METHOD FOR PRODUCING SOLVENT-FREE POLYVINYL ESTER DISPERSIONS WITH GREATER RESISTANCE TO WATER

The present invention relates to the preparation of heterogeneous, water-resistant polyvinyl ester dispersions having a film-forming temperature of below 10 DEG C., comprising the formation of a homo- or copolymer A, having a glass transistion temperature of more that 20 DEG C., by seed polymerizati...

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Hauptverfasser: JAKOB, MARTIN, PRASS, WERNER
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PRASS, WERNER
description The present invention relates to the preparation of heterogeneous, water-resistant polyvinyl ester dispersions having a film-forming temperature of below 10 DEG C., comprising the formation of a homo- or copolymer A, having a glass transistion temperature of more that 20 DEG C., by seed polymerization of a monomer mixture comprising 85-100% by weight of a vinyl ester of carboxylic acids having 1 to 18 carbon atoms, 0-10% by weight of an alpha , beta -unsaturated carboxylic acid and/or of an N-functional compound and 0-5% by weight of a polyethylenically unsaturated monomer in the presence of a seed base comprising a copolymer B having a glass transition temperature of below 20 DEG C., comprising 45-98% by weight of a vinyl ester of carboxylic acids having 1 to 18 carbon atoms, 2-50% by weight of an alpha -olefin having 1 to 4 carbon atoms and 0-5% by weight of a polyethylenically unsaturated monomer.
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subjects ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE
ADHESIVES
CHEMISTRY
COMPOSITIONS BASED THEREON
DYES
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
NATURAL RESINS
NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL
ORGANIC MACROMOLECULAR COMPOUNDS
PAINTS
POLISHES
THEIR PREPARATION OR CHEMICAL WORKING-UP
USE OF MATERIALS AS ADHESIVES
title METHOD FOR PRODUCING SOLVENT-FREE POLYVINYL ESTER DISPERSIONS WITH GREATER RESISTANCE TO WATER
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