Toner and resin composition for the toner
A toner is constituted by at least a binder resin, a colorant and a wax. The binder resin has been formed from monomers including a vinyl monomer and polyester-forming monomers containing at least a polybasic carboxylic acid having three or more carboxyl groups or its anhydride, and comprises at lea...
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creator | KASUYA, TAKASHIGE KARAKI, YUKI YUSA, HIROSHI OGAWA, YOSHIHIRO |
description | A toner is constituted by at least a binder resin, a colorant and a wax. The binder resin has been formed from monomers including a vinyl monomer and polyester-forming monomers containing at least a polybasic carboxylic acid having three or more carboxyl groups or its anhydride, and comprises at least a hybrid resin comprising a vinyl polymer unit and a polyester unit. The toner contains a THF (tetrahydrofuran)-soluble content which includes a first component having molecular weights of below 1x10 containing W1 (mol. %) of the polybasic carboxylic acid and its anhydride based on the polyester-forming monomers contained in the first component and a second component having molecular weight of at least 1x10 containing W2 (mol. %) of the polybasic carboxylic acid and its anhydride based on the polyester-forming monomers contained in the second component, W1 and W2 satisfying the following relationship: 0 W1. The THF-soluble content provides a GPC (gel permeation chromatography) chromatogram including 40 - 70 wt. % (M1) of a component having molecular weights of below 1x10 , 25 - 50 wt. % (M2) of a component having molecular weights of 1x10 - 5x10 , 2 - 25 wt. % (M3) of a component having molecular weights of above 5x10 , and below 10 wt. % (M4) of a component having molecular weights of at least 10x10 , M1, M2 and M3 satisfying the following relationship: M1 >/= M2 > M3. |
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The binder resin has been formed from monomers including a vinyl monomer and polyester-forming monomers containing at least a polybasic carboxylic acid having three or more carboxyl groups or its anhydride, and comprises at least a hybrid resin comprising a vinyl polymer unit and a polyester unit. The toner contains a THF (tetrahydrofuran)-soluble content which includes a first component having molecular weights of below 1x10 containing W1 (mol. %) of the polybasic carboxylic acid and its anhydride based on the polyester-forming monomers contained in the first component and a second component having molecular weight of at least 1x10 containing W2 (mol. %) of the polybasic carboxylic acid and its anhydride based on the polyester-forming monomers contained in the second component, W1 and W2 satisfying the following relationship: 0 </= W1 < 30, 0 < W2 < 50, and W2 > W1. The THF-soluble content provides a GPC (gel permeation chromatography) chromatogram including 40 - 70 wt. % (M1) of a component having molecular weights of below 1x10 , 25 - 50 wt. % (M2) of a component having molecular weights of 1x10 - 5x10 , 2 - 25 wt. % (M3) of a component having molecular weights of above 5x10 , and below 10 wt. % (M4) of a component having molecular weights of at least 10x10 , M1, M2 and M3 satisfying the following relationship: M1 >/= M2 > M3.</description><edition>7</edition><language>eng ; fre ; ger</language><subject>CINEMATOGRAPHY ; ELECTROGRAPHY ; ELECTROPHOTOGRAPHY ; HOLOGRAPHY ; MAGNETOGRAPHY ; PHOTOGRAPHY ; PHYSICS</subject><creationdate>2004</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20040407&DB=EPODOC&CC=EP&NR=1096326B1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25542,76516</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20040407&DB=EPODOC&CC=EP&NR=1096326B1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>KASUYA, TAKASHIGE</creatorcontrib><creatorcontrib>KARAKI, YUKI</creatorcontrib><creatorcontrib>YUSA, HIROSHI</creatorcontrib><creatorcontrib>OGAWA, YOSHIHIRO</creatorcontrib><title>Toner and resin composition for the toner</title><description>A toner is constituted by at least a binder resin, a colorant and a wax. 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The binder resin has been formed from monomers including a vinyl monomer and polyester-forming monomers containing at least a polybasic carboxylic acid having three or more carboxyl groups or its anhydride, and comprises at least a hybrid resin comprising a vinyl polymer unit and a polyester unit. The toner contains a THF (tetrahydrofuran)-soluble content which includes a first component having molecular weights of below 1x10 containing W1 (mol. %) of the polybasic carboxylic acid and its anhydride based on the polyester-forming monomers contained in the first component and a second component having molecular weight of at least 1x10 containing W2 (mol. %) of the polybasic carboxylic acid and its anhydride based on the polyester-forming monomers contained in the second component, W1 and W2 satisfying the following relationship: 0 </= W1 < 30, 0 < W2 < 50, and W2 > W1. The THF-soluble content provides a GPC (gel permeation chromatography) chromatogram including 40 - 70 wt. % (M1) of a component having molecular weights of below 1x10 , 25 - 50 wt. % (M2) of a component having molecular weights of 1x10 - 5x10 , 2 - 25 wt. % (M3) of a component having molecular weights of above 5x10 , and below 10 wt. % (M4) of a component having molecular weights of at least 10x10 , M1, M2 and M3 satisfying the following relationship: M1 >/= M2 > M3.</abstract><edition>7</edition><oa>free_for_read</oa></addata></record> |
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subjects | CINEMATOGRAPHY ELECTROGRAPHY ELECTROPHOTOGRAPHY HOLOGRAPHY MAGNETOGRAPHY PHOTOGRAPHY PHYSICS |
title | Toner and resin composition for the toner |
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