Verfahren zur Herstellung von Hexafluorpropan und Perfluorpropan

Perfluoroisobutene-MeOH adduct (2H-octafluoroisobutyl methyl ether) converted to hexafluoropropane by reaction with trialkyl amine (e.g., triethylamine) and H2O. 1,1,1,3,3-Pentafluoropropene also produced in lesser amounts. Electrolysis of reaction product in anhydrous HF (at 10 - 50 C, 0 - 140 kPa,...

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Hauptverfasser:	HANSEN, JOHN C, CHEBURKOV, YURI
Format:	Patent
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Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS APPARATUS THEREFOR CHEMISTRY ELECTROLYTIC OR ELECTROPHORETIC PROCESSES ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTIONOF COMPOUNDS OR NON-METALS METALLURGY ORGANIC CHEMISTRY
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creator	HANSEN, JOHN C CHEBURKOV, YURI
description	Perfluoroisobutene-MeOH adduct (2H-octafluoroisobutyl methyl ether) converted to hexafluoropropane by reaction with trialkyl amine (e.g., triethylamine) and H2O. 1,1,1,3,3-Pentafluoropropene also produced in lesser amounts. Electrolysis of reaction product in anhydrous HF (at 10 - 50 C, 0 - 140 kPa, and 50 - 300 amps/m anode area) yields C3F8 and some CF3CFHCF3 condensed out of gas stream from electrolysis cell.
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subjects	ACYCLIC OR CARBOCYCLIC COMPOUNDS APPARATUS THEREFOR CHEMISTRY ELECTROLYTIC OR ELECTROPHORETIC PROCESSES ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTIONOF COMPOUNDS OR NON-METALS METALLURGY ORGANIC CHEMISTRY
title	Verfahren zur Herstellung von Hexafluorpropan und Perfluorpropan
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