VANADIUM TRAPS FOR CATALYTIC CRACKING PROCESSES AND PREPARATION THEREOF

The invention relates to chemical compositions that can be used for hydrocarbon catalytic cracking processes with vanadium as a contaminant, including an active phase formed by different pyrophosphates M2P207 (M=Ba or Ca) supported on a mixture of magnesium and aluminium oxide, preferably magnesium...

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Hauptverfasser: VERGEL HERNANDEZ, CESAR AUGUSTO, ALMANZA RUBIANO, LUIS OSWALDO, HOYOS MARIN, LUIS JAVIER
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creator VERGEL HERNANDEZ, CESAR AUGUSTO
ALMANZA RUBIANO, LUIS OSWALDO
HOYOS MARIN, LUIS JAVIER
description The invention relates to chemical compositions that can be used for hydrocarbon catalytic cracking processes with vanadium as a contaminant, including an active phase formed by different pyrophosphates M2P207 (M=Ba or Ca) supported on a mixture of magnesium and aluminium oxide, preferably magnesium aluminate in the spinel phase. The composition captures the metals originating from the charge, particularly vanadium, and thus protects the catalyst. Said composition is preferably used in the form of a separated particle in order to the control the addition thereof to the unit according to the metal content of the charge. The invention also relates to the method for preparing said composition, including synthesis of pyrophosphates, formation of a suspension of boehmite alumina, magnesium oxide or magnesium hydroxide, together with oxides M2P207, spray drying and calcination of the microspheres without generating any loss in the crystalline structure of oxides M2P2O7.
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The composition captures the metals originating from the charge, particularly vanadium, and thus protects the catalyst. Said composition is preferably used in the form of a separated particle in order to the control the addition thereof to the unit according to the metal content of the charge. The invention also relates to the method for preparing said composition, including synthesis of pyrophosphates, formation of a suspension of boehmite alumina, magnesium oxide or magnesium hydroxide, together with oxides M2P207, spray drying and calcination of the microspheres without generating any loss in the crystalline structure of oxides M2P2O7.</description><language>eng ; fre ; ger</language><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY ; CHEMISTRY ; CRACKING HYDROCARBON OILS ; FUELS ; LUBRICANTS ; METALLURGY ; MINERAL WAXES ; PEAT ; PERFORMING OPERATIONS ; PETROLEUM, GAS OR COKE INDUSTRIES ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION ; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES ; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS ; REFORMING OF NAPHTHA ; TECHNICAL GASES CONTAINING CARBON MONOXIDE ; THEIR RELEVANT APPARATUS ; TRANSPORTING</subject><creationdate>2010</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20101201&amp;DB=EPODOC&amp;CC=EP&amp;NR=2105488A4$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25542,76289</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20101201&amp;DB=EPODOC&amp;CC=EP&amp;NR=2105488A4$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>VERGEL HERNANDEZ, CESAR AUGUSTO</creatorcontrib><creatorcontrib>ALMANZA RUBIANO, LUIS OSWALDO</creatorcontrib><creatorcontrib>HOYOS MARIN, LUIS JAVIER</creatorcontrib><title>VANADIUM TRAPS FOR CATALYTIC CRACKING PROCESSES AND PREPARATION THEREOF</title><description>The invention relates to chemical compositions that can be used for hydrocarbon catalytic cracking processes with vanadium as a contaminant, including an active phase formed by different pyrophosphates M2P207 (M=Ba or Ca) supported on a mixture of magnesium and aluminium oxide, preferably magnesium aluminate in the spinel phase. 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The composition captures the metals originating from the charge, particularly vanadium, and thus protects the catalyst. Said composition is preferably used in the form of a separated particle in order to the control the addition thereof to the unit according to the metal content of the charge. The invention also relates to the method for preparing said composition, including synthesis of pyrophosphates, formation of a suspension of boehmite alumina, magnesium oxide or magnesium hydroxide, together with oxides M2P207, spray drying and calcination of the microspheres without generating any loss in the crystalline structure of oxides M2P2O7.</abstract><oa>free_for_read</oa></addata></record>
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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
CRACKING HYDROCARBON OILS
FUELS
LUBRICANTS
METALLURGY
MINERAL WAXES
PEAT
PERFORMING OPERATIONS
PETROLEUM, GAS OR COKE INDUSTRIES
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION
RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES
REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS
REFORMING OF NAPHTHA
TECHNICAL GASES CONTAINING CARBON MONOXIDE
THEIR RELEVANT APPARATUS
TRANSPORTING
title VANADIUM TRAPS FOR CATALYTIC CRACKING PROCESSES AND PREPARATION THEREOF
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