Chromophoric compounds and their preparation process

Chromophore, NLO-aktive Verbindungen der allgemeinen Formel 1 und Verfahren zur Herstellung solcher Verbindungen. Die erfindungsgemäßen Verbindungen können zur Herstellung von NLO-aktiven Polymeren und damit zum Aufbau von elektrooptischen und photonischen Bauelementen verwendet werden. New chromoph...

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Hauptverfasser: HARTMANN, HORST DR, KANITZ, ANDREAS DR, FRICKE, CHRISTIAN DR
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KANITZ, ANDREAS DR
FRICKE, CHRISTIAN DR
description Chromophore, NLO-aktive Verbindungen der allgemeinen Formel 1 und Verfahren zur Herstellung solcher Verbindungen. Die erfindungsgemäßen Verbindungen können zur Herstellung von NLO-aktiven Polymeren und damit zum Aufbau von elektrooptischen und photonischen Bauelementen verwendet werden. New chromophore compounds are 7-aminophenoxazines (I) with a condensed carbo- or heterocyclic ring substituted by an electron acceptor-substituted methylene or imino group. New chromophore compounds are 7-aminophenoxazines, with a condensed carbo- or heterocyclic ring substituted by an electron acceptor-substituted methylene or imino group, of formula (I); R , R , R , R , R = hydrogen (I), linear or branched 1-20 carbon (C) alkyl (optionally with 1-5 ether oxygen (O) atoms in the chain), aryl or heteroaryl; R , R can also = benzyl; or one of R , R = is hydroxyl (OH) or carboxyl; Z = an electron acceptor-substituted methylene or imino group; X = sulfur (S), O, NR , a ring double bond or a (hetero)cyclic group of formula (II): ; T = CH or N; or optionally Z and T together = a structure of the type =N-SO2-C=, =N-CS-C= or =N-CO-C=; Y = CR or N; R , R = H, linear or branched 1-20 C alkyl, phenyl or naphthyl. An Independent claim is also included for the preparation of (I).
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Die erfindungsgemäßen Verbindungen können zur Herstellung von NLO-aktiven Polymeren und damit zum Aufbau von elektrooptischen und photonischen Bauelementen verwendet werden. New chromophore compounds are 7-aminophenoxazines (I) with a condensed carbo- or heterocyclic ring substituted by an electron acceptor-substituted methylene or imino group. New chromophore compounds are 7-aminophenoxazines, with a condensed carbo- or heterocyclic ring substituted by an electron acceptor-substituted methylene or imino group, of formula (I); R , R , R , R , R = hydrogen (I), linear or branched 1-20 carbon (C) alkyl (optionally with 1-5 ether oxygen (O) atoms in the chain), aryl or heteroaryl; R , R can also = benzyl; or one of R , R = is hydroxyl (OH) or carboxyl; Z = an electron acceptor-substituted methylene or imino group; X = sulfur (S), O, NR , a ring double bond or a (hetero)cyclic group of formula (II): ; T = CH or N; or optionally Z and T together = a structure of the type =N-SO2-C=, =N-CS-C= or =N-CO-C=; Y = CR or N; R , R = H, linear or branched 1-20 C alkyl, phenyl or naphthyl. 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New chromophore compounds are 7-aminophenoxazines, with a condensed carbo- or heterocyclic ring substituted by an electron acceptor-substituted methylene or imino group, of formula (I); R , R , R , R , R = hydrogen (I), linear or branched 1-20 carbon (C) alkyl (optionally with 1-5 ether oxygen (O) atoms in the chain), aryl or heteroaryl; R , R can also = benzyl; or one of R , R = is hydroxyl (OH) or carboxyl; Z = an electron acceptor-substituted methylene or imino group; X = sulfur (S), O, NR , a ring double bond or a (hetero)cyclic group of formula (II): ; T = CH or N; or optionally Z and T together = a structure of the type =N-SO2-C=, =N-CS-C= or =N-CO-C=; Y = CR or N; R , R = H, linear or branched 1-20 C alkyl, phenyl or naphthyl. An Independent claim is also included for the preparation of (I).</abstract><edition>6</edition><oa>free_for_read</oa></addata></record>
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subjects ADHESIVES
CHEMISTRY
CINEMATOGRAPHY
DEVICES OR ARRANGEMENTS, THE OPTICAL OPERATION OF WHICH ISMODIFIED BY CHANGING THE OPTICAL PROPERTIES OF THE MEDIUM OF THEDEVICES OR ARRANGEMENTS FOR THE CONTROL OF THE INTENSITY,COLOUR, PHASE, POLARISATION OR DIRECTION OF LIGHT, e.g.SWITCHING, GATING, MODULATING OR DEMODULATING
DYES
ELECTROGRAPHY
ELECTROPHOTOGRAPHY
FREQUENCY-CHANGING
HETEROCYCLIC COMPOUNDS
HOLOGRAPHY
LAKES
MAGNETOGRAPHY
METALLURGY
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
MORDANTS
NATURAL RESINS
NON-LINEAR OPTICS
OPTICAL ANALOGUE/DIGITAL CONVERTERS
OPTICAL LOGIC ELEMENTS
OPTICS
ORGANIC CHEMISTRY
ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES
PAINTS
PHOTOGRAPHY
PHYSICS
POLISHES
TECHNIQUES OR PROCEDURES FOR THE OPERATION THEREOF
title Chromophoric compounds and their preparation process
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