A PROCESS FOR A TWO STAGE MELT POLYMERIZATION FOR THE PRODUCTION OF POLYBENZIMIDAZOLE
A process is presented for the production of high molecular weight polybenzimidazole, in two steps. Step one: provide a first reaction vessel and charge it with at least one aromatic hydrocarbon tetraamine, and a heterocyclic ring making up the dicarboxylic component. Heat the reactants under agitat...
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| creator | BAKER, J., DEAN DAWKINS, BOBBY, G JOINER, RITA, H HUDSON, KARIN, M |
| description | A process is presented for the production of high molecular weight polybenzimidazole, in two steps. Step one: provide a first reaction vessel and charge it with at least one aromatic hydrocarbon tetraamine, and a heterocyclic ring making up the dicarboxylic component. Heat the reactants under agitation. Terminate the agitation while continuing to heat the reaction mixture to about 230° C. while allowing the reaction mass to foam. Cool the reaction mass to a friable foamed mass. Crush the friable foamed mass to obtain a ground prepolymer. Step two; provide a second reaction vessel, transferring the ground prepolymer to it. A pressure wash of the first reaction vessel and the means for agitation to obtain a second ground prepolymer. Transfer the second ground prepolymer to the second reaction vessel. Heat the ground prepolymer and second ground prepolymer under agitation to a higher temperature than the first step until the desired degree of polymerization is achieved. |
| format | Patent |
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| subjects | CHEMISTRY COMPOSITIONS BASED THEREON MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS THEIR PREPARATION OR CHEMICAL WORKING-UP |
| title | A PROCESS FOR A TWO STAGE MELT POLYMERIZATION FOR THE PRODUCTION OF POLYBENZIMIDAZOLE |
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