COLOUR STABILISED POLYOLEFINS

A polyolefin composition which comprises: (a) a polyolefin containing transition metal catalyst residue (excluding metallic co-catalyst residues) at a level below 5 ppm based on the weight of the polyolefin; (b) optionally a first stabilizing component consisting of a phenolic antioxidant or mixture...

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Hauptverfasser: DEJOLIER, BRUNO, KECK-ANTOINE, KLAUS, TOTELIN, CLAUDE
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creator DEJOLIER, BRUNO
KECK-ANTOINE, KLAUS
TOTELIN, CLAUDE
description A polyolefin composition which comprises: (a) a polyolefin containing transition metal catalyst residue (excluding metallic co-catalyst residues) at a level below 5 ppm based on the weight of the polyolefin; (b) optionally a first stabilizing component consisting of a phenolic antioxidant or mixture of phenolic antioxidants; (c) optionally a second stabilizing component consisting of a phosphite antioxidant or a mixture of phosphite antioxidants; and (d) a third stabilizing component which acts also as a color suppressant and which is a polyfunctional alcohol, amine or amide or mixtures thereof, with at least one of (b) and (c) present and with the proviso that if the phosphite antioxidant is trilauryl phosphite it must be used in combination with another phosphite. The preferred stabilizing components (b) is 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6 dimethyl,benzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione or mixed tocopherols. The preferred stabilizing component (c) is Tris(mono-nonylphenyl)phosphite, Tris(2,4-di-t-butylphenyl)phosphite or bis(2,4-di-t-butyl phenyl)pentaerythritol diphosphite. The preferred stabilizing component (d) which also acts as a color suppressant component (d) is dipentaerythritol or tri-isopropanol amine. The preferred polyolefins are polypropylene and polyethylene. The polyolefin composition also may contain a hindered amine stabilizer (HAS) and an acid scavenger (e.g. calcium stearate).
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The preferred stabilizing components (b) is 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6 dimethyl,benzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione or mixed tocopherols. The preferred stabilizing component (c) is Tris(mono-nonylphenyl)phosphite, Tris(2,4-di-t-butylphenyl)phosphite or bis(2,4-di-t-butyl phenyl)pentaerythritol diphosphite. The preferred stabilizing component (d) which also acts as a color suppressant component (d) is dipentaerythritol or tri-isopropanol amine. The preferred polyolefins are polypropylene and polyethylene. 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subjects BUILDING
BUILDING IMPLEMENTS OR OTHER BUILDING AIDS, OR THEIRUSE
CHEMISTRY
COMPOSITIONS BASED THEREON
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
FIXED CONSTRUCTIONS
FORMS
HANDLING BUILDING MATERIALS ON THE SITE
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
REPAIRING, BREAKING-UP OR OTHER WORK ON EXISTINGBUILDINGS
SCAFFOLDING
SHUTTERING
THEIR PREPARATION OR CHEMICAL WORKING-UP
USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS
title COLOUR STABILISED POLYOLEFINS
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