Separation of carbon dioxide and hydrogen

This invention relates to recovering carbon dioxide (77) and hydrogen (31) in concentrated form from a shifted synthesis gas stream (1) comprising hydrogen and carbon dioxide thereby generating a carbon dioxide stream that is sequestered or used for enhanced oil recovery and a hydrogen stream that i...

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Hauptverfasser: HINDERINK, ANTONIE PIETER, HARPER, ROGER NEIL, HUDA, BADRUL, VAN DER POL, EVERT
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Sprache:eng ; fre ; ger
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creator HINDERINK, ANTONIE PIETER
HARPER, ROGER NEIL
HUDA, BADRUL
VAN DER POL, EVERT
description This invention relates to recovering carbon dioxide (77) and hydrogen (31) in concentrated form from a shifted synthesis gas stream (1) comprising hydrogen and carbon dioxide thereby generating a carbon dioxide stream that is sequestered or used for enhanced oil recovery and a hydrogen stream that is used as fuel for a power plant thereby generating electricity. In the process of this invention a shifted synthesis gas stream is fed to a membrane separation unit (M-1) at a pressure of at least 50 bar gauge and the hydrogen rich permeate stream (3) is fed directly to the combustor of a gas turbine without any requirement to recompress the hydrogen. The residual gas stream (carbon dioxide enriched stream 2) from the membrane separation unit is cooled using at least one, preferably, at least two internal refrigeration stages (Ex-2,Ex-3,Ex-4,Ex-5,Ex-6,Ex-7,Ex-8) such that the hydrogen containing offgas (29) is also obtained at above the operating pressure of the combustor of the gas turbine.
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subjects BLASTING
CHEMISTRY
COMBINED HEATING AND REFRIGERATION SYSTEMS
COMPOUNDS THEREOF
HEAT PUMP SYSTEMS
HEATING
INORGANIC CHEMISTRY
LIGHTING
LIQUEFACTION SOLIDIFICATION OF GASES
LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS
MANUFACTURE OR STORAGE OF ICE
MECHANICAL ENGINEERING
METALLURGY
MIXTURES BY PRESSURE AND COLD TREATMENT
NON-METALLIC ELEMENTS
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
REFRIGERATION OR COOLING
SEPARATION
TRANSPORTING
WEAPONS
title Separation of carbon dioxide and hydrogen
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