Isoindolin pigments

Neue Isoindolinpigmente der Formel (I) worin R¹: die Bedeutung -CN hat und R² die Bedeutung CN oder ein 5- bis 7-gliedriger Heterocyclus; R³: Wasserstoff, C1-C4-Alkyl, Phenyl, C1-C4-Alkoxy, Halogen oder C2-C4-Acylamino; R : Wasserstoff, C1-C4-Alkyl, Halogen, Trifluormethyl, Methoxy, Ethoxy oder Nitr...

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Hauptverfasser: KAPAUN, GUSTAV, ALFTER, FRANK, DIETZ, ERWIN, SCHIESSLER, SIEGFRIED
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ALFTER, FRANK
DIETZ, ERWIN
SCHIESSLER, SIEGFRIED
description Neue Isoindolinpigmente der Formel (I) worin R¹: die Bedeutung -CN hat und R² die Bedeutung CN oder ein 5- bis 7-gliedriger Heterocyclus; R³: Wasserstoff, C1-C4-Alkyl, Phenyl, C1-C4-Alkoxy, Halogen oder C2-C4-Acylamino; R : Wasserstoff, C1-C4-Alkyl, Halogen, Trifluormethyl, Methoxy, Ethoxy oder Nitro bedeuten; m: eine Zahl von 1 bis 4 ist; n: eine Zahl von 1 bis 3 ist; und; R : Wasserstoff oder C1-C4-Alkyl bedeutet. Novel isoindoline pigments of formula (I) are claimed, as are also (i) prepn. of (I) by reacting an isoindoline of formula (II) having nucleophilically-exchangeable gps. X and Y in the 1- and 3-positions with a cpd. of formula (III) in which the H atoms of the -CH2- gp. are CH acids so as to give an intermediate of formula (IV) which is then reacted with a benzimidazolone of formula (V); and (ii) the use of (I) in pigmenting high mol. wt. organic materials. R = CN; R = (a) CN; (b) an (un)satd. (non)aromatic 5-7 membered N, O and/or S heterocyclic ring opt. modified by condensation or bridging to further heterocyclic or isocyclic ring systems; (c) -CONR R where R and R = H or 1-4C alkyl; or (d) -CONR R where R = unsubstd. or with at least 5 1-4C alkyl, halogen, CF3, 1-4C alkoxy, carbo(m)ethoxy or carbonamide- or with one 1-4C alkyl or phenyl gp.-substd. carbonamide, NO2, 1-4C alkylamino or OH-substd. (un)satd., (non)aromatic, iso- or hetero-cyclic (N, O and/or S) 5-7-membered ring opt. modified as per the ring of (b) above; or R and R together = ring as per (b) above opt. substd. as per (d) but excluding NO2; R = H, 1-4C alkyl, phenyl, 1-4C alkoxy, halogen or 1-4C acylamino; R = H, 1-4C alkyl, halogen, CF3, MeO, EtO or NO2; m = 1, 2, 3 or 4; n = 1, 2 or 3; and R = H or 1-4C alkyl.
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Novel isoindoline pigments of formula (I) are claimed, as are also (i) prepn. of (I) by reacting an isoindoline of formula (II) having nucleophilically-exchangeable gps. X and Y in the 1- and 3-positions with a cpd. of formula (III) in which the H atoms of the -CH2- gp. are CH acids so as to give an intermediate of formula (IV) which is then reacted with a benzimidazolone of formula (V); and (ii) the use of (I) in pigmenting high mol. wt. organic materials. R = CN; R = (a) CN; (b) an (un)satd. (non)aromatic 5-7 membered N, O and/or S heterocyclic ring opt. modified by condensation or bridging to further heterocyclic or isocyclic ring systems; (c) -CONR R where R and R = H or 1-4C alkyl; or (d) -CONR R where R = unsubstd. or with at least 5 1-4C alkyl, halogen, CF3, 1-4C alkoxy, carbo(m)ethoxy or carbonamide- or with one 1-4C alkyl or phenyl gp.-substd. carbonamide, NO2, 1-4C alkylamino or OH-substd. 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Novel isoindoline pigments of formula (I) are claimed, as are also (i) prepn. of (I) by reacting an isoindoline of formula (II) having nucleophilically-exchangeable gps. X and Y in the 1- and 3-positions with a cpd. of formula (III) in which the H atoms of the -CH2- gp. are CH acids so as to give an intermediate of formula (IV) which is then reacted with a benzimidazolone of formula (V); and (ii) the use of (I) in pigmenting high mol. wt. organic materials. R = CN; R = (a) CN; (b) an (un)satd. (non)aromatic 5-7 membered N, O and/or S heterocyclic ring opt. modified by condensation or bridging to further heterocyclic or isocyclic ring systems; (c) -CONR R where R and R = H or 1-4C alkyl; or (d) -CONR R where R = unsubstd. or with at least 5 1-4C alkyl, halogen, CF3, 1-4C alkoxy, carbo(m)ethoxy or carbonamide- or with one 1-4C alkyl or phenyl gp.-substd. carbonamide, NO2, 1-4C alkylamino or OH-substd. (un)satd., (non)aromatic, iso- or hetero-cyclic (N, O and/or S) 5-7-membered ring opt. modified as per the ring of (b) above; or R and R together = ring as per (b) above opt. substd. as per (d) but excluding NO2; R = H, 1-4C alkyl, phenyl, 1-4C alkoxy, halogen or 1-4C acylamino; R = H, 1-4C alkyl, halogen, CF3, MeO, EtO or NO2; m = 1, 2, 3 or 4; n = 1, 2 or 3; and R = H or 1-4C alkyl.</description><subject>ADHESIVES</subject><subject>CHEMISTRY</subject><subject>DYEING LEATHER, FURS, OR SOLID MACROMOLECULAR SUBSTANCES INANY FORM</subject><subject>DYEING OR PRINTING TEXTILES</subject><subject>DYES</subject><subject>FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR</subject><subject>LAKES</subject><subject>LAUNDERING</subject><subject>METALLURGY</subject><subject>MISCELLANEOUS APPLICATIONS OF MATERIALS</subject><subject>MISCELLANEOUS COMPOSITIONS</subject><subject>MORDANTS</subject><subject>NATURAL RESINS</subject><subject>ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES</subject><subject>PAINTS</subject><subject>POLISHES</subject><subject>TEXTILES</subject><subject>TREATMENT OF TEXTILES OR THE LIKE</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>1995</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZBD2LM7PzEvJz8nMUyjITM9NzSsp5mFgTUvMKU7lhdLcDApuriHOHrqpBfnxqcUFicmpeakl8a4BBmYWZmbmxo6GxkQoAQD93SBJ</recordid><startdate>19951213</startdate><enddate>19951213</enddate><creator>KAPAUN, GUSTAV</creator><creator>ALFTER, FRANK</creator><creator>DIETZ, ERWIN</creator><creator>SCHIESSLER, SIEGFRIED</creator><scope>EVB</scope></search><sort><creationdate>19951213</creationdate><title>Isoindolin pigments</title><author>KAPAUN, GUSTAV ; ALFTER, FRANK ; DIETZ, ERWIN ; SCHIESSLER, SIEGFRIED</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_EP0686673A13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; fre ; ger</language><creationdate>1995</creationdate><topic>ADHESIVES</topic><topic>CHEMISTRY</topic><topic>DYEING LEATHER, FURS, OR SOLID MACROMOLECULAR SUBSTANCES INANY FORM</topic><topic>DYEING OR PRINTING TEXTILES</topic><topic>DYES</topic><topic>FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR</topic><topic>LAKES</topic><topic>LAUNDERING</topic><topic>METALLURGY</topic><topic>MISCELLANEOUS APPLICATIONS OF MATERIALS</topic><topic>MISCELLANEOUS COMPOSITIONS</topic><topic>MORDANTS</topic><topic>NATURAL RESINS</topic><topic>ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES</topic><topic>PAINTS</topic><topic>POLISHES</topic><topic>TEXTILES</topic><topic>TREATMENT OF TEXTILES OR THE LIKE</topic><toplevel>online_resources</toplevel><creatorcontrib>KAPAUN, GUSTAV</creatorcontrib><creatorcontrib>ALFTER, FRANK</creatorcontrib><creatorcontrib>DIETZ, ERWIN</creatorcontrib><creatorcontrib>SCHIESSLER, SIEGFRIED</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>KAPAUN, GUSTAV</au><au>ALFTER, FRANK</au><au>DIETZ, ERWIN</au><au>SCHIESSLER, SIEGFRIED</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Isoindolin pigments</title><date>1995-12-13</date><risdate>1995</risdate><abstract>Neue Isoindolinpigmente der Formel (I) worin R¹: die Bedeutung -CN hat und R² die Bedeutung CN oder ein 5- bis 7-gliedriger Heterocyclus; R³: Wasserstoff, C1-C4-Alkyl, Phenyl, C1-C4-Alkoxy, Halogen oder C2-C4-Acylamino; R : Wasserstoff, C1-C4-Alkyl, Halogen, Trifluormethyl, Methoxy, Ethoxy oder Nitro bedeuten; m: eine Zahl von 1 bis 4 ist; n: eine Zahl von 1 bis 3 ist; und; R : Wasserstoff oder C1-C4-Alkyl bedeutet. Novel isoindoline pigments of formula (I) are claimed, as are also (i) prepn. of (I) by reacting an isoindoline of formula (II) having nucleophilically-exchangeable gps. X and Y in the 1- and 3-positions with a cpd. of formula (III) in which the H atoms of the -CH2- gp. are CH acids so as to give an intermediate of formula (IV) which is then reacted with a benzimidazolone of formula (V); and (ii) the use of (I) in pigmenting high mol. wt. organic materials. R = CN; R = (a) CN; (b) an (un)satd. (non)aromatic 5-7 membered N, O and/or S heterocyclic ring opt. modified by condensation or bridging to further heterocyclic or isocyclic ring systems; (c) -CONR R where R and R = H or 1-4C alkyl; or (d) -CONR R where R = unsubstd. or with at least 5 1-4C alkyl, halogen, CF3, 1-4C alkoxy, carbo(m)ethoxy or carbonamide- or with one 1-4C alkyl or phenyl gp.-substd. carbonamide, NO2, 1-4C alkylamino or OH-substd. (un)satd., (non)aromatic, iso- or hetero-cyclic (N, O and/or S) 5-7-membered ring opt. modified as per the ring of (b) above; or R and R together = ring as per (b) above opt. substd. as per (d) but excluding NO2; R = H, 1-4C alkyl, phenyl, 1-4C alkoxy, halogen or 1-4C acylamino; R = H, 1-4C alkyl, halogen, CF3, MeO, EtO or NO2; m = 1, 2, 3 or 4; n = 1, 2 or 3; and R = H or 1-4C alkyl.</abstract><edition>6</edition><oa>free_for_read</oa></addata></record>
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subjects ADHESIVES
CHEMISTRY
DYEING LEATHER, FURS, OR SOLID MACROMOLECULAR SUBSTANCES INANY FORM
DYEING OR PRINTING TEXTILES
DYES
FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
LAKES
LAUNDERING
METALLURGY
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
MORDANTS
NATURAL RESINS
ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES
PAINTS
POLISHES
TEXTILES
TREATMENT OF TEXTILES OR THE LIKE
title Isoindolin pigments
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