Katalysator, dessen Herstellung und Verwendung zur Gasphasenpolymerisation von konjugierten Dienen

Catalysts comprising A) an alkoxide of a rare-earth element, a carboxylate of a rare-earth element, a complex compound of a rare-earth element with a diketone and/or an addition compound of a halide of a rare-earth element with an oxygen or nitrogen donor compound, B) a trialkylaluminium compound, a...

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Hauptverfasser: VERNALEKEN, HUGO. DR., 47800 KREFELD, DE, SYLVESTER, GERD. DR., 50375 LEVERKUSEN, DE
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creator VERNALEKEN, HUGO. DR., 47800 KREFELD, DE
SYLVESTER, GERD. DR., 50375 LEVERKUSEN, DE
description Catalysts comprising A) an alkoxide of a rare-earth element, a carboxylate of a rare-earth element, a complex compound of a rare-earth element with a diketone and/or an addition compound of a halide of a rare-earth element with an oxygen or nitrogen donor compound, B) a trialkylaluminium compound, a dialkylaluminium hydride and/or an aluminoxane, C) a further Lewis acid and D) an inert, particulate, inorganic solid having a specific surface area of greater than 10 m /g (BET) and a pore volume of from 0.3 to 15 ml/g, are eminently suitable for the polymerisation of conjugated dienes, in particular butadiene, in the gas phase.
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title Katalysator, dessen Herstellung und Verwendung zur Gasphasenpolymerisation von konjugierten Dienen
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