4,4'-BIS(ALKOXYCARBONYL)BENZOINAETHER, SOWIE VERFAHREN ZU IHRER HERSTELLUNG

Disclosed are certain novel 4,4'-bis(alkoxycarbonyl)benzoin ethers which have the formula AND WHICH ARE USEFUL AS PHOTOINITIATORS OF POLYMERIZATION, E.G., IN THE FORMATION OF COATINGS AND THIN FILMS. The novel 4,4'-bis(alkoxycarbonyl)-benzoin ethers are prepared by contacting aldehydes of...

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Hauptverfasser: KELLY, CHARLES ANDREW, PACIFICI, JAMES GRADY
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creator KELLY, CHARLES ANDREW
PACIFICI, JAMES GRADY
description Disclosed are certain novel 4,4'-bis(alkoxycarbonyl)benzoin ethers which have the formula AND WHICH ARE USEFUL AS PHOTOINITIATORS OF POLYMERIZATION, E.G., IN THE FORMATION OF COATINGS AND THIN FILMS. The novel 4,4'-bis(alkoxycarbonyl)-benzoin ethers are prepared by contacting aldehydes of the formulaWITH A CYANIDE CATALYST TO FORM 4,4'-BIS(ALKOXYCARBONYL)BENZOINS OF THE FORMULA AND BY REACTING SUCH 4,4'-BIS(ALKOXYCARBONYL)BENZOINS WITH AN ALCOHOL OF THE FORMULA R1OH to form a 4,4'-bis(alkoxycarbonyl)benzoin ether of the foregoing formula. Each of R and R1 are straight or branched chain alkyl of one to 10 carbon atoms.
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The novel 4,4'-bis(alkoxycarbonyl)-benzoin ethers are prepared by contacting aldehydes of the formulaWITH A CYANIDE CATALYST TO FORM 4,4'-BIS(ALKOXYCARBONYL)BENZOINS OF THE FORMULA AND BY REACTING SUCH 4,4'-BIS(ALKOXYCARBONYL)BENZOINS WITH AN ALCOHOL OF THE FORMULA R1OH to form a 4,4'-bis(alkoxycarbonyl)benzoin ether of the foregoing formula. 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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
APPARATUS SPECIALLY ADAPTED THEREFOR
CHEMISTRY
CINEMATOGRAPHY
COMPOSITIONS BASED THEREON
ELECTROGRAPHY
HOLOGRAPHY
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
MATERIALS THEREFOR
METALLURGY
ORGANIC CHEMISTRY
ORGANIC MACROMOLECULAR COMPOUNDS
ORIGINALS THEREFOR
PHOTOGRAPHY
PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES,e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTORDEVICES
PHYSICS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title 4,4'-BIS(ALKOXYCARBONYL)BENZOINAETHER, SOWIE VERFAHREN ZU IHRER HERSTELLUNG
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