Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen

Catalyst component for the polymerization of alpha-olefins in solution, in suspension, in gas phase at low and high pressure and temperature or in mass at high pressures and high or low temperatures, characterised in that is defined by general formulas I or II (L(R)a)xMXy wherein: R, equal to or dif...

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Hauptverfasser: HIDALGO LLINAS, GERARDO, MARTIN MARCOS, CARLOS, PENA GARCIA, BEGONA, LAFUENTE CANAS, PILAR, MUNOZ-ESCALONA LAFUENTE, ANTONIO, MARTINEZ NUNEZ, FRANCISCA, SANCHO ROYO, JOSE
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creator HIDALGO LLINAS, GERARDO
MARTIN MARCOS, CARLOS
PENA GARCIA, BEGONA
LAFUENTE CANAS, PILAR
MUNOZ-ESCALONA LAFUENTE, ANTONIO
MARTINEZ NUNEZ, FRANCISCA
SANCHO ROYO, JOSE
description Catalyst component for the polymerization of alpha-olefins in solution, in suspension, in gas phase at low and high pressure and temperature or in mass at high pressures and high or low temperatures, characterised in that is defined by general formulas I or II (L(R)a)xMXy wherein: R, equal to or different from each other, is hydrogen or a radical which contains from 1 to 20 carbon atoms; this group optionally contains heteroatoms of groups 14 to 16 of the periodic table of the elements and boron ; at. least one group R contains a group OSiR"3, Q is selected from a group comprising: boron or an element from groups 14 or 16 of the periodic table,; m value can change from 1 to 4 and it preferably is 1 or 2; L, equal to or different from each other, is a cyclic organic group united to M through a pi bond, or it is an atom from groups 15 or 16 of the periodic table; L1 and L2, equal to or different from each other, have the same meaning of L; M is a metal from groups 3, 4, 10 of the periodic table, lanthanide or actinide. X ,equal to or different froni each other, is selected froni a group comprising: halogen, hydrogen, OR"', N(R"')2, C1-C20 alkyl or C6-C20 aryl; wherein R"' is selected from the group comprising: C1-C20 alkyl , C3-C20 cycloalkyl, C6-C20 aryl, C7-C20 alkenyl, C7-C20 arylalkyl, C7-C20 arylalkenyl or alkylaryl, linear or branched; x is 1 or 2, y is 2 or 3 iii such a way that x + y = 4 d ranges from 0 to 2; a, b and c are integers from 0 to 10, in such a way that a + b + c ≥ 1
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X ,equal to or different froni each other, is selected froni a group comprising: halogen, hydrogen, OR"', N(R"')2, C1-C20 alkyl or C6-C20 aryl; wherein R"' is selected from the group comprising: C1-C20 alkyl , C3-C20 cycloalkyl, C6-C20 aryl, C7-C20 alkenyl, C7-C20 arylalkyl, C7-C20 arylalkenyl or alkylaryl, linear or branched; x is 1 or 2, y is 2 or 3 iii such a way that x + y = 4 d ranges from 0 to 2; a, b and c are integers from 0 to 10, in such a way that a + b + c ≥ 1</abstract><edition>7</edition><oa>free_for_read</oa></addata></record>
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subjects ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC CHEMISTRY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen
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