METHOD OF PREPARING SAMPLE FOR CRYSTAL STRUCTURE ANALYSIS, METHOD OF DETERMINING ABSOLUTE CONFIGURATION OF CHIRAL COMPOUND, AND POLYNUCLEAR METAL COMPLEX MONOCRYSTAL

Provided are: a method for preparing a crystal structure analysis sample for determining an absolute configuration of a chiral compound, the method comprising bringing a single crystal of a porous compound into contact with a solvent solution that comprises a chiral compound for which the absolute c...

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Hauptverfasser: FUJITA Makoto, ARAI Tatsuhiko, INOKUMA Yasuhide
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Sprache:eng ; fre ; ger
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creator FUJITA Makoto
ARAI Tatsuhiko
INOKUMA Yasuhide
description Provided are: a method for preparing a crystal structure analysis sample for determining an absolute configuration of a chiral compound, the method comprising bringing a single crystal of a porous compound into contact with a solvent solution that comprises a chiral compound for which the absolute configuration is to be determined, to prepare a crystal structure analysis sample, the single crystal of the porous compound comprising a three-dimensional framework, and either or both of pores and voids that are defined by the three-dimensional framework, and are three-dimensionally arranged in an ordered manner, the three-dimensional framework being formed by one molecular chain or two or more molecular chains, or formed by one molecular chain or two or more molecular chains, and a framework-forming compound, and comprising a chiral substituent of which the absolute configuration is known, the crystal structure analysis sample having a structure in which molecules of the chiral compound are arranged in either or both of the pores and the voids of the single crystal in an ordered manner; a method for determining an absolute configuration of a chiral compound, wherein a crystal structure analysis sample obtained by the aforementioned method is used; and a single crystal of a polynuclear metal complex suitable for used the method for preparing a sample for crystal structure analysis.
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subjects AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUSPOLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE
APPARATUS THEREFOR
CHEMISTRY
CRYSTAL GROWTH
INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIRCHEMICAL OR PHYSICAL PROPERTIES
MEASURING
METALLURGY
PHYSICS
PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITHDEFINED STRUCTURE
REFINING BY ZONE-MELTING OF MATERIAL
SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITHDEFINED STRUCTURE
SINGLE-CRYSTAL-GROWTH
TESTING
UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL ORUNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL
title METHOD OF PREPARING SAMPLE FOR CRYSTAL STRUCTURE ANALYSIS, METHOD OF DETERMINING ABSOLUTE CONFIGURATION OF CHIRAL COMPOUND, AND POLYNUCLEAR METAL COMPLEX MONOCRYSTAL
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