ETHYLENE/ALPHA-OLEFIN/UNCONJUGATED POLYENE COPOLYMER RUBBER, RUBBER COMPOSITION FOR SEALING, MOLDED RUBBER FOR SEALING, AND PROCESS FOR PRODUCING THE MOLDED RUBBER PART
The present invention relates to an ethylene- alpha -olefin-non-conjugated polyene copolymer rubber comprising ethylene, an alpha -olefin having 3 to 20 carbon atoms and a non-conjugated polyene, characterized in that: (i) the intrinsic viscosity Ä eta Ü as measured in decalin solvent at 135 DEG C i...
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creator | KODA, TAKU KAWASAKI, MASAAKI |
description | The present invention relates to an ethylene- alpha -olefin-non-conjugated polyene copolymer rubber comprising ethylene, an alpha -olefin having 3 to 20 carbon atoms and a non-conjugated polyene, characterized in that: (i) the intrinsic viscosity Ä eta Ü as measured in decalin solvent at 135 DEG C is 1.5 to 5.0 dl/g; (ii) the g eta * or g' value is 0.6 to 0.9, wherein the g eta * value is defined as a ratio of the intrinsic viscosity Ä eta Ü as measured in (i) above to an intrinsic viscosity Ä eta Üblank as measured in decalin solvent at 135 DEG C of a linear ethylene-propylene copolymer having an ethylene content of 70% by mole which has the same weight average molecular weight (according to light scattering method) as the ethylene- alpha -olefin-non-conjugated polyene copolymer rubber having the intrinsic viscosity Ä eta Ü (Ä eta Ü/Ä eta Üblank), and the g' value is defined as a ratio of the intrinsic viscosity Ä eta Ü as measured in (i) above to an intrinsic viscosity Ä eta Üblank' as reduced to a linear ethylene-propylene copolymer having an ethylene content of 70% by mole, which is determined by gel permeation chromatography (140 DEG C, o-dichlorobenzene solvent) of the ethylene- alpha -olefin-non-conjugated polyene copolymer (g'=Ä eta Ü/Ä eta Üblank'); (iii) the Mw/Mn is 3.0 to 50; (iv) the iodine value is 10 to 40; (v) the molar ratio of ethylene to the alpha -olefin having 3 to 20 carbon atoms is 40/60 to 95/5; and (vi) the intensity ratio D of T alpha beta to T alpha alpha in C-NMR spectrum (T alpha beta /T alpha alpha ) is 0.5 or less, as well as to a rubber composition for sealing using said copolymer rubber, a molded rubber part for sealing, and a process for preparing said molded part. |
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(ii) the g eta * or g' value is 0.6 to 0.9, wherein the g eta * value is defined as a ratio of the intrinsic viscosity Ä eta Ü as measured in (i) above to an intrinsic viscosity Ä eta Üblank as measured in decalin solvent at 135 DEG C of a linear ethylene-propylene copolymer having an ethylene content of 70% by mole which has the same weight average molecular weight (according to light scattering method) as the ethylene- alpha -olefin-non-conjugated polyene copolymer rubber having the intrinsic viscosity Ä eta Ü (Ä eta Ü/Ä eta Üblank), and the g' value is defined as a ratio of the intrinsic viscosity Ä eta Ü as measured in (i) above to an intrinsic viscosity Ä eta Üblank' as reduced to a linear ethylene-propylene copolymer having an ethylene content of 70% by mole, which is determined by gel permeation chromatography (140 DEG C, o-dichlorobenzene solvent) of the ethylene- alpha -olefin-non-conjugated polyene copolymer (g'=Ä eta Ü/Ä eta Üblank'); (iii) the Mw/Mn is 3.0 to 50; (iv) the iodine value is 10 to 40; (v) the molar ratio of ethylene to the alpha -olefin having 3 to 20 carbon atoms is 40/60 to 95/5; and (vi) the intensity ratio D of T alpha beta to T alpha alpha in C-NMR spectrum (T alpha beta /T alpha alpha ) is 0.5 or less, as well as to a rubber composition for sealing using said copolymer rubber, a molded rubber part for sealing, and a process for preparing said molded part.</description><language>eng ; fre ; ger</language><subject>ADHESIVES ; CHEMISTRY ; COMPOSITIONS BASED THEREON ; COMPOSITIONS OF MACROMOLECULAR COMPOUNDS ; DYES ; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS ; MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE ; METALLURGY ; MISCELLANEOUS APPLICATIONS OF MATERIALS ; MISCELLANEOUS COMPOSITIONS ; NATURAL RESINS ; ORGANIC MACROMOLECULAR COMPOUNDS ; PAINTS ; POLISHES ; THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><creationdate>2012</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20121121&DB=EPODOC&CC=EP&NR=1088836B1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25543,76293</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20121121&DB=EPODOC&CC=EP&NR=1088836B1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>KODA, TAKU</creatorcontrib><creatorcontrib>KAWASAKI, MASAAKI</creatorcontrib><title>ETHYLENE/ALPHA-OLEFIN/UNCONJUGATED POLYENE COPOLYMER RUBBER, RUBBER COMPOSITION FOR SEALING, MOLDED RUBBER FOR SEALING, AND PROCESS FOR PRODUCING THE MOLDED RUBBER PART</title><description>The present invention relates to an ethylene- alpha -olefin-non-conjugated polyene copolymer rubber comprising ethylene, an alpha -olefin having 3 to 20 carbon atoms and a non-conjugated polyene, characterized in that: (i) the intrinsic viscosity Ä eta Ü as measured in decalin solvent at 135 DEG C is 1.5 to 5.0 dl/g; (ii) the g eta * or g' value is 0.6 to 0.9, wherein the g eta * value is defined as a ratio of the intrinsic viscosity Ä eta Ü as measured in (i) above to an intrinsic viscosity Ä eta Üblank as measured in decalin solvent at 135 DEG C of a linear ethylene-propylene copolymer having an ethylene content of 70% by mole which has the same weight average molecular weight (according to light scattering method) as the ethylene- alpha -olefin-non-conjugated polyene copolymer rubber having the intrinsic viscosity Ä eta Ü (Ä eta Ü/Ä eta Üblank), and the g' value is defined as a ratio of the intrinsic viscosity Ä eta Ü as measured in (i) above to an intrinsic viscosity Ä eta Üblank' as reduced to a linear ethylene-propylene copolymer having an ethylene content of 70% by mole, which is determined by gel permeation chromatography (140 DEG C, o-dichlorobenzene solvent) of the ethylene- alpha -olefin-non-conjugated polyene copolymer (g'=Ä eta Ü/Ä eta Üblank'); (iii) the Mw/Mn is 3.0 to 50; (iv) the iodine value is 10 to 40; (v) the molar ratio of ethylene to the alpha -olefin having 3 to 20 carbon atoms is 40/60 to 95/5; and (vi) the intensity ratio D of T alpha beta to T alpha alpha in C-NMR spectrum (T alpha beta /T alpha alpha ) is 0.5 or less, as well as to a rubber composition for sealing using said copolymer rubber, a molded rubber part for sealing, and a process for preparing said molded part.</description><subject>ADHESIVES</subject><subject>CHEMISTRY</subject><subject>COMPOSITIONS BASED THEREON</subject><subject>COMPOSITIONS OF MACROMOLECULAR COMPOUNDS</subject><subject>DYES</subject><subject>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</subject><subject>MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE</subject><subject>METALLURGY</subject><subject>MISCELLANEOUS APPLICATIONS OF MATERIALS</subject><subject>MISCELLANEOUS COMPOSITIONS</subject><subject>NATURAL RESINS</subject><subject>ORGANIC MACROMOLECULAR COMPOUNDS</subject><subject>PAINTS</subject><subject>POLISHES</subject><subject>THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2012</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNqNjL0KwjAUhbs4iPoOeYCWWgTpmqa3TSTNDfkZOpUicRIt1IfyMY3SRSenc-D7zlknT3C8l6Agp1JzmqGERqjcK4bq5FvqoCYaZR8NwvDdOjDE-KoCky4ZQafRCidQkQYNsUClUG1KOpR1PFi0L0RVPDbIwNoPiL32LCLiOPwMNTVum6wu43UOuyU3CWnAMZ6F6T6EeRrP4RYeA-hiX5bl4VgVhz-UF0McRsA</recordid><startdate>20121121</startdate><enddate>20121121</enddate><creator>KODA, TAKU</creator><creator>KAWASAKI, MASAAKI</creator><scope>EVB</scope></search><sort><creationdate>20121121</creationdate><title>ETHYLENE/ALPHA-OLEFIN/UNCONJUGATED POLYENE COPOLYMER RUBBER, RUBBER COMPOSITION FOR SEALING, MOLDED RUBBER FOR SEALING, AND PROCESS FOR PRODUCING THE MOLDED RUBBER PART</title><author>KODA, TAKU ; KAWASAKI, MASAAKI</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_EP1088836B13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; fre ; ger</language><creationdate>2012</creationdate><topic>ADHESIVES</topic><topic>CHEMISTRY</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>COMPOSITIONS OF MACROMOLECULAR COMPOUNDS</topic><topic>DYES</topic><topic>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</topic><topic>MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE</topic><topic>METALLURGY</topic><topic>MISCELLANEOUS APPLICATIONS OF MATERIALS</topic><topic>MISCELLANEOUS COMPOSITIONS</topic><topic>NATURAL RESINS</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>PAINTS</topic><topic>POLISHES</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><toplevel>online_resources</toplevel><creatorcontrib>KODA, TAKU</creatorcontrib><creatorcontrib>KAWASAKI, MASAAKI</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>KODA, TAKU</au><au>KAWASAKI, MASAAKI</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>ETHYLENE/ALPHA-OLEFIN/UNCONJUGATED POLYENE COPOLYMER RUBBER, RUBBER COMPOSITION FOR SEALING, MOLDED RUBBER FOR SEALING, AND PROCESS FOR PRODUCING THE MOLDED RUBBER PART</title><date>2012-11-21</date><risdate>2012</risdate><abstract>The present invention relates to an ethylene- alpha -olefin-non-conjugated polyene copolymer rubber comprising ethylene, an alpha -olefin having 3 to 20 carbon atoms and a non-conjugated polyene, characterized in that: (i) the intrinsic viscosity Ä eta Ü as measured in decalin solvent at 135 DEG C is 1.5 to 5.0 dl/g; (ii) the g eta * or g' value is 0.6 to 0.9, wherein the g eta * value is defined as a ratio of the intrinsic viscosity Ä eta Ü as measured in (i) above to an intrinsic viscosity Ä eta Üblank as measured in decalin solvent at 135 DEG C of a linear ethylene-propylene copolymer having an ethylene content of 70% by mole which has the same weight average molecular weight (according to light scattering method) as the ethylene- alpha -olefin-non-conjugated polyene copolymer rubber having the intrinsic viscosity Ä eta Ü (Ä eta Ü/Ä eta Üblank), and the g' value is defined as a ratio of the intrinsic viscosity Ä eta Ü as measured in (i) above to an intrinsic viscosity Ä eta Üblank' as reduced to a linear ethylene-propylene copolymer having an ethylene content of 70% by mole, which is determined by gel permeation chromatography (140 DEG C, o-dichlorobenzene solvent) of the ethylene- alpha -olefin-non-conjugated polyene copolymer (g'=Ä eta Ü/Ä eta Üblank'); (iii) the Mw/Mn is 3.0 to 50; (iv) the iodine value is 10 to 40; (v) the molar ratio of ethylene to the alpha -olefin having 3 to 20 carbon atoms is 40/60 to 95/5; and (vi) the intensity ratio D of T alpha beta to T alpha alpha in C-NMR spectrum (T alpha beta /T alpha alpha ) is 0.5 or less, as well as to a rubber composition for sealing using said copolymer rubber, a molded rubber part for sealing, and a process for preparing said molded part.</abstract><oa>free_for_read</oa></addata></record> |
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subjects | ADHESIVES CHEMISTRY COMPOSITIONS BASED THEREON COMPOSITIONS OF MACROMOLECULAR COMPOUNDS DYES MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS ORGANIC MACROMOLECULAR COMPOUNDS PAINTS POLISHES THEIR PREPARATION OR CHEMICAL WORKING-UP |
title | ETHYLENE/ALPHA-OLEFIN/UNCONJUGATED POLYENE COPOLYMER RUBBER, RUBBER COMPOSITION FOR SEALING, MOLDED RUBBER FOR SEALING, AND PROCESS FOR PRODUCING THE MOLDED RUBBER PART |
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