Process for reclaiming used oil coolants

The treatment of used coolants comprises the addition of an alkali or acid to the oil to give a pH ≤ 3 or ≥ 10. By means of two electrodes the solution is then electrolysed using a voltage of 10-20 V, a current of 15-25 A and a current density of 1-5 A/dm . The consumption (C) is 15-25 wh/l. The emu...

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Hauptverfasser: IPINAZAR ALONSO, ENRIQUE, SOLOZABAL ECHEVARRIA, RODOLFO, ALAVA MARQUINEZ, INAKI, OTAOLA GONZALEZ, JOSE MARIA, MUGICA IRAOLA, JUAN CARLOS
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creator IPINAZAR ALONSO, ENRIQUE
SOLOZABAL ECHEVARRIA, RODOLFO
ALAVA MARQUINEZ, INAKI
OTAOLA GONZALEZ, JOSE MARIA
MUGICA IRAOLA, JUAN CARLOS
description The treatment of used coolants comprises the addition of an alkali or acid to the oil to give a pH ≤ 3 or ≥ 10. By means of two electrodes the solution is then electrolysed using a voltage of 10-20 V, a current of 15-25 A and a current density of 1-5 A/dm . The consumption (C) is 15-25 wh/l. The emulsion is destabilised and the separated oil can be withdrawn. 1-3 g/l of iron chloride (FeCl2) is added to the remaining liquid and the solution is electrolysed at 9-14 V and a current density ≥ 4 A/dm . The consumption is 60-100 wh/l and the final pH is ≤ 3 or ≥ 10. Alkali is then added to a pH of 8-9 and a muddy precipitate is obtained which is separated from a residual water effluent only slightly polluted by oil and organic compounds. Processus de traitement d'huiles usées de refroidissements, de celles contenant une émulsion eau-huile et une dissolution d'eau-composés organiques, qui se compose de trois phases consécutives : a) à l'huile de refroidissement on rajoute un alcali ou un acide jusqu'à obtenir un pH de : pH = 10, on électrolyse, l'émulsion devenant instable, ce qui permet que soit retirée l'huile flottante; b) en rajoutant au liquide restant, du chlorure de fer Cl2Fe en quantité de 1 ÷ 3 g/l et en électrolysant on obtient un pH final de pH = 10, pour procéder à, c) son alcalinisation pour arriver à un pH de 8
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By means of two electrodes the solution is then electrolysed using a voltage of 10-20 V, a current of 15-25 A and a current density of 1-5 A/dm . The consumption (C) is 15-25 wh/l. The emulsion is destabilised and the separated oil can be withdrawn. 1-3 g/l of iron chloride (FeCl2) is added to the remaining liquid and the solution is electrolysed at 9-14 V and a current density ≥ 4 A/dm . The consumption is 60-100 wh/l and the final pH is ≤ 3 or ≥ 10. Alkali is then added to a pH of 8-9 and a muddy precipitate is obtained which is separated from a residual water effluent only slightly polluted by oil and organic compounds. 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subjects CHEMISTRY
FUELS
LUBRICANTS
LUBRICATING COMPOSITIONS
METALLURGY
PEAT
PERFORMING OPERATIONS
PETROLEUM, GAS OR COKE INDUSTRIES
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
SEPARATION
TECHNICAL GASES CONTAINING CARBON MONOXIDE
TRANSPORTING
USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATINGINGREDIENTS IN A LUBRICATING COMPOSITION
title Process for reclaiming used oil coolants
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