SINGLE-STAGE HYDROTREATING PROCESS

A process is provided for converting pitch-containing residual hydrocarbon oils containing asphaltenes, sulfur and nitrogen compounds and heavy metals into distillate fuels, which comprises: mixing from about 5-60% v residual oils with catalytic cracking feedstock and with hydrogen and passing said...

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Hauptverfasser: ADAMS, CHARLES TERRELL, WASHECHECK, DON MILES
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creator ADAMS, CHARLES TERRELL
WASHECHECK, DON MILES
description A process is provided for converting pitch-containing residual hydrocarbon oils containing asphaltenes, sulfur and nitrogen compounds and heavy metals into distillate fuels, which comprises: mixing from about 5-60% v residual oils with catalytic cracking feedstock and with hydrogen and passing said mixture downwardly into a hydrotreating zone over a stacked-bed catalyst under conditions suitable to convert from about 45-75% of the sulfur compounds present in the mixture to H2S; wherein said stacked bed comprises an upper bed consisting of from about 15-85 % v, basis total catalyst, of a high-activity hydrotreating catalyst which contains from about 2-4% w nickel, from about 8-15% w molybdenum and from about 2-4% w phosphorus supported on a carrier consisting mostly of alumina, and a lower bed of a high-activity, hydrodesulfurization catalyst consisting of from about 2-4% w cobalt and/or nickel, from about 8-15% w molybdenum and less than about 0.5% w phosphorus supported on a carrier consisting mostly of alumina; and separating the reaction product from said hydrotreating zone into a hydrogen-rich gas and a liquid residue-containing oil having reduced heavy metal content and being suitable as a catalytic cracking feedstock.
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wherein said stacked bed comprises an upper bed consisting of from about 15-85 % v, basis total catalyst, of a high-activity hydrotreating catalyst which contains from about 2-4% w nickel, from about 8-15% w molybdenum and from about 2-4% w phosphorus supported on a carrier consisting mostly of alumina, and a lower bed of a high-activity, hydrodesulfurization catalyst consisting of from about 2-4% w cobalt and/or nickel, from about 8-15% w molybdenum and less than about 0.5% w phosphorus supported on a carrier consisting mostly of alumina; and separating the reaction product from said hydrotreating zone into a hydrogen-rich gas and a liquid residue-containing oil having reduced heavy metal content and being suitable as a catalytic cracking feedstock.</description><language>eng</language><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY ; CHEMISTRY ; CRACKING HYDROCARBON OILS ; FUELS ; LUBRICANTS ; METALLURGY ; MINERAL WAXES ; PEAT ; PERFORMING OPERATIONS ; PETROLEUM, GAS OR COKE INDUSTRIES ; 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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
CRACKING HYDROCARBON OILS
FUELS
LUBRICANTS
METALLURGY
MINERAL WAXES
PEAT
PERFORMING OPERATIONS
PETROLEUM, GAS OR COKE INDUSTRIES
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION
RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES
REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS
REFORMING OF NAPHTHA
TECHNICAL GASES CONTAINING CARBON MONOXIDE
THEIR RELEVANT APPARATUS
TRANSPORTING
title SINGLE-STAGE HYDROTREATING PROCESS
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