Polymer mixture, useful to produce injection molded articles that are used as parts of e.g. communication devices, comprises low or high molecular (meth)acrylate(co)polymer; shock resistant modifying agent; and/or (meth)acrylate(co)polymer

Polymer mixture (A) comprises a low molecular (meth)acrylate(co)polymer (I); shock resistant modifying agent (II) based on cross linked poly(meth)acrylate; high-molecular (meth)acrylate(co)polymer (III); and/or a further (meth)acrylate(co)polymer (different from (I)). Polymer mixture (A) comprises a...

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Hauptverfasser: HOES, WERNER, WICKER, MICHAEL, HALBLAENDER, TONY, GOLDACKER, THORSTEN, REINHEIMER, ERIC, SCHULTES, KLAUS, ALBRECHT, KLAUS
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creator HOES, WERNER
WICKER, MICHAEL
HALBLAENDER, TONY
GOLDACKER, THORSTEN
REINHEIMER, ERIC
SCHULTES, KLAUS
ALBRECHT, KLAUS
description Polymer mixture (A) comprises a low molecular (meth)acrylate(co)polymer (I); shock resistant modifying agent (II) based on cross linked poly(meth)acrylate; high-molecular (meth)acrylate(co)polymer (III); and/or a further (meth)acrylate(co)polymer (different from (I)). Polymer mixture (A) comprises a low molecular (meth)acrylate(co)polymer (I) with a solution viscosity, in chloroform, at 25?C (international standard organization (ISO) 1628 - parts 6) of less than or equal to 55 ml/g; shock resistant modifying agent (II) based on cross linked poly(meth)acrylate; high-molecular (meth)acrylate(co)polymer (III) with a solution viscosity, in chloroform, at 25[deg]C (ISO 1628 - part 6) of greater than or equal to 65 ml/g; and/or a further (meth)acrylate(co)polymer (different from (I)) with a solution viscosity, in chloroform, at 25[deg]C (ISO 1628 - part 6) of 50-55 ml/g (where: (I), (II), (III) and/or (IV) exist as individual polymer or as polymer mixture; (I), (II), (III) and/or (IV) are added to make up to 100 wt.%; (A) further comprises common additives, auxiliaries and/or fillers; and a sample substance produced from (A) shows the characteristics such as tensile module (ISO 527) of at least 2500 MPa, Vicat softening temperature (ISO 306-B50) of at least 110[deg]C, impact strength (ISO 179, edgewise) of at least 30 KJ/m 2>, and a melt index (ISO 1133, 230[deg]C/3.8 kg) of at least 1 cm 3>/10 min. Independent claims are also included for: (1) a kernel-shell-particle comprising a kernel (comprising 75 wt.% of (meth)acrylate repeating units), first shell (exhibiting a glass transition temperature of less than 30[deg]C; and comprising 92-98 wt.% of (meth)acrylate repeating units and 2-8 wt.% of styrolic repeating units (both added to give 100 wt.%)) and a second shell (comprising 75 wt.% of (meth)acrylate repeating units of formula (I)) (where the radius of the kernel-shell-particle including the second shell, measured using Coulter-procedure, is greater than 160-250 nm); and (2) an injection molding molded article comprising (A). R 1>-R 5>H, halo, 1-6C alkyl or 2-6C alkenyl; and R 6>H or 1-6C alkyl. [Image]. Die Erfindung betrifft eine Polymermischung, basierend auf den (Meth)acrylat(co)polymerkomponenten a.), b.), c.) und/oder d.) gemäß Anspruch 1, wobei ein aus der Polymermischung hergestellter Probekörper gleichzeitig folgende Eigenschaften aufweist: DOLLAR A - ein Zugmodul (ISO 527) von mindestens 2500 MPa, DOLLAR A - eine Vicaterweichungstemperatur VET (ISO
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Polymer mixture (A) comprises a low molecular (meth)acrylate(co)polymer (I) with a solution viscosity, in chloroform, at 25?C (international standard organization (ISO) 1628 - parts 6) of less than or equal to 55 ml/g; shock resistant modifying agent (II) based on cross linked poly(meth)acrylate; high-molecular (meth)acrylate(co)polymer (III) with a solution viscosity, in chloroform, at 25[deg]C (ISO 1628 - part 6) of greater than or equal to 65 ml/g; and/or a further (meth)acrylate(co)polymer (different from (I)) with a solution viscosity, in chloroform, at 25[deg]C (ISO 1628 - part 6) of 50-55 ml/g (where: (I), (II), (III) and/or (IV) exist as individual polymer or as polymer mixture; (I), (II), (III) and/or (IV) are added to make up to 100 wt.%; (A) further comprises common additives, auxiliaries and/or fillers; and a sample substance produced from (A) shows the characteristics such as tensile module (ISO 527) of at least 2500 MPa, Vicat softening temperature (ISO 306-B50) of at least 110[deg]C, impact strength (ISO 179, edgewise) of at least 30 KJ/m 2&gt;, and a melt index (ISO 1133, 230[deg]C/3.8 kg) of at least 1 cm 3&gt;/10 min. Independent claims are also included for: (1) a kernel-shell-particle comprising a kernel (comprising 75 wt.% of (meth)acrylate repeating units), first shell (exhibiting a glass transition temperature of less than 30[deg]C; and comprising 92-98 wt.% of (meth)acrylate repeating units and 2-8 wt.% of styrolic repeating units (both added to give 100 wt.%)) and a second shell (comprising 75 wt.% of (meth)acrylate repeating units of formula (I)) (where the radius of the kernel-shell-particle including the second shell, measured using Coulter-procedure, is greater than 160-250 nm); and (2) an injection molding molded article comprising (A). R 1&gt;-R 5&gt;H, halo, 1-6C alkyl or 2-6C alkenyl; and R 6&gt;H or 1-6C alkyl. [Image]. Die Erfindung betrifft eine Polymermischung, basierend auf den (Meth)acrylat(co)polymerkomponenten a.), b.), c.) und/oder d.) gemäß Anspruch 1, wobei ein aus der Polymermischung hergestellter Probekörper gleichzeitig folgende Eigenschaften aufweist: DOLLAR A - ein Zugmodul (ISO 527) von mindestens 2500 MPa, DOLLAR A - eine Vicaterweichungstemperatur VET (ISO 306-B50) von mindestens 110 DEG C, DOLLAR A - eine Schlagzähigkeit (ISO 179-2D, flatwise) von mindestens 30 KJ/m·2·, und DOLLAR A - einen Schmelzindex MVR (ISO 1133, 230 DEG C/3,8 kg) von mindestens 1,0 cm·3·/10 mindestens. DOLLAR A Die Erfindung betrifft weiterhin spritzgegossene Formkörper bzw. die Verwendung der Polymermischung zur Herstellung von Spritzgussteilen.</description><language>eng ; ger</language><subject>AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G ; CHEMISTRY ; COMPOSITIONS BASED THEREON ; COMPOSITIONS OF MACROMOLECULAR COMPOUNDS ; GENERAL PROCESSES OF COMPOUNDING ; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS ; METALLURGY ; ORGANIC MACROMOLECULAR COMPOUNDS ; THEIR PREPARATION OR CHEMICAL WORKING-UP ; WORKING-UP</subject><creationdate>2006</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20060727&amp;DB=EPODOC&amp;CC=DE&amp;NR=102005003302A1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20060727&amp;DB=EPODOC&amp;CC=DE&amp;NR=102005003302A1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>HOES, WERNER</creatorcontrib><creatorcontrib>WICKER, MICHAEL</creatorcontrib><creatorcontrib>HALBLAENDER, TONY</creatorcontrib><creatorcontrib>GOLDACKER, THORSTEN</creatorcontrib><creatorcontrib>REINHEIMER, ERIC</creatorcontrib><creatorcontrib>SCHULTES, KLAUS</creatorcontrib><creatorcontrib>ALBRECHT, KLAUS</creatorcontrib><title>Polymer mixture, useful to produce injection molded articles that are used as parts of e.g. communication devices, comprises low or high molecular (meth)acrylate(co)polymer; shock resistant modifying agent; and/or (meth)acrylate(co)polymer</title><description>Polymer mixture (A) comprises a low molecular (meth)acrylate(co)polymer (I); shock resistant modifying agent (II) based on cross linked poly(meth)acrylate; high-molecular (meth)acrylate(co)polymer (III); and/or a further (meth)acrylate(co)polymer (different from (I)). Polymer mixture (A) comprises a low molecular (meth)acrylate(co)polymer (I) with a solution viscosity, in chloroform, at 25?C (international standard organization (ISO) 1628 - parts 6) of less than or equal to 55 ml/g; shock resistant modifying agent (II) based on cross linked poly(meth)acrylate; high-molecular (meth)acrylate(co)polymer (III) with a solution viscosity, in chloroform, at 25[deg]C (ISO 1628 - part 6) of greater than or equal to 65 ml/g; and/or a further (meth)acrylate(co)polymer (different from (I)) with a solution viscosity, in chloroform, at 25[deg]C (ISO 1628 - part 6) of 50-55 ml/g (where: (I), (II), (III) and/or (IV) exist as individual polymer or as polymer mixture; (I), (II), (III) and/or (IV) are added to make up to 100 wt.%; (A) further comprises common additives, auxiliaries and/or fillers; and a sample substance produced from (A) shows the characteristics such as tensile module (ISO 527) of at least 2500 MPa, Vicat softening temperature (ISO 306-B50) of at least 110[deg]C, impact strength (ISO 179, edgewise) of at least 30 KJ/m 2&gt;, and a melt index (ISO 1133, 230[deg]C/3.8 kg) of at least 1 cm 3&gt;/10 min. Independent claims are also included for: (1) a kernel-shell-particle comprising a kernel (comprising 75 wt.% of (meth)acrylate repeating units), first shell (exhibiting a glass transition temperature of less than 30[deg]C; and comprising 92-98 wt.% of (meth)acrylate repeating units and 2-8 wt.% of styrolic repeating units (both added to give 100 wt.%)) and a second shell (comprising 75 wt.% of (meth)acrylate repeating units of formula (I)) (where the radius of the kernel-shell-particle including the second shell, measured using Coulter-procedure, is greater than 160-250 nm); and (2) an injection molding molded article comprising (A). R 1&gt;-R 5&gt;H, halo, 1-6C alkyl or 2-6C alkenyl; and R 6&gt;H or 1-6C alkyl. [Image]. Die Erfindung betrifft eine Polymermischung, basierend auf den (Meth)acrylat(co)polymerkomponenten a.), b.), c.) und/oder d.) gemäß Anspruch 1, wobei ein aus der Polymermischung hergestellter Probekörper gleichzeitig folgende Eigenschaften aufweist: DOLLAR A - ein Zugmodul (ISO 527) von mindestens 2500 MPa, DOLLAR A - eine Vicaterweichungstemperatur VET (ISO 306-B50) von mindestens 110 DEG C, DOLLAR A - eine Schlagzähigkeit (ISO 179-2D, flatwise) von mindestens 30 KJ/m·2·, und DOLLAR A - einen Schmelzindex MVR (ISO 1133, 230 DEG C/3,8 kg) von mindestens 1,0 cm·3·/10 mindestens. DOLLAR A Die Erfindung betrifft weiterhin spritzgegossene Formkörper bzw. die Verwendung der Polymermischung zur Herstellung von Spritzgussteilen.</description><subject>AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G</subject><subject>CHEMISTRY</subject><subject>COMPOSITIONS BASED THEREON</subject><subject>COMPOSITIONS OF MACROMOLECULAR COMPOUNDS</subject><subject>GENERAL PROCESSES OF COMPOUNDING</subject><subject>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</subject><subject>METALLURGY</subject><subject>ORGANIC MACROMOLECULAR COMPOUNDS</subject><subject>THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><subject>WORKING-UP</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2006</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNqNjr9OAzEMxm9hQMA7eEFqpVLSnpg6obaIkYG9ihzfXSCJo9gB7ql5Be6AGTFZ35_fJ583n08cxkgFov_QWmgFVairAZQhF3YVCXx6IVTPCSIHRw5sUY-BBHSwOimaockWyFMkwB3Qul8Dcow1ebTfsKM3jySr2c7Fy8QHfgcuMPh-mLcJa7AFFpF0WFosY7BKC-Rl_nlyBzIwvkIh8aI26QQ5340-9WB7SroDm9wt_zFx2Zx1Nghd_d6L5vrh-Lx_vKHMJ5JskRLp6XDcmK0xd8a0rdneb9r_9r4AH0Vz0Q</recordid><startdate>20060727</startdate><enddate>20060727</enddate><creator>HOES, WERNER</creator><creator>WICKER, MICHAEL</creator><creator>HALBLAENDER, TONY</creator><creator>GOLDACKER, THORSTEN</creator><creator>REINHEIMER, ERIC</creator><creator>SCHULTES, KLAUS</creator><creator>ALBRECHT, KLAUS</creator><scope>EVB</scope></search><sort><creationdate>20060727</creationdate><title>Polymer mixture, useful to produce injection molded articles that are used as parts of e.g. communication devices, comprises low or high molecular (meth)acrylate(co)polymer; shock resistant modifying agent; and/or (meth)acrylate(co)polymer</title><author>HOES, WERNER ; WICKER, MICHAEL ; HALBLAENDER, TONY ; GOLDACKER, THORSTEN ; REINHEIMER, ERIC ; SCHULTES, KLAUS ; ALBRECHT, KLAUS</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_DE102005003302A13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; ger</language><creationdate>2006</creationdate><topic>AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G</topic><topic>CHEMISTRY</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>COMPOSITIONS OF MACROMOLECULAR COMPOUNDS</topic><topic>GENERAL PROCESSES OF COMPOUNDING</topic><topic>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</topic><topic>METALLURGY</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><topic>WORKING-UP</topic><toplevel>online_resources</toplevel><creatorcontrib>HOES, WERNER</creatorcontrib><creatorcontrib>WICKER, MICHAEL</creatorcontrib><creatorcontrib>HALBLAENDER, TONY</creatorcontrib><creatorcontrib>GOLDACKER, THORSTEN</creatorcontrib><creatorcontrib>REINHEIMER, ERIC</creatorcontrib><creatorcontrib>SCHULTES, KLAUS</creatorcontrib><creatorcontrib>ALBRECHT, KLAUS</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>HOES, WERNER</au><au>WICKER, MICHAEL</au><au>HALBLAENDER, TONY</au><au>GOLDACKER, THORSTEN</au><au>REINHEIMER, ERIC</au><au>SCHULTES, KLAUS</au><au>ALBRECHT, KLAUS</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Polymer mixture, useful to produce injection molded articles that are used as parts of e.g. communication devices, comprises low or high molecular (meth)acrylate(co)polymer; shock resistant modifying agent; and/or (meth)acrylate(co)polymer</title><date>2006-07-27</date><risdate>2006</risdate><abstract>Polymer mixture (A) comprises a low molecular (meth)acrylate(co)polymer (I); shock resistant modifying agent (II) based on cross linked poly(meth)acrylate; high-molecular (meth)acrylate(co)polymer (III); and/or a further (meth)acrylate(co)polymer (different from (I)). Polymer mixture (A) comprises a low molecular (meth)acrylate(co)polymer (I) with a solution viscosity, in chloroform, at 25?C (international standard organization (ISO) 1628 - parts 6) of less than or equal to 55 ml/g; shock resistant modifying agent (II) based on cross linked poly(meth)acrylate; high-molecular (meth)acrylate(co)polymer (III) with a solution viscosity, in chloroform, at 25[deg]C (ISO 1628 - part 6) of greater than or equal to 65 ml/g; and/or a further (meth)acrylate(co)polymer (different from (I)) with a solution viscosity, in chloroform, at 25[deg]C (ISO 1628 - part 6) of 50-55 ml/g (where: (I), (II), (III) and/or (IV) exist as individual polymer or as polymer mixture; (I), (II), (III) and/or (IV) are added to make up to 100 wt.%; (A) further comprises common additives, auxiliaries and/or fillers; and a sample substance produced from (A) shows the characteristics such as tensile module (ISO 527) of at least 2500 MPa, Vicat softening temperature (ISO 306-B50) of at least 110[deg]C, impact strength (ISO 179, edgewise) of at least 30 KJ/m 2&gt;, and a melt index (ISO 1133, 230[deg]C/3.8 kg) of at least 1 cm 3&gt;/10 min. Independent claims are also included for: (1) a kernel-shell-particle comprising a kernel (comprising 75 wt.% of (meth)acrylate repeating units), first shell (exhibiting a glass transition temperature of less than 30[deg]C; and comprising 92-98 wt.% of (meth)acrylate repeating units and 2-8 wt.% of styrolic repeating units (both added to give 100 wt.%)) and a second shell (comprising 75 wt.% of (meth)acrylate repeating units of formula (I)) (where the radius of the kernel-shell-particle including the second shell, measured using Coulter-procedure, is greater than 160-250 nm); and (2) an injection molding molded article comprising (A). R 1&gt;-R 5&gt;H, halo, 1-6C alkyl or 2-6C alkenyl; and R 6&gt;H or 1-6C alkyl. [Image]. Die Erfindung betrifft eine Polymermischung, basierend auf den (Meth)acrylat(co)polymerkomponenten a.), b.), c.) und/oder d.) gemäß Anspruch 1, wobei ein aus der Polymermischung hergestellter Probekörper gleichzeitig folgende Eigenschaften aufweist: DOLLAR A - ein Zugmodul (ISO 527) von mindestens 2500 MPa, DOLLAR A - eine Vicaterweichungstemperatur VET (ISO 306-B50) von mindestens 110 DEG C, DOLLAR A - eine Schlagzähigkeit (ISO 179-2D, flatwise) von mindestens 30 KJ/m·2·, und DOLLAR A - einen Schmelzindex MVR (ISO 1133, 230 DEG C/3,8 kg) von mindestens 1,0 cm·3·/10 mindestens. DOLLAR A Die Erfindung betrifft weiterhin spritzgegossene Formkörper bzw. die Verwendung der Polymermischung zur Herstellung von Spritzgussteilen.</abstract><oa>free_for_read</oa></addata></record>
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subjects AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G
CHEMISTRY
COMPOSITIONS BASED THEREON
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
GENERAL PROCESSES OF COMPOUNDING
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
WORKING-UP
title Polymer mixture, useful to produce injection molded articles that are used as parts of e.g. communication devices, comprises low or high molecular (meth)acrylate(co)polymer; shock resistant modifying agent; and/or (meth)acrylate(co)polymer
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