Method of making 5,6-dihydro-2-methyl-N-phenyl-1,4-oxathiin-3-carboxamide

Method of making 5,6-dihydro-2-methyl-N-phenyl-1,4-oxathiin-3-carboxamide

A method of making 2-methyl-N-phenyl-1,3-oxathiolane-2-acetamide 3-oxide characterised in that the method comprises bringing together 2-methyl-N-phenyl-1,3-oxathiolane-2-acetamide und hydrogen peroxide under basic conditions in the presence of a catalytic quantity of a heavy metal compound oxidation...

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Hauptverfasser: BREWER, ARTHUR D, ZNOTINS, ANDREW
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Sprache:eng ; fre ; ger
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CHEMISTRY
HETEROCYCLIC COMPOUNDS
METALLURGY
ORGANIC CHEMISTRY
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ZNOTINS, ANDREW
description A method of making 2-methyl-N-phenyl-1,3-oxathiolane-2-acetamide 3-oxide characterised in that the method comprises bringing together 2-methyl-N-phenyl-1,3-oxathiolane-2-acetamide und hydrogen peroxide under basic conditions in the presence of a catalytic quantity of a heavy metal compound oxidation catalyst in a liquid medium comprising water or water plus at least one nonprotic organic solvent liquid selected from (a) an aromatic hydrocarbon solvent having a boiling point not greater than 145 DEG C, (b) a chlorinated hydrocarbon solvent having a boiling point not greater than 130 DEG C, and (c) a solvent having a boiling point not greater than 130 DEG C which is an alkyl ester of an aliphatic carboxylic acid, and subjecting the resulting mixture while agitating to a temperature of from 0-25 DEG C, whereby 2-methyl-N-phenyl-1,3-oxathiolane-2-acetamide 3-oxide is formed. The product may be used for the preparation of 5,6-dihydro-2-methyl-N-phenyl-1,4-oxathi in 3-carboxamide which is a known bactericide and fungicide.
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subjects CHEMISTRY
HETEROCYCLIC COMPOUNDS
METALLURGY
ORGANIC CHEMISTRY
title Method of making 5,6-dihydro-2-methyl-N-phenyl-1,4-oxathiin-3-carboxamide
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