PROCESSES FOR THE PREPARATION OF STANNIC OXIDE

PROCESSES FOR THE PREPARATION OF STANNIC OXIDE

Disclosed herein are processes for oxidising Sn2+ dissolved in an aqueous solution to stannic compounds using NO2 and optionally O2 as oxidants, wherein the aqueous solution is kept at a pH in the range of 0 to 7, wherein a salt Sn2+(Xn−)2/n and the oxidants are used according to the reaction scheme...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: CERESA, ALAN, CARLO, HECKENDORN, RENÉ, SCHERRER, ELISABETH
Format: Patent
Sprache:eng ; fre ; ger
Schlagworte:
CHEMISTRY
COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F
INORGANIC CHEMISTRY
METALLURGY
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Beschreibung
Zusammenfassung:Disclosed herein are processes for oxidising Sn2+ dissolved in an aqueous solution to stannic compounds using NO2 and optionally O2 as oxidants, wherein the aqueous solution is kept at a pH in the range of 0 to 7, wherein a salt Sn2+(Xn−)2/n and the oxidants are used according to the reaction scheme a Sn2+(Xn−)2/n +b O2+c NO2−→stannic compounds in which scheme a, b and c are mole numbers; with the proviso that when b is essentially zero, then the aqueous solution is essentially free of Cl−, HSO4− and SO42−.