Process for preparing polyketones

A process for preparing polyketones by polymerising a mixture of carbon monoxide and one or more olefins in the presence of a group VIII metal catalyst which is prepared by reacting together: (a) a source of a group VIII metal, and (b) an amine, phosphine, arsine or stibine, characterised in that th...

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Hauptverfasser: BROPHY, JOHN HOWARD, BP ICALS LIMITED, COOLEY, NEIL ANDREW, BP ICALS LIMITED, GREEN, MICHAEL JAME, BP ICALS LIMITED
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Sprache:eng ; fre ; ger
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creator BROPHY, JOHN HOWARD, BP ICALS LIMITED
COOLEY, NEIL ANDREW, BP ICALS LIMITED
GREEN, MICHAEL JAME, BP ICALS LIMITED
description A process for preparing polyketones by polymerising a mixture of carbon monoxide and one or more olefins in the presence of a group VIII metal catalyst which is prepared by reacting together: (a) a source of a group VIII metal, and (b) an amine, phosphine, arsine or stibine, characterised in that the polymerisation is carried out in the presence of a hydrocarbyl aluminoxane is disclosed. The group VIII metal is preferably palladium. The aluminoxane can be of the formula [(R R Al)2O]n'' or [R AlO]n''+2, where n'' is 2-40 and R , R and R are independently a C1-C20 hydrocarbyl group.
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language eng ; fre ; ger
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title Process for preparing polyketones
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