METHOD FOR PRODUCING LITHIUM-MIXED METAL OXIDES AND USE THEREOF AS CATHODE MATERIAL

Process for preparing lithium mixed metal oxides which comprise essentially lithium, manganese, cobalt and nickel as metal atoms and have a stoichiometric ratio of lithium to the total transition metals of greater than 1, which comprises a) the preparation of a mixture designated as intermediate (B)...

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Hauptverfasser: HIBST, Hartmut, PETROVIC, Ivan, SCHRÖDLE, Simon, SCHWETER, Mark, LAMPERT, Jordan Keith
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Sprache:eng ; fre ; ger
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creator HIBST, Hartmut
PETROVIC, Ivan
SCHRÖDLE, Simon
SCHWETER, Mark
LAMPERT, Jordan Keith
description Process for preparing lithium mixed metal oxides which comprise essentially lithium, manganese, cobalt and nickel as metal atoms and have a stoichiometric ratio of lithium to the total transition metals of greater than 1, which comprises a) the preparation of a mixture designated as intermediate (B) which comprises essentially lithium-comprising mixed metal hydroxides and lithium-comprising mixed metal oxide hydroxides, where manganese, cobalt and nickel are comprised in the ratio (1-a-b):a:b and the oxidation state averaged over all ions of manganese, cobalt and nickel is at least 4-1.75a-1.75b, where 0 a 0.5 and 0.1 b 0.8, by a thermal treatment carried out with continual mixing and in the presence of oxygen of a mixture (A) comprising at least one transition metal compound and at least one lithium salt (L), during which L does not melt, and b) the thermal treatment carried out without mixing and in the presence of oxygen of the intermediate (B).
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subjects BASIC ELECTRIC ELEMENTS
CABLES
CHEMISTRY
COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F
CONDUCTORS
ELECTRICITY
INORGANIC CHEMISTRY
INSULATORS
METALLURGY
PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY
SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING ORDIELECTRIC PROPERTIES
title METHOD FOR PRODUCING LITHIUM-MIXED METAL OXIDES AND USE THEREOF AS CATHODE MATERIAL
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