VERFAHREN ZUR HERSTELLUNG VON REAKTIVEN POLYETHERPOLYOLEN MIT ETHYLENOXID-ENDBLOCK

Process for preparing polyether polyols having an end block of ethylene oxide by addition of alkylene oxides onto H-functional starter substances, in which A) a polyether polyol precursor is prepared by means of double metal cyanide (DMC) catalysis in a semicontinuous mode of operation in which prev...

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Hauptverfasser: BERGMANN, SASCHA, BAUM, EVA, OSTROWSKI, THOMAS, RUPPEL, RAIMUND, VANDEWALLE, KOEN, HOEPPNER, GERD
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creator BERGMANN, SASCHA
BAUM, EVA
OSTROWSKI, THOMAS
RUPPEL, RAIMUND
VANDEWALLE, KOEN
HOEPPNER, GERD
description Process for preparing polyether polyols having an end block of ethylene oxide by addition of alkylene oxides onto H-functional starter substances, in which A) a polyether polyol precursor is prepared by means of double metal cyanide (DMC) catalysis in a semicontinuous mode of operation in which previously prepared polyether polyol together with the DMC catalyst are placed in a reactor and H-functional starter substance and propylene oxide are added continuously, B) the polyether polyol precursor from stage A) is reacted with propylene oxide or an ethylene oxide/propylene oxide mixture in the presence of the DMC catalyst in a continuously operating reactor to give a polyether polyol intermediate, C) the intermediate from stage B) is mixed with an alkali metal hydroxide as catalyst and D) reacted with ethylene oxide in a continuously operating reactor to give the final product, E) the catalyst is separated off from the final product obtained in stage D).
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title VERFAHREN ZUR HERSTELLUNG VON REAKTIVEN POLYETHERPOLYOLEN MIT ETHYLENOXID-ENDBLOCK
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