PRODUCTION OF ISOTACTIC AND REGIORANDOM POLYPROPYLENE BASED POLYMER AND BLOCK COPOLYMERS

One step ortho-alkylation of anilines with styrenes to give chiral anilines is obtained using a strong acid catalyst, e.g. CF3SO3H. Condensation of the product to give ligand and metallation gives complex which catalyzes polymerization of propylene to give isotactic propylene or regiorandom propylen...

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Hauptverfasser: COATES, GEOFFREY, W, ROSE, JEFFREY, M, CHERIAN, ANNA
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creator COATES, GEOFFREY, W
ROSE, JEFFREY, M
CHERIAN, ANNA
description One step ortho-alkylation of anilines with styrenes to give chiral anilines is obtained using a strong acid catalyst, e.g. CF3SO3H. Condensation of the product to give ligand and metallation gives complex which catalyzes polymerization of propylene to give isotactic propylene or regiorandom propylene of low PDI or blocks thereof, depending on polymerization temperature.
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC CHEMISTRY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title PRODUCTION OF ISOTACTIC AND REGIORANDOM POLYPROPYLENE BASED POLYMER AND BLOCK COPOLYMERS
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