Verfahren zur Erhoehung der Aufnahmefaehigkeit von Glasfasern fuer Harzmaterialien
Glass fibres are treated with a composition comprising a polyvalent metal salt and a phenol, a phenolic acid or a mixture thereof, to improve their receptivity for synthetic resinous materials. The polyvalent metal salt may be ferric chloride, ferrous sulphate, ferric sulphate, ferrous bromide, coba...
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| creator | KITAJ,WALTER BREWINGTON HURLEY,ELMER HENRY KIEL,ROBERT VAN SMITH,ELLSWORTH LE |
| description | Glass fibres are treated with a composition comprising a polyvalent metal salt and a phenol, a phenolic acid or a mixture thereof, to improve their receptivity for synthetic resinous materials. The polyvalent metal salt may be ferric chloride, ferrous sulphate, ferric sulphate, ferrous bromide, cobalt chloride, aluminium chloride or chromic chloride and the phenolic acid may be salicylic acid or parahydroxy benzoic acid. The composition, which may be applied from an aqueous or organic solvent medium, may also contain a polymer, copolymer or heteropolymer of an acrylate, methacrylate, styrene, vinyl acetate, vinyl chloride, vinylidene chloride or butadiene, a lubricant, e.g. an amide formed from a mono- or dibasic fatty acid and a polyethylene amine and solubilized with acetic, methacrylic or acrylic acid, and polyvinyl pyrrolidone and may have a pH of 3-7. The composition may be applied to the fibres as they are drawn from the bushing and the fibres may subsequently be used to reinforce laminates and moulded articles made from polyester or epoxy resins. The laminating or moulding resins may contain a silane, e.g. vinyltriethoxy silane, mono- or di-methoxy vinyl silane, di- or trimethoxy allyl silane, di- or tri-ethoxy allyl silane, diallyl methyl ethoxy silane and silanes containing aryloxy and haloradicals. |
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The polyvalent metal salt may be ferric chloride, ferrous sulphate, ferric sulphate, ferrous bromide, cobalt chloride, aluminium chloride or chromic chloride and the phenolic acid may be salicylic acid or parahydroxy benzoic acid. The composition, which may be applied from an aqueous or organic solvent medium, may also contain a polymer, copolymer or heteropolymer of an acrylate, methacrylate, styrene, vinyl acetate, vinyl chloride, vinylidene chloride or butadiene, a lubricant, e.g. an amide formed from a mono- or dibasic fatty acid and a polyethylene amine and solubilized with acetic, methacrylic or acrylic acid, and polyvinyl pyrrolidone and may have a pH of 3-7. The composition may be applied to the fibres as they are drawn from the bushing and the fibres may subsequently be used to reinforce laminates and moulded articles made from polyester or epoxy resins. The laminating or moulding resins may contain a silane, e.g. vinyltriethoxy silane, mono- or di-methoxy vinyl silane, di- or trimethoxy allyl silane, di- or tri-ethoxy allyl silane, diallyl methyl ethoxy silane and silanes containing aryloxy and haloradicals.</description><language>ger</language><subject>CHEMICAL COMPOSITION OF GLASSES, GLAZES, OR VITREOUSENAMELS ; CHEMISTRY ; COMPOSITIONS BASED THEREON ; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR ; GLASS ; JOINING GLASS TO GLASS OR OTHER MATERIALS ; LAUNDERING ; METALLURGY ; MINERAL OR SLAG WOOL ; ORGANIC MACROMOLECULAR COMPOUNDS ; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS,MINERALS OR SLAGS ; SURFACE TREATMENT OF GLASS ; TEXTILES ; THEIR PREPARATION OR CHEMICAL WORKING-UP ; TREATMENT OF TEXTILES OR THE LIKE ; TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS,FABRICS, FEATHERS, OR FIBROUS GOODS MADE FROM SUCH MATERIALS ; USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS</subject><creationdate>1969</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19690109&DB=EPODOC&CC=DE&NR=1469173A1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19690109&DB=EPODOC&CC=DE&NR=1469173A1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>KITAJ,WALTER</creatorcontrib><creatorcontrib>BREWINGTON HURLEY,ELMER</creatorcontrib><creatorcontrib>HENRY KIEL,ROBERT</creatorcontrib><creatorcontrib>VAN SMITH,ELLSWORTH LE</creatorcontrib><title>Verfahren zur Erhoehung der Aufnahmefaehigkeit von Glasfasern fuer Harzmaterialien</title><description>Glass fibres are treated with a composition comprising a polyvalent metal salt and a phenol, a phenolic acid or a mixture thereof, to improve their receptivity for synthetic resinous materials. The polyvalent metal salt may be ferric chloride, ferrous sulphate, ferric sulphate, ferrous bromide, cobalt chloride, aluminium chloride or chromic chloride and the phenolic acid may be salicylic acid or parahydroxy benzoic acid. The composition, which may be applied from an aqueous or organic solvent medium, may also contain a polymer, copolymer or heteropolymer of an acrylate, methacrylate, styrene, vinyl acetate, vinyl chloride, vinylidene chloride or butadiene, a lubricant, e.g. an amide formed from a mono- or dibasic fatty acid and a polyethylene amine and solubilized with acetic, methacrylic or acrylic acid, and polyvinyl pyrrolidone and may have a pH of 3-7. The composition may be applied to the fibres as they are drawn from the bushing and the fibres may subsequently be used to reinforce laminates and moulded articles made from polyester or epoxy resins. The laminating or moulding resins may contain a silane, e.g. vinyltriethoxy silane, mono- or di-methoxy vinyl silane, di- or trimethoxy allyl silane, di- or tri-ethoxy allyl silane, diallyl methyl ethoxy silane and silanes containing aryloxy and haloradicals.</description><subject>CHEMICAL COMPOSITION OF GLASSES, GLAZES, OR VITREOUSENAMELS</subject><subject>CHEMISTRY</subject><subject>COMPOSITIONS BASED THEREON</subject><subject>FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR</subject><subject>GLASS</subject><subject>JOINING GLASS TO GLASS OR OTHER MATERIALS</subject><subject>LAUNDERING</subject><subject>METALLURGY</subject><subject>MINERAL OR SLAG WOOL</subject><subject>ORGANIC MACROMOLECULAR COMPOUNDS</subject><subject>SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS,MINERALS OR SLAGS</subject><subject>SURFACE TREATMENT OF GLASS</subject><subject>TEXTILES</subject><subject>THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><subject>TREATMENT OF TEXTILES OR THE LIKE</subject><subject>TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS,FABRICS, FEATHERS, OR FIBROUS GOODS MADE FROM SUCH MATERIALS</subject><subject>USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>1969</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNqNyrEOgjAQBmAWB6O-w72AQ4PROBKsMhvjSi76lzaWg1ypA0-vgw_g9C3fsrjeoY69QmjOSlb9AJ-loyeUquyEfQ_H8KF7IUz0HoQukZPjBBVy-dsa1rnnCRo4Bsi6WDiOCZufq4LO9lY3W4xDizTyA4KpPVmz2x_NoaxM-Uf5ANeLOAo</recordid><startdate>19690109</startdate><enddate>19690109</enddate><creator>KITAJ,WALTER</creator><creator>BREWINGTON HURLEY,ELMER</creator><creator>HENRY KIEL,ROBERT</creator><creator>VAN SMITH,ELLSWORTH LE</creator><scope>EVB</scope></search><sort><creationdate>19690109</creationdate><title>Verfahren zur Erhoehung der Aufnahmefaehigkeit von Glasfasern fuer Harzmaterialien</title><author>KITAJ,WALTER ; BREWINGTON HURLEY,ELMER ; HENRY KIEL,ROBERT ; VAN SMITH,ELLSWORTH LE</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_DE1469173A13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>ger</language><creationdate>1969</creationdate><topic>CHEMICAL COMPOSITION OF GLASSES, GLAZES, OR VITREOUSENAMELS</topic><topic>CHEMISTRY</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR</topic><topic>GLASS</topic><topic>JOINING GLASS TO GLASS OR OTHER MATERIALS</topic><topic>LAUNDERING</topic><topic>METALLURGY</topic><topic>MINERAL OR SLAG WOOL</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS,MINERALS OR SLAGS</topic><topic>SURFACE TREATMENT OF GLASS</topic><topic>TEXTILES</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><topic>TREATMENT OF TEXTILES OR THE LIKE</topic><topic>TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS,FABRICS, FEATHERS, OR FIBROUS GOODS MADE FROM SUCH MATERIALS</topic><topic>USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS</topic><toplevel>online_resources</toplevel><creatorcontrib>KITAJ,WALTER</creatorcontrib><creatorcontrib>BREWINGTON HURLEY,ELMER</creatorcontrib><creatorcontrib>HENRY KIEL,ROBERT</creatorcontrib><creatorcontrib>VAN SMITH,ELLSWORTH LE</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>KITAJ,WALTER</au><au>BREWINGTON HURLEY,ELMER</au><au>HENRY KIEL,ROBERT</au><au>VAN SMITH,ELLSWORTH LE</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Verfahren zur Erhoehung der Aufnahmefaehigkeit von Glasfasern fuer Harzmaterialien</title><date>1969-01-09</date><risdate>1969</risdate><abstract>Glass fibres are treated with a composition comprising a polyvalent metal salt and a phenol, a phenolic acid or a mixture thereof, to improve their receptivity for synthetic resinous materials. The polyvalent metal salt may be ferric chloride, ferrous sulphate, ferric sulphate, ferrous bromide, cobalt chloride, aluminium chloride or chromic chloride and the phenolic acid may be salicylic acid or parahydroxy benzoic acid. The composition, which may be applied from an aqueous or organic solvent medium, may also contain a polymer, copolymer or heteropolymer of an acrylate, methacrylate, styrene, vinyl acetate, vinyl chloride, vinylidene chloride or butadiene, a lubricant, e.g. an amide formed from a mono- or dibasic fatty acid and a polyethylene amine and solubilized with acetic, methacrylic or acrylic acid, and polyvinyl pyrrolidone and may have a pH of 3-7. The composition may be applied to the fibres as they are drawn from the bushing and the fibres may subsequently be used to reinforce laminates and moulded articles made from polyester or epoxy resins. The laminating or moulding resins may contain a silane, e.g. vinyltriethoxy silane, mono- or di-methoxy vinyl silane, di- or trimethoxy allyl silane, di- or tri-ethoxy allyl silane, diallyl methyl ethoxy silane and silanes containing aryloxy and haloradicals.</abstract><oa>free_for_read</oa></addata></record> |
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| subjects | CHEMICAL COMPOSITION OF GLASSES, GLAZES, OR VITREOUSENAMELS CHEMISTRY COMPOSITIONS BASED THEREON FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR GLASS JOINING GLASS TO GLASS OR OTHER MATERIALS LAUNDERING METALLURGY MINERAL OR SLAG WOOL ORGANIC MACROMOLECULAR COMPOUNDS SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS,MINERALS OR SLAGS SURFACE TREATMENT OF GLASS TEXTILES THEIR PREPARATION OR CHEMICAL WORKING-UP TREATMENT OF TEXTILES OR THE LIKE TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS,FABRICS, FEATHERS, OR FIBROUS GOODS MADE FROM SUCH MATERIALS USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS |
| title | Verfahren zur Erhoehung der Aufnahmefaehigkeit von Glasfasern fuer Harzmaterialien |
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