Stable electrolyte counteranions for capacitors

The invention relates to electrolyte salts for electrochemical devices of improved physical, chemical and electrochemical stability. The improvement resides in the use of anions of salts of the formula comprising: i) (B 12 F x Z 12-x ) 2- wherein Z comprises at least one of H, Cl, Br or OR; R compri...

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Hauptverfasser: PEZ, GUIDO PETER, DANTSIN, GENNADY, IVANOV, SERGEI VLADIMIROVICH, LEHMANN, JOHN F, CASTEEL, WILLIAM JACK
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creator PEZ, GUIDO PETER
DANTSIN, GENNADY
IVANOV, SERGEI VLADIMIROVICH
LEHMANN, JOHN F
CASTEEL, WILLIAM JACK
description The invention relates to electrolyte salts for electrochemical devices of improved physical, chemical and electrochemical stability. The improvement resides in the use of anions of salts of the formula comprising: i) (B 12 F x Z 12-x ) 2- wherein Z comprises at least one of H, Cl, Br or OR; R comprises at least one of H, alkyl or fluoroalkyl, or at least one polymer and x is at least 3 on an average basis but not more than 12; ii) ((R'R''R''')NB 12 F x Z (11-x) ) - , wherein N is bonded to B and each of R', R", R''' comprise a member independently selected from the group consisting of hydrogen, alkyl, cycloalkyl, aryl and a polymer; Z comprises H, Cl, Br, or OR, where R comprises H, alkyl or perfluoroalkyl or a polymer, and x is an integer from 0 to 11; or iii) (R""CB 11 F x Z (11-x) ) - , wherein R"" is bonded to C and comprises a member selected from the group consisting of hydrogen, alkyl, cycloalkyl, aryl, and a polymer, Z comprises H, Cl, Br, or OR, wherein R comprises H, alkyl or perfluoroalkyl or a polymer, and x is an integer from 0 to 11.
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The improvement resides in the use of anions of salts of the formula comprising: i) (B 12 F x Z 12-x ) 2- wherein Z comprises at least one of H, Cl, Br or OR; R comprises at least one of H, alkyl or fluoroalkyl, or at least one polymer and x is at least 3 on an average basis but not more than 12; ii) ((R'R''R''')NB 12 F x Z (11-x) ) - , wherein N is bonded to B and each of R', R", R''' comprise a member independently selected from the group consisting of hydrogen, alkyl, cycloalkyl, aryl and a polymer; Z comprises H, Cl, Br, or OR, where R comprises H, alkyl or perfluoroalkyl or a polymer, and x is an integer from 0 to 11; or iii) (R""CB 11 F x Z (11-x) ) - , wherein R"" is bonded to C and comprises a member selected from the group consisting of hydrogen, alkyl, cycloalkyl, aryl, and a polymer, Z comprises H, Cl, Br, or OR, wherein R comprises H, alkyl or perfluoroalkyl or a polymer, and x is an integer from 0 to 11.</abstract><oa>free_for_read</oa></addata></record>
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language eng ; fre ; ger
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subjects APPARATUS THEREFOR
BASIC ELECTRIC ELEMENTS
CABLES
CAPACITORS
CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES ORLIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
CHEMISTRY
CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TOTRANSPORTATION
CONDUCTORS
ELECTRICITY
ELECTROLYTIC OR ELECTROPHORETIC PROCESSES
ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTIONOF COMPOUNDS OR NON-METALS
GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS
INSULATORS
METALLURGY
PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY
SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING ORDIELECTRIC PROPERTIES
TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE
title Stable electrolyte counteranions for capacitors
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