Process for producing benzyl acetate and benzyl alcohol
A process is provided wherein benzyl alcohol which cannot readily be isolated and purified from the hydrolysis product of benzyl acetate can be produced economically by constructing an isolation-purification process in consideration of the azeotropy of the components including benzyl alcohol and ace...
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creator | NAGIRA, NOBUO HANAYA, MAKOTO HATTORI, AKITAKA IKUMI, SHUNYA MIZUI, NORIMASA HORI, TAKASHI MIYAKE, TAKANORI OKADA, TAKASHI |
description | A process is provided wherein benzyl alcohol which cannot readily be isolated and purified from the hydrolysis product of benzyl acetate can be produced economically by constructing an isolation-purification process in consideration of the azeotropy of the components including benzyl alcohol and acetic acid as hydrolysis products, unreacted benzyl acetate and water, and recycling the process fractions to the specified process, and by using, as the catalyst, a sulfonated styrenedivinylbenzene copolymer having divinylbenzene units in a specified content range, and by reacting the starting materials in a specific ratio. Moreover, according to the present application, benzyl alcohol can be produced economically by transesterification of benzyl acetate with methanol in the presence of a basic catalyst, and combining process fractions reasonably in consideration of the later isolation-purification process. |
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Moreover, according to the present application, benzyl alcohol can be produced economically by transesterification of benzyl acetate with methanol in the presence of a basic catalyst, and combining process fractions reasonably in consideration of the later isolation-purification process.</description><edition>7</edition><language>eng ; fre ; ger</language><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS ; BEER ; BIOCHEMISTRY ; BREWING OF BEER ; CHEMISTRY ; CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION ORPROCESSING OF GOODS ; ENZYMOLOGY ; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC ; GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS ; METALLURGY ; MICROBIOLOGY ; MUTATION OR GENETIC ENGINEERING ; ORGANIC CHEMISTRY ; SPIRITS ; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS ; TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE ; VINEGAR ; WINE</subject><creationdate>2002</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20020502&DB=EPODOC&CC=EP&NR=1199299A3$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20020502&DB=EPODOC&CC=EP&NR=1199299A3$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>NAGIRA, NOBUO</creatorcontrib><creatorcontrib>HANAYA, MAKOTO</creatorcontrib><creatorcontrib>HATTORI, AKITAKA</creatorcontrib><creatorcontrib>IKUMI, SHUNYA</creatorcontrib><creatorcontrib>MIZUI, NORIMASA</creatorcontrib><creatorcontrib>HORI, TAKASHI</creatorcontrib><creatorcontrib>MIYAKE, TAKANORI</creatorcontrib><creatorcontrib>OKADA, TAKASHI</creatorcontrib><title>Process for producing benzyl acetate and benzyl alcohol</title><description>A process is provided wherein benzyl alcohol which cannot readily be isolated and purified from the hydrolysis product of benzyl acetate can be produced economically by constructing an isolation-purification process in consideration of the azeotropy of the components including benzyl alcohol and acetic acid as hydrolysis products, unreacted benzyl acetate and water, and recycling the process fractions to the specified process, and by using, as the catalyst, a sulfonated styrenedivinylbenzene copolymer having divinylbenzene units in a specified content range, and by reacting the starting materials in a specific ratio. 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language | eng ; fre ; ger |
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subjects | ACYCLIC OR CARBOCYCLIC COMPOUNDS BEER BIOCHEMISTRY BREWING OF BEER CHEMISTRY CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION ORPROCESSING OF GOODS ENZYMOLOGY GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS METALLURGY MICROBIOLOGY MUTATION OR GENETIC ENGINEERING ORGANIC CHEMISTRY SPIRITS TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE VINEGAR WINE |
title | Process for producing benzyl acetate and benzyl alcohol |
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