Method for the production of an isotropic polymeric network
The present invention relates to a method for the production of an isotropic polymeric network comprising multifunctional molecules with a functionality of at least 5 by reacting in a solvent the multifunctional molecules with a coupling agent, wherein the coupling agent is present in an amount whic...
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creator | MARISSEN ROELOF,LANGE RONALD FRANS MARIA,COUSSENSBETTY BERNICE,PUT JOZEF ALBERT,VAN DIJK JOACHIM,LOONTEJENS JACOBUS ANTONIUS |
description | The present invention relates to a method for the production of an isotropic polymeric network comprising multifunctional molecules with a functionality of at least 5 by reacting in a solvent the multifunctional molecules with a coupling agent, wherein the coupling agent is present in an amount which is sufficient to couple the multifunctional molecules to at least 5 other multifunctional molecules and wherein the sum, p , of the amounts of the multifunctional molecules and coupling agent per unit of volume, in kg/m , is at least equal to the value as given by expression (I) a(m1 + n DIVIDED 2m2) DIVIDED 10 (d+L) in which a = 0.2 d = the diameter of the multifunctional molecule, including the length of the bonds to the middle of atoms of the coupling agent to which it is attached. L = the length of the coupling agent, measured between the middle of the atoms that are connected to the multifunctional molecule. m1 = the molecular mass of the multifunctional molecule as present in the isotropic polymeric network m2 = the molecular mass of the coupling agent as present in the isotropic polymeric network n = the functionality of the multifunctional molecule ( n ≥ 5) The invention furthermore relates to an isotropic polymeric network with a density lower than 1000 kg/m and a specific Young's modulus of at least 0.01 GPa.m /kg, shaped articles hereof and the use of the isotropic polymeric network as construction material |
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L = the length of the coupling agent, measured between the middle of the atoms that are connected to the multifunctional molecule. m1 = the molecular mass of the multifunctional molecule as present in the isotropic polymeric network m2 = the molecular mass of the coupling agent as present in the isotropic polymeric network n = the functionality of the multifunctional molecule ( n ≥ 5) The invention furthermore relates to an isotropic polymeric network with a density lower than 1000 kg/m and a specific Young's modulus of at least 0.01 GPa.m /kg, shaped articles hereof and the use of the isotropic polymeric network as construction material</description><language>eng</language><subject>CHEMISTRY ; COMPOSITIONS BASED THEREON ; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS ; METALLURGY ; ORGANIC MACROMOLECULAR COMPOUNDS ; THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><creationdate>2006</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20060517&DB=EPODOC&CC=CN&NR=1774465A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20060517&DB=EPODOC&CC=CN&NR=1774465A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>MARISSEN ROELOF,LANGE RONALD FRANS MARIA,COUSSENSBETTY BERNICE,PUT JOZEF ALBERT,VAN DIJK JOACHIM,LOONTEJENS JACOBUS ANTONIUS</creatorcontrib><title>Method for the production of an isotropic polymeric network</title><description>The present invention relates to a method for the production of an isotropic polymeric network comprising multifunctional molecules with a functionality of at least 5 by reacting in a solvent the multifunctional molecules with a coupling agent, wherein the coupling agent is present in an amount which is sufficient to couple the multifunctional molecules to at least 5 other multifunctional molecules and wherein the sum, p , of the amounts of the multifunctional molecules and coupling agent per unit of volume, in kg/m , is at least equal to the value as given by expression (I) a(m1 + n DIVIDED 2m2) DIVIDED 10 (d+L) in which a = 0.2 d = the diameter of the multifunctional molecule, including the length of the bonds to the middle of atoms of the coupling agent to which it is attached. 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subjects | CHEMISTRY COMPOSITIONS BASED THEREON MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS THEIR PREPARATION OR CHEMICAL WORKING-UP |
title | Method for the production of an isotropic polymeric network |
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