FISCHER-TROPSCH SUPPORTED CATALYST ACTIVATION
A process for activating a supported metal catalyst or catalyst precursor useful for the hydrogenation of carbon monoxide to form a mixture of hydrocarbons, comprising reducing with a hydrogen-containing gas at elevated temperature so that at least a portion is in the metallic state, impregnating un...
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creator | CLARK, JANET, RENEE DAAGE, MICHEL KOVEAL, RUSSELL, JOHN |
description | A process for activating a supported metal catalyst or catalyst precursor useful for the hydrogenation of carbon monoxide to form a mixture of hydrocarbons, comprising reducing with a hydrogen-containing gas at elevated temperature so that at least a portion is in the metallic state, impregnating under a non-oxidizing atmosphere with a solution of at least one member selected from the group consisting of ammonium salts, alkyl ammonium salts and weak organic acids, optionally further including ammonia, to the point where it has absorbed a volume of solution equal to at least about 10% of its calculated pore volume, oxidizing with a gaseous oxidant in the presence of the impregnating solution and reducing with hydrogen-containing gas at elevated temperatures to form an active catalyst. The steps beginning with the impregnation may be repeated. Optionally, the catalyst may be calcined after the oxidation step and/or passivated after activation. |
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The steps beginning with the impregnation may be repeated. Optionally, the catalyst may be calcined after the oxidation step and/or passivated after activation.</description><language>eng ; fre ; ger</language><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS ; APPARATUS THEREFOR ; CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY ; CHEMISTRY ; CRACKING HYDROCARBON OILS ; FUELS ; GENERAL METHODS OF ORGANIC CHEMISTRY ; LUBRICANTS ; METALLURGY ; MINERAL WAXES ; ORGANIC CHEMISTRY ; PEAT ; PERFORMING OPERATIONS ; PETROLEUM, GAS OR COKE INDUSTRIES ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION ; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES ; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS ; REFORMING OF NAPHTHA ; TECHNICAL GASES CONTAINING CARBON MONOXIDE ; THEIR RELEVANT APPARATUS ; TRANSPORTING</subject><creationdate>2006</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20060913&DB=EPODOC&CC=EP&NR=1480743B1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20060913&DB=EPODOC&CC=EP&NR=1480743B1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>CLARK, JANET, RENEE</creatorcontrib><creatorcontrib>DAAGE, MICHEL</creatorcontrib><creatorcontrib>KOVEAL, RUSSELL, JOHN</creatorcontrib><title>FISCHER-TROPSCH SUPPORTED CATALYST ACTIVATION</title><description>A process for activating a supported metal catalyst or catalyst precursor useful for the hydrogenation of carbon monoxide to form a mixture of hydrocarbons, comprising reducing with a hydrogen-containing gas at elevated temperature so that at least a portion is in the metallic state, impregnating under a non-oxidizing atmosphere with a solution of at least one member selected from the group consisting of ammonium salts, alkyl ammonium salts and weak organic acids, optionally further including ammonia, to the point where it has absorbed a volume of solution equal to at least about 10% of its calculated pore volume, oxidizing with a gaseous oxidant in the presence of the impregnating solution and reducing with hydrogen-containing gas at elevated temperatures to form an active catalyst. The steps beginning with the impregnation may be repeated. Optionally, the catalyst may be calcined after the oxidation step and/or passivated after activation.</description><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS</subject><subject>APPARATUS THEREFOR</subject><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</subject><subject>CHEMISTRY</subject><subject>CRACKING HYDROCARBON OILS</subject><subject>FUELS</subject><subject>GENERAL METHODS OF ORGANIC CHEMISTRY</subject><subject>LUBRICANTS</subject><subject>METALLURGY</subject><subject>MINERAL WAXES</subject><subject>ORGANIC CHEMISTRY</subject><subject>PEAT</subject><subject>PERFORMING OPERATIONS</subject><subject>PETROLEUM, GAS OR COKE INDUSTRIES</subject><subject>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</subject><subject>PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION</subject><subject>RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES</subject><subject>REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS</subject><subject>REFORMING OF NAPHTHA</subject><subject>TECHNICAL GASES CONTAINING CARBON MONOXIDE</subject><subject>THEIR RELEVANT APPARATUS</subject><subject>TRANSPORTING</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2006</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZNB18wx29nAN0g0J8g8AshSCQwMC_INCXF0UnB1DHH0ig0MUHJ1DPMMcQzz9_XgYWNMSc4pTeaE0N4OCm2uIs4duakF-fGpxQWJyal5qSbxrgKGJhYG5ibGToTERSgCmliWF</recordid><startdate>20060913</startdate><enddate>20060913</enddate><creator>CLARK, JANET, RENEE</creator><creator>DAAGE, MICHEL</creator><creator>KOVEAL, RUSSELL, JOHN</creator><scope>EVB</scope></search><sort><creationdate>20060913</creationdate><title>FISCHER-TROPSCH SUPPORTED CATALYST ACTIVATION</title><author>CLARK, JANET, RENEE ; DAAGE, MICHEL ; KOVEAL, RUSSELL, JOHN</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_EP1480743B13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; fre ; ger</language><creationdate>2006</creationdate><topic>ACYCLIC OR CARBOCYCLIC COMPOUNDS</topic><topic>APPARATUS THEREFOR</topic><topic>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</topic><topic>CHEMISTRY</topic><topic>CRACKING HYDROCARBON OILS</topic><topic>FUELS</topic><topic>GENERAL METHODS OF ORGANIC CHEMISTRY</topic><topic>LUBRICANTS</topic><topic>METALLURGY</topic><topic>MINERAL WAXES</topic><topic>ORGANIC CHEMISTRY</topic><topic>PEAT</topic><topic>PERFORMING OPERATIONS</topic><topic>PETROLEUM, GAS OR COKE INDUSTRIES</topic><topic>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</topic><topic>PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION</topic><topic>RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES</topic><topic>REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS</topic><topic>REFORMING OF NAPHTHA</topic><topic>TECHNICAL GASES CONTAINING CARBON MONOXIDE</topic><topic>THEIR RELEVANT APPARATUS</topic><topic>TRANSPORTING</topic><toplevel>online_resources</toplevel><creatorcontrib>CLARK, JANET, RENEE</creatorcontrib><creatorcontrib>DAAGE, MICHEL</creatorcontrib><creatorcontrib>KOVEAL, RUSSELL, JOHN</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>CLARK, JANET, RENEE</au><au>DAAGE, MICHEL</au><au>KOVEAL, RUSSELL, JOHN</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>FISCHER-TROPSCH SUPPORTED CATALYST ACTIVATION</title><date>2006-09-13</date><risdate>2006</risdate><abstract>A process for activating a supported metal catalyst or catalyst precursor useful for the hydrogenation of carbon monoxide to form a mixture of hydrocarbons, comprising reducing with a hydrogen-containing gas at elevated temperature so that at least a portion is in the metallic state, impregnating under a non-oxidizing atmosphere with a solution of at least one member selected from the group consisting of ammonium salts, alkyl ammonium salts and weak organic acids, optionally further including ammonia, to the point where it has absorbed a volume of solution equal to at least about 10% of its calculated pore volume, oxidizing with a gaseous oxidant in the presence of the impregnating solution and reducing with hydrogen-containing gas at elevated temperatures to form an active catalyst. The steps beginning with the impregnation may be repeated. Optionally, the catalyst may be calcined after the oxidation step and/or passivated after activation.</abstract><oa>free_for_read</oa></addata></record> |
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language | eng ; fre ; ger |
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subjects | ACYCLIC OR CARBOCYCLIC COMPOUNDS APPARATUS THEREFOR CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY CRACKING HYDROCARBON OILS FUELS GENERAL METHODS OF ORGANIC CHEMISTRY LUBRICANTS METALLURGY MINERAL WAXES ORGANIC CHEMISTRY PEAT PERFORMING OPERATIONS PETROLEUM, GAS OR COKE INDUSTRIES PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS REFORMING OF NAPHTHA TECHNICAL GASES CONTAINING CARBON MONOXIDE THEIR RELEVANT APPARATUS TRANSPORTING |
title | FISCHER-TROPSCH SUPPORTED CATALYST ACTIVATION |
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