Ammoxidation of a mixture of ketones to acetonitrile and hydrogen cyanide

A process increasing the yield of both HCN and acetonitrile produced during the manufacture of acrylonitrile comprising introducing a hydrocarbon selected from the group consisting of propylene and propane, a crude ketone and/or a mixture of at least two ketones, ammonia and air, into a reaction zon...

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Hauptverfasser: SEELEY, MICHAEL J, SURESH, DEV D, GODBOLE, SANJAY P
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creator SEELEY, MICHAEL J
SURESH, DEV D
GODBOLE, SANJAY P
description A process increasing the yield of both HCN and acetonitrile produced during the manufacture of acrylonitrile comprising introducing a hydrocarbon selected from the group consisting of propylene and propane, a crude ketone and/or a mixture of at least two ketones, ammonia and air, into a reaction zone containing an ammoxidation catalyst, reacting the hydrocarbon, the ketone, ammonia and oxygen over said catalyst at an elevated temperature to produce acrylonitrile, hydrogen cyanide and acetonitrile, and recovering the acrylonitrile, hydrogen cyanide and acetonitrile from the reactor.
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
AMMONIA
APPARATUS THEREFOR
CHEMISTRY
COMPOUNDS THEREOF
CYANOGEN
GENERAL METHODS OF ORGANIC CHEMISTRY
INORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
title Ammoxidation of a mixture of ketones to acetonitrile and hydrogen cyanide
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