Method of manufacturing polycarbonate using the melting ester interchange method

Preparing polycarbonate by the melt transesterification involves, reacting a dihydroxyaryl compound with a diarylcarbonate in the presence of catalyst in a multistage process; where at least one inhibitor is added to the melt before the last reaction stage and at least one aliphatic hydroxydicarboxy...

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Hauptverfasser: HAESE, WILFRIED DR, MEYER, ALEXANDER DR
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creator HAESE, WILFRIED DR
MEYER, ALEXANDER DR
description Preparing polycarbonate by the melt transesterification involves, reacting a dihydroxyaryl compound with a diarylcarbonate in the presence of catalyst in a multistage process; where at least one inhibitor is added to the melt before the last reaction stage and at least one aliphatic hydroxydicarboxylic acid(s) and/or hydroxypolycarboxylic acid(s) or its derivative(s) are added in or after the last reaction stage. An independent claim is included for an optical disc having mean electric field strength of -20 to +20 kV/m and a field strength variation of less than 15 kV/m and comprising the polycarbonate containing at least one aliphatic hydroxydicarboxylic acid and/or hydroxypolycarboxylic acid or its derivative (5-500 parts per million (ppm)), and a phenolic terminal OH groups content of greater than 150 ppm.
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS
title Method of manufacturing polycarbonate using the melting ester interchange method
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