Method for continuous production of a prepolymer based on phenol resins, oxazolines and epoxides
Continuous preparation (M1) of a prepolymer composition (P1) involves: combining a phenolic resin component, oxazoline component and epoxide component, in presence of a catalyst, in an extruder. The phenolic resin component and oxazoline component are supplied to the extruder in a stream A; at least...
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description | Continuous preparation (M1) of a prepolymer composition (P1) involves: combining a phenolic resin component, oxazoline component and epoxide component, in presence of a catalyst, in an extruder. The phenolic resin component and oxazoline component are supplied to the extruder in a stream A; at least one catalyst selected from Lewis adduct of boron trifluoride or aluminum trichloride, arylsulfonic acid, alkylsulfonic acid, latent arylsulfonic acid, and latent alkylsulfonic acid, is supplied to the extruder as stream B; and the epoxide component is supplied to extruder in a stream C. Continuous preparation (M1) of a prepolymer composition (P1) involves: combining a phenolic resin component, an oxazoline component and epoxide component, in the presence of a catalyst, in an extruder. The phenolic resin component and oxazoline component are supplied to the extruder in a stream A, and at least one catalyst selected from a Lewis adduct of boron trifluoride or aluminum trichloride, arylsulfonic acid, alkylsulfonic acid, a latent arylsulfonic acid, and latent alkylsulfonic acid, is supplied to the extruder as stream B, and the epoxide component is supplied to the extruder in a stream C. An infeed of the stream A, relative to an extrusion direction, is before an infeed of the stream C, where the streams A, B and C are combined at 120-200[deg] C with a residence time of 3 seconds to 15 minutes in the extruder to form a product, and then discharging the product from the extruder and cooling to less than 45[deg] C within 30-60 seconds. Independent claims are included for the following: (1) a prepolymer (P1) obtained by the process (M1); (2) a composition comprising the prepolymer (P1); (3) producing impregnated reinforcing fibers involving: dissolving the prepolymer (P1) in 2-butanone and impregnating at least one reinforcing fiber selected from a glass fiber and a carbon fiber with the dissolved prepolymer, and curing the impregnated reinforcing fiber; and (4) a powder for producing prepregs, comprising: the prepolymer (P1) and at least one additional component.
Verfahren zur kontinuierlichen Herstellung von Prepolymeren basierend auf Phenolharz, einer Oxazolin-Komponente und einem Epoxid in Gegenwart eines Katalysators, das sich dadurch auszeichnet, dass das Phenolharz und die Oxazolin-Komponente in einem Stoffstrom A und ein Lewis-Addukt des Bortrifluorids oder des Aluminiumtrichlorids oder Arylsulfonsäuren oder Alkylsulfonsäuren oder latente Arylsulfonsäuren oder l |
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fullrecord | <record><control><sourceid>epo_EVB</sourceid><recordid>TN_cdi_epo_espacenet_EP2455424A1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>EP2455424A1</sourcerecordid><originalsourceid>FETCH-epo_espacenet_EP2455424A13</originalsourceid><addsrcrecordid>eNqNyjEKAjEQheE0FqLeYQ6ghWv2ACIrNoKF_RqTCRuIMyGTwOrpTeEBrB4_71uqxxXLxA48Z7BMJVDlKpAyu2pLYAL2YFpj4vh-YYanEXTQjjQhcYSMEki2wLP5cAyEAoYcND8Hh7JWC2-i4Oa3KwXn4X667BoYUZKxSFjG4dbpvtedPu4Pf5AvhVc9UA</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>patent</recordtype></control><display><type>patent</type><title>Method for continuous production of a prepolymer based on phenol resins, oxazolines and epoxides</title><source>esp@cenet</source><creator>VON ITTER, FRANZ-ALBERT ; WEIHRAUCH, THOMAS ; OMEIS, MARIANNE</creator><creatorcontrib>VON ITTER, FRANZ-ALBERT ; WEIHRAUCH, THOMAS ; OMEIS, MARIANNE</creatorcontrib><description>Continuous preparation (M1) of a prepolymer composition (P1) involves: combining a phenolic resin component, oxazoline component and epoxide component, in presence of a catalyst, in an extruder. The phenolic resin component and oxazoline component are supplied to the extruder in a stream A; at least one catalyst selected from Lewis adduct of boron trifluoride or aluminum trichloride, arylsulfonic acid, alkylsulfonic acid, latent arylsulfonic acid, and latent alkylsulfonic acid, is supplied to the extruder as stream B; and the epoxide component is supplied to extruder in a stream C. Continuous preparation (M1) of a prepolymer composition (P1) involves: combining a phenolic resin component, an oxazoline component and epoxide component, in the presence of a catalyst, in an extruder. The phenolic resin component and oxazoline component are supplied to the extruder in a stream A, and at least one catalyst selected from a Lewis adduct of boron trifluoride or aluminum trichloride, arylsulfonic acid, alkylsulfonic acid, a latent arylsulfonic acid, and latent alkylsulfonic acid, is supplied to the extruder as stream B, and the epoxide component is supplied to the extruder in a stream C. An infeed of the stream A, relative to an extrusion direction, is before an infeed of the stream C, where the streams A, B and C are combined at 120-200[deg] C with a residence time of 3 seconds to 15 minutes in the extruder to form a product, and then discharging the product from the extruder and cooling to less than 45[deg] C within 30-60 seconds. Independent claims are included for the following: (1) a prepolymer (P1) obtained by the process (M1); (2) a composition comprising the prepolymer (P1); (3) producing impregnated reinforcing fibers involving: dissolving the prepolymer (P1) in 2-butanone and impregnating at least one reinforcing fiber selected from a glass fiber and a carbon fiber with the dissolved prepolymer, and curing the impregnated reinforcing fiber; and (4) a powder for producing prepregs, comprising: the prepolymer (P1) and at least one additional component.
Verfahren zur kontinuierlichen Herstellung von Prepolymeren basierend auf Phenolharz, einer Oxazolin-Komponente und einem Epoxid in Gegenwart eines Katalysators, das sich dadurch auszeichnet, dass das Phenolharz und die Oxazolin-Komponente in einem Stoffstrom A und ein Lewis-Addukt des Bortrifluorids oder des Aluminiumtrichlorids oder Arylsulfonsäuren oder Alkylsulfonsäuren oder latente Arylsulfonsäuren oder latente Alkylsulfonsäuren als Katalysator in einem Stoffstrom B und das Epoxid in einem Stoffstrom C dem Extruder zugeführt werden, wobei der Zulauf des Stoffstroms A in Extrusionsrichtung gesehen vor dem Zulauf des Stoffstroms C liegt, bei einer Reaktionstemperatur von 120 bis 200 °C und bei einer Verweilzeit dieser Edukte im Extruder von 3 Sekunden bis 15 Minuten durchmischt werden und anschließend der Produktaustrag des Extruders auf eine Temperatur von kleiner 45 °C innerhalb von 30 bis 60 Sekunden abgekühlt wird.</description><language>eng ; fre ; ger</language><subject>ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE ; ADHESIVES ; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING ; CHEMICAL PAINT OR INK REMOVERS ; CHEMISTRY ; COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS ; COMPOSITIONS BASED THEREON ; COMPOSITIONS OF MACROMOLECULAR COMPOUNDS ; CORRECTING FLUIDS ; DYES ; FILLING PASTES ; INKS ; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS ; METALLURGY ; MISCELLANEOUS APPLICATIONS OF MATERIALS ; MISCELLANEOUS COMPOSITIONS ; NATURAL RESINS ; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL ; ORGANIC MACROMOLECULAR COMPOUNDS ; PAINTS ; PASTES OR SOLIDS FOR COLOURING OR PRINTING ; PERFORMING OPERATIONS ; POLISHES ; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDEDFOR ; SHAPING OR JOINING OF PLASTICS ; THEIR PREPARATION OR CHEMICAL WORKING-UP ; TRANSPORTING ; USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS ; USE OF MATERIALS AS ADHESIVES ; USE OF MATERIALS THEREFOR ; WOODSTAINS ; WORKING OF PLASTICS ; WORKING OF SUBSTANCES IN A PLASTIC STATE, IN GENERAL</subject><creationdate>2012</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20120523&DB=EPODOC&CC=EP&NR=2455424A1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25563,76418</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20120523&DB=EPODOC&CC=EP&NR=2455424A1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>VON ITTER, FRANZ-ALBERT</creatorcontrib><creatorcontrib>WEIHRAUCH, THOMAS</creatorcontrib><creatorcontrib>OMEIS, MARIANNE</creatorcontrib><title>Method for continuous production of a prepolymer based on phenol resins, oxazolines and epoxides</title><description>Continuous preparation (M1) of a prepolymer composition (P1) involves: combining a phenolic resin component, oxazoline component and epoxide component, in presence of a catalyst, in an extruder. The phenolic resin component and oxazoline component are supplied to the extruder in a stream A; at least one catalyst selected from Lewis adduct of boron trifluoride or aluminum trichloride, arylsulfonic acid, alkylsulfonic acid, latent arylsulfonic acid, and latent alkylsulfonic acid, is supplied to the extruder as stream B; and the epoxide component is supplied to extruder in a stream C. Continuous preparation (M1) of a prepolymer composition (P1) involves: combining a phenolic resin component, an oxazoline component and epoxide component, in the presence of a catalyst, in an extruder. The phenolic resin component and oxazoline component are supplied to the extruder in a stream A, and at least one catalyst selected from a Lewis adduct of boron trifluoride or aluminum trichloride, arylsulfonic acid, alkylsulfonic acid, a latent arylsulfonic acid, and latent alkylsulfonic acid, is supplied to the extruder as stream B, and the epoxide component is supplied to the extruder in a stream C. An infeed of the stream A, relative to an extrusion direction, is before an infeed of the stream C, where the streams A, B and C are combined at 120-200[deg] C with a residence time of 3 seconds to 15 minutes in the extruder to form a product, and then discharging the product from the extruder and cooling to less than 45[deg] C within 30-60 seconds. Independent claims are included for the following: (1) a prepolymer (P1) obtained by the process (M1); (2) a composition comprising the prepolymer (P1); (3) producing impregnated reinforcing fibers involving: dissolving the prepolymer (P1) in 2-butanone and impregnating at least one reinforcing fiber selected from a glass fiber and a carbon fiber with the dissolved prepolymer, and curing the impregnated reinforcing fiber; and (4) a powder for producing prepregs, comprising: the prepolymer (P1) and at least one additional component.
Verfahren zur kontinuierlichen Herstellung von Prepolymeren basierend auf Phenolharz, einer Oxazolin-Komponente und einem Epoxid in Gegenwart eines Katalysators, das sich dadurch auszeichnet, dass das Phenolharz und die Oxazolin-Komponente in einem Stoffstrom A und ein Lewis-Addukt des Bortrifluorids oder des Aluminiumtrichlorids oder Arylsulfonsäuren oder Alkylsulfonsäuren oder latente Arylsulfonsäuren oder latente Alkylsulfonsäuren als Katalysator in einem Stoffstrom B und das Epoxid in einem Stoffstrom C dem Extruder zugeführt werden, wobei der Zulauf des Stoffstroms A in Extrusionsrichtung gesehen vor dem Zulauf des Stoffstroms C liegt, bei einer Reaktionstemperatur von 120 bis 200 °C und bei einer Verweilzeit dieser Edukte im Extruder von 3 Sekunden bis 15 Minuten durchmischt werden und anschließend der Produktaustrag des Extruders auf eine Temperatur von kleiner 45 °C innerhalb von 30 bis 60 Sekunden abgekühlt wird.</description><subject>ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE</subject><subject>ADHESIVES</subject><subject>AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING</subject><subject>CHEMICAL PAINT OR INK REMOVERS</subject><subject>CHEMISTRY</subject><subject>COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS</subject><subject>COMPOSITIONS BASED THEREON</subject><subject>COMPOSITIONS OF MACROMOLECULAR COMPOUNDS</subject><subject>CORRECTING FLUIDS</subject><subject>DYES</subject><subject>FILLING PASTES</subject><subject>INKS</subject><subject>MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS</subject><subject>METALLURGY</subject><subject>MISCELLANEOUS APPLICATIONS OF MATERIALS</subject><subject>MISCELLANEOUS COMPOSITIONS</subject><subject>NATURAL RESINS</subject><subject>NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL</subject><subject>ORGANIC MACROMOLECULAR COMPOUNDS</subject><subject>PAINTS</subject><subject>PASTES OR SOLIDS FOR COLOURING OR PRINTING</subject><subject>PERFORMING OPERATIONS</subject><subject>POLISHES</subject><subject>SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDEDFOR</subject><subject>SHAPING OR JOINING OF PLASTICS</subject><subject>THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><subject>TRANSPORTING</subject><subject>USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS</subject><subject>USE OF MATERIALS AS ADHESIVES</subject><subject>USE OF MATERIALS THEREFOR</subject><subject>WOODSTAINS</subject><subject>WORKING OF PLASTICS</subject><subject>WORKING OF SUBSTANCES IN A PLASTIC STATE, IN GENERAL</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2012</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNqNyjEKAjEQheE0FqLeYQ6ghWv2ACIrNoKF_RqTCRuIMyGTwOrpTeEBrB4_71uqxxXLxA48Z7BMJVDlKpAyu2pLYAL2YFpj4vh-YYanEXTQjjQhcYSMEki2wLP5cAyEAoYcND8Hh7JWC2-i4Oa3KwXn4X667BoYUZKxSFjG4dbpvtedPu4Pf5AvhVc9UA</recordid><startdate>20120523</startdate><enddate>20120523</enddate><creator>VON ITTER, FRANZ-ALBERT</creator><creator>WEIHRAUCH, THOMAS</creator><creator>OMEIS, MARIANNE</creator><scope>EVB</scope></search><sort><creationdate>20120523</creationdate><title>Method for continuous production of a prepolymer based on phenol resins, oxazolines and epoxides</title><author>VON ITTER, FRANZ-ALBERT ; WEIHRAUCH, THOMAS ; OMEIS, MARIANNE</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_EP2455424A13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; fre ; ger</language><creationdate>2012</creationdate><topic>ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE</topic><topic>ADHESIVES</topic><topic>AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING</topic><topic>CHEMICAL PAINT OR INK REMOVERS</topic><topic>CHEMISTRY</topic><topic>COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>COMPOSITIONS OF MACROMOLECULAR COMPOUNDS</topic><topic>CORRECTING FLUIDS</topic><topic>DYES</topic><topic>FILLING PASTES</topic><topic>INKS</topic><topic>MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS</topic><topic>METALLURGY</topic><topic>MISCELLANEOUS APPLICATIONS OF MATERIALS</topic><topic>MISCELLANEOUS COMPOSITIONS</topic><topic>NATURAL RESINS</topic><topic>NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>PAINTS</topic><topic>PASTES OR SOLIDS FOR COLOURING OR PRINTING</topic><topic>PERFORMING OPERATIONS</topic><topic>POLISHES</topic><topic>SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDEDFOR</topic><topic>SHAPING OR JOINING OF PLASTICS</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><topic>TRANSPORTING</topic><topic>USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS</topic><topic>USE OF MATERIALS AS ADHESIVES</topic><topic>USE OF MATERIALS THEREFOR</topic><topic>WOODSTAINS</topic><topic>WORKING OF PLASTICS</topic><topic>WORKING OF SUBSTANCES IN A PLASTIC STATE, IN GENERAL</topic><toplevel>online_resources</toplevel><creatorcontrib>VON ITTER, FRANZ-ALBERT</creatorcontrib><creatorcontrib>WEIHRAUCH, THOMAS</creatorcontrib><creatorcontrib>OMEIS, MARIANNE</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>VON ITTER, FRANZ-ALBERT</au><au>WEIHRAUCH, THOMAS</au><au>OMEIS, MARIANNE</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Method for continuous production of a prepolymer based on phenol resins, oxazolines and epoxides</title><date>2012-05-23</date><risdate>2012</risdate><abstract>Continuous preparation (M1) of a prepolymer composition (P1) involves: combining a phenolic resin component, oxazoline component and epoxide component, in presence of a catalyst, in an extruder. The phenolic resin component and oxazoline component are supplied to the extruder in a stream A; at least one catalyst selected from Lewis adduct of boron trifluoride or aluminum trichloride, arylsulfonic acid, alkylsulfonic acid, latent arylsulfonic acid, and latent alkylsulfonic acid, is supplied to the extruder as stream B; and the epoxide component is supplied to extruder in a stream C. Continuous preparation (M1) of a prepolymer composition (P1) involves: combining a phenolic resin component, an oxazoline component and epoxide component, in the presence of a catalyst, in an extruder. The phenolic resin component and oxazoline component are supplied to the extruder in a stream A, and at least one catalyst selected from a Lewis adduct of boron trifluoride or aluminum trichloride, arylsulfonic acid, alkylsulfonic acid, a latent arylsulfonic acid, and latent alkylsulfonic acid, is supplied to the extruder as stream B, and the epoxide component is supplied to the extruder in a stream C. An infeed of the stream A, relative to an extrusion direction, is before an infeed of the stream C, where the streams A, B and C are combined at 120-200[deg] C with a residence time of 3 seconds to 15 minutes in the extruder to form a product, and then discharging the product from the extruder and cooling to less than 45[deg] C within 30-60 seconds. Independent claims are included for the following: (1) a prepolymer (P1) obtained by the process (M1); (2) a composition comprising the prepolymer (P1); (3) producing impregnated reinforcing fibers involving: dissolving the prepolymer (P1) in 2-butanone and impregnating at least one reinforcing fiber selected from a glass fiber and a carbon fiber with the dissolved prepolymer, and curing the impregnated reinforcing fiber; and (4) a powder for producing prepregs, comprising: the prepolymer (P1) and at least one additional component.
Verfahren zur kontinuierlichen Herstellung von Prepolymeren basierend auf Phenolharz, einer Oxazolin-Komponente und einem Epoxid in Gegenwart eines Katalysators, das sich dadurch auszeichnet, dass das Phenolharz und die Oxazolin-Komponente in einem Stoffstrom A und ein Lewis-Addukt des Bortrifluorids oder des Aluminiumtrichlorids oder Arylsulfonsäuren oder Alkylsulfonsäuren oder latente Arylsulfonsäuren oder latente Alkylsulfonsäuren als Katalysator in einem Stoffstrom B und das Epoxid in einem Stoffstrom C dem Extruder zugeführt werden, wobei der Zulauf des Stoffstroms A in Extrusionsrichtung gesehen vor dem Zulauf des Stoffstroms C liegt, bei einer Reaktionstemperatur von 120 bis 200 °C und bei einer Verweilzeit dieser Edukte im Extruder von 3 Sekunden bis 15 Minuten durchmischt werden und anschließend der Produktaustrag des Extruders auf eine Temperatur von kleiner 45 °C innerhalb von 30 bis 60 Sekunden abgekühlt wird.</abstract><oa>free_for_read</oa></addata></record> |
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subjects | ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE ADHESIVES AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING CHEMICAL PAINT OR INK REMOVERS CHEMISTRY COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS COMPOSITIONS BASED THEREON COMPOSITIONS OF MACROMOLECULAR COMPOUNDS CORRECTING FLUIDS DYES FILLING PASTES INKS MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL ORGANIC MACROMOLECULAR COMPOUNDS PAINTS PASTES OR SOLIDS FOR COLOURING OR PRINTING PERFORMING OPERATIONS POLISHES SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDEDFOR SHAPING OR JOINING OF PLASTICS THEIR PREPARATION OR CHEMICAL WORKING-UP TRANSPORTING USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS USE OF MATERIALS AS ADHESIVES USE OF MATERIALS THEREFOR WOODSTAINS WORKING OF PLASTICS WORKING OF SUBSTANCES IN A PLASTIC STATE, IN GENERAL |
title | Method for continuous production of a prepolymer based on phenol resins, oxazolines and epoxides |
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