTING AIR OR OTHER GASES ; CHEMISTRY ; COMPOUNDS THEREOF ; CRACKING HYDROCARBON OILS ; FUELS ; INORGANIC CHEMISTRY ; LUBRICANTS ; METALLURGY ; MINERAL WAXES ; NON-METALLIC ELEMENTS ; PEAT ; PETROLEUM, GAS OR COKE INDUSTRIES ; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION ; PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROMSOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES ; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES ; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS ; REFORMING OF NAPHTHA ; TECHNICAL GASES CONTAINING CARBON MONOXIDE</subject><creationdate>2019</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20190116&DB=EPODOC&CC=EP&NR=3322771A4$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25563,76318</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20190116&DB=EPODOC&CC=EP&NR=3322771A4$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>SIENGCHUM, Tritti</creatorcontrib><creatorcontrib>FLYNN, Thomas</creatorcontrib><creatorcontrib>DEVAULT, Douglas</creatorcontrib><creatorcontrib>VELAZQUEZ-VARGAS, Luis</creatorcontrib><title>SYNGAS PRODUCTION VIA CYCLIC REDUCTION AND OXIDATION METAL OXIDES</title><description>A chemical-looping system utilizes oxygen-carrier particles to produce syngas from carbonaceous fuels. The system provides a circuitous flow path for the oxygen-carrier particles, which are used to partially oxidize the fuel to produce syngas. The circuitous flow path can proceed through a plurality of unit operations, including a reducer, a conversion reactor, an oxidizer, and a combustor. The conversion reactor is designed to partially oxidize carbonaceous fuel in co-current flow with the oxygen-carrier particles to produce syngas. In embodiments including an oxidizer, the oxidizer is designed to at partially re-oxidize the carrier particles, yielding hydrogen that can be mixed with partially oxidized products from the conversion reactor to adjust syngas quality. The combustor can be used to fully oxidize the carrier particles traveling in a closed loop. Reactions carried out in the combustor are highly exothermic and yield thermal energy that is absorbed by the carrier particles. The absorbed energy is used at other parts of the process, including the conversion reactor, to drive endothermic reactions. In this manner the system can be operated autothermally or nearly so. Methods of producing syngas are also disclosed.</description><subject>CARBURETTING AIR OR OTHER GASES</subject><subject>CHEMISTRY</subject><subject>COMPOUNDS THEREOF</subject><subject>CRACKING HYDROCARBON OILS</subject><subject>FUELS</subject><subject>INORGANIC CHEMISTRY</subject><subject>LUBRICANTS</subject><subject>METALLURGY</subject><subject>MINERAL WAXES</subject><subject>NON-METALLIC ELEMENTS</subject><subject>PEAT</subject><subject>PETROLEUM, GAS OR COKE INDUSTRIES</subject><subject>PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION</subject><subject>PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROMSOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES</subject><subject>RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES</subject><subject>REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS</subject><subject>REFORMING OF NAPHTHA</subject><subject>TECHNICAL GASES CONTAINING CARBON MONOXIDE</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2019</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZHAMjvRzdwxWCAjydwl1DvH091MI83RUcI509vF0VghyhQk6-rko-Ed4ujiCeb6uIY4-YL5rMA8Da1piTnEqL5TmZlBwcw1x9tBNLciPTy0uSExOzUstiXcNMDY2MjI3N3Q0MSZCCQCWVyqp</recordid><startdate>20190116</startdate><enddate>20190116</enddate><creator>SIENGCHUM, Tritti</creator><creator>FLYNN, Thomas</creator><creator>DEVAULT, Douglas</creator><creator>VELAZQUEZ-VARGAS, Luis</creator><scope>EVB</scope></search><sort><creationdate>20190116</creationdate><title>SYNGAS PRODUCTION VIA CYCLIC REDUCTION AND OXIDATION METAL OXIDES</title><author>SIENGCHUM, Tritti ; FLYNN, Thomas ; DEVAULT, Douglas ; VELAZQUEZ-VARGAS, Luis</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_EP3322771A43</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; fre ; ger</language><creationdate>2019</creationdate><topic>CARBURETTING AIR OR OTHER GASES</topic><topic>CHEMISTRY</topic><topic>COMPOUNDS THEREOF</topic><topic>CRACKING HYDROCARBON OILS</topic><topic>FUELS</topic><topic>INORGANIC CHEMISTRY</topic><topic>LUBRICANTS</topic><topic>METALLURGY</topic><topic>MINERAL WAXES</topic><topic>NON-METALLIC ELEMENTS</topic><topic>PEAT</topic><topic>PETROLEUM, GAS OR COKE INDUSTRIES</topic><topic>PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION</topic><topic>PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROMSOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES</topic><topic>RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES</topic><topic>REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS</topic><topic>REFORMING OF NAPHTHA</topic><topic>TECHNICAL GASES CONTAINING CARBON MONOXIDE</topic><toplevel>online_resources</toplevel><creatorcontrib>SIENGCHUM, Tritti</creatorcontrib><creatorcontrib>FLYNN, Thomas</creatorcontrib><creatorcontrib>DEVAULT, Douglas</creatorcontrib><creatorcontrib>VELAZQUEZ-VARGAS, Luis</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>SIENGCHUM, Tritti</au><au>FLYNN, Thomas</au><au>DEVAULT, Douglas</au><au>VELAZQUEZ-VARGAS, Luis</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>SYNGAS PRODUCTION VIA CYCLIC REDUCTION AND OXIDATION METAL OXIDES</title><date>2019-01-16</date><risdate>2019</risdate><abstract>A chemical-looping system utilizes oxygen-carrier particles to produce syngas from carbonaceous fuels. The system provides a circuitous flow path for the oxygen-carrier particles, which are used to partially oxidize the fuel to produce syngas. The circuitous flow path can proceed through a plurality of unit operations, including a reducer, a conversion reactor, an oxidizer, and a combustor. The conversion reactor is designed to partially oxidize carbonaceous fuel in co-current flow with the oxygen-carrier particles to produce syngas. In embodiments including an oxidizer, the oxidizer is designed to at partially re-oxidize the carrier particles, yielding hydrogen that can be mixed with partially oxidized products from the conversion reactor to adjust syngas quality. The combustor can be used to fully oxidize the carrier particles traveling in a closed loop. Reactions carried out in the combustor are highly exothermic and yield thermal energy that is absorbed by the carrier particles. The absorbed energy is used at other parts of the process, including the conversion reactor, to drive endothermic reactions. In this manner the system can be operated autothermally or nearly so. Methods of producing syngas are also disclosed.</abstract><oa>free_for_read</oa></addata></record> |
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| subjects | CARBURETTING AIR OR OTHER GASES CHEMISTRY COMPOUNDS THEREOF CRACKING HYDROCARBON OILS FUELS INORGANIC CHEMISTRY LUBRICANTS METALLURGY MINERAL WAXES NON-METALLIC ELEMENTS PEAT PETROLEUM, GAS OR COKE INDUSTRIES PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROMSOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS REFORMING OF NAPHTHA TECHNICAL GASES CONTAINING CARBON MONOXIDE |
| title | SYNGAS PRODUCTION VIA CYCLIC REDUCTION AND OXIDATION METAL OXIDES |
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