COLOR STABLE MANGANESE-DOPED PHOSPHORS

A process for preparing color stable Mn +4 doped phosphors includes providing a phosphor of formula I; €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ A x [MF y ]:Mn +4 €ƒ€ƒ€ƒ€ƒ€ƒI and contacting the phosphor in particulate form with a saturated solution of a composition of formula II in aqueous hydrofluoric acid; €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€...

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Hauptverfasser: DESHPANDE, ANIRUDHA, RAJENDRA, LYONS, ROBERT, JOSEPH, GRIGOROV, LJUDMIL, SLAVCHEV, SETLUR, ANANT, ACHYUT
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creator DESHPANDE, ANIRUDHA, RAJENDRA
LYONS, ROBERT, JOSEPH
GRIGOROV, LJUDMIL, SLAVCHEV
SETLUR, ANANT, ACHYUT
description A process for preparing color stable Mn +4 doped phosphors includes providing a phosphor of formula I; €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ A x [MF y ]:Mn +4 €ƒ€ƒ€ƒ€ƒ€ƒI and contacting the phosphor in particulate form with a saturated solution of a composition of formula II in aqueous hydrofluoric acid; €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ A x [MF y ];€ƒ€ƒ€ƒ€ƒ€ƒII wherein A is Li, Na, K, Rb, Cs, NR 4 or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; R is H, lower alkyl, or a combination thereof; x is the absolute value of the charge of the [MF y ] ion; and y is 5, 6 or 7. In particular embodiments, M is Si, Ge, Sn, Ti, Zr, or a combination thereof. A lighting apparatus capable of emitting white light includes a semiconductor light source; and a phosphor composition radiationally coupled to the light source, and which includes a color stable Mn +4 doped phosphor.
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In particular embodiments, M is Si, Ge, Sn, Ti, Zr, or a combination thereof. 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In particular embodiments, M is Si, Ge, Sn, Ti, Zr, or a combination thereof. A lighting apparatus capable of emitting white light includes a semiconductor light source; and a phosphor composition radiationally coupled to the light source, and which includes a color stable Mn +4 doped phosphor.</abstract><oa>free_for_read</oa></addata></record>
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subjects ADHESIVES
BASIC ELECTRIC ELEMENTS
CHEMISTRY
DYES
ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR
ELECTRICITY
MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE
METALLURGY
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
NATURAL RESINS
PAINTS
POLISHES
SEMICONDUCTOR DEVICES
title COLOR STABLE MANGANESE-DOPED PHOSPHORS
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